text:
When you first think about the Everglades, Florida's famous "River of Grass," you may imagine vast expanses of sawgrass, abundant wildlife, deep swamp holes, towering cypress trees, and lush mangrove forests that all add up to an unparalleled, uniquely natural beauty. But these images of a pristine wilderness are in serious danger of becoming a thing of the past. This intertwined and incredibly complex ecosystem is in trouble on many fronts. Now is the time to act to restore the Everglades for future generations. We simply cannot kick the can down the road anymore, millions of lives depend on it––both human and animal.
As complex of an ecosystem as the Everglades is, the history and politics of how it came to be in such a dire state may be even more complex. But there simply isn't enough room in this short post to get into all of that. Regardless of the reason, the fact remains that the Everglades need our help. So take a stand and support Everglades restoration now.
Do we want this? Pristine wilderness...
Or this? Toxic blue-green algae...
The current Governor of Florida has put forth a bold vision to restore water quality in Florida and the Everglades. His proposal calls for $625 million dollars per year to fund critical restoration projects that will help save this natural treasure from collapse.
The Florida Legislature has this proposal in front of them right now and will be voting on it at the beginning of May. Here is a link that makes it easy to contact your state and federal representatives to let them know you support this plan and funding in full!
It literally takes thirty-seconds to fill out the form and it could make the difference between full funding and a too-small portion of that. Click here to support full funding for Everglades restoration now.
This is a national issue, so please make sure you share this with anyone you know who may have interests in Florida, wants to visit Florida, or who simply just cares about keeping places like the Everglades intact for the future! The federal government shares the cost of this restoration so we can increase our available funds by speaking to all Senators and Congressmen in Washington D.C. as well as the President.
This isn't only an Everglades problem. All of the water systems in Florida are connected, so what happens to the Everglades happens to Florida. That is why it is so important that we act now. Estuaries on both coasts are dying, marine animals are dying, businesses are dying. We can not let toxic algae and polluted water become the norm. Now is our chance to make a difference.
All of us at 4ocean thank you in advance for helping to protect our home state and this one-of-a-kind global treasure!
Each year we mark World Oceans Day on our calendar knowing that it's one of our biggest opportunities to reach millions of people around the world at once with our message of a cleaner ocean. This year, New York City, the United Nations, the Peace Boat, and Rockaway Beach played host to the 4ocean team for the weekend and as it turns out, World Oceans Day 2019 was an adventure beyond our wildest expectations.
Traveling 80 miles across the Gulfstream in the Atlantic Ocean can be a daunting task in a boat. Now think about making that same crossing on a paddleboard — intimidating, right? Now imagine that you have cystic fibrosis, an inherited disorder that causes damage to your lungs as well as other organs. Do you think you could make it?
For our May 2019 bracelet, we had the chance to showcase an animal that generally doesn't get a lot of attention when it comes to ocean conservation––the incredible octopus. But thanks to "Octo Girl" and her research, these animals may play an even bigger role in the future health of coral reefs and the ocean.

domain: politics


text: One-stage object detectors such as SSD or YOLO already have shown promising accuracy with small memory footprint and fast speed. However, it is widely recognized that one-stage detectors have difficulty in detecting small objects while they are competitive with two-stage methods on large objects. In this paper, we investigate how to alleviate this problem starting from the SSD framework. Due to their pyramidal design, the lower layer that is responsible for small objects lacks strong semantics(e.g contextual information). We address this problem by introducing a feature combining module that spreads out the strong semantics in a top-down manner. Our final model StairNet detector unifies the multi-scale representations and semantic distribution effectively. Experiments on PASCAL VOC 2007 and PASCAL VOC 2012 datasets demonstrate that StairNet significantly improves the weakness of SSD and outperforms the other state-of-the-art one-stage detectors.

domain: design


text:
Macedonian opposition leader indicted
The Macedonian Prosecution for Organized Crime and Corruption has indicted a group of suspects in the so-called "Coup Case".Source: Tanjug
Among them is leader of the opposition SDSM party Zoran Zaev.
The first-accused is a former director of the Security and Counter-Intelligence Administration, Zoran Verusevski, who is charged with illegal eavesdropping and taping, espionage and violence against state officials, the MIA news agency reported on Friday.
Three more suspects have been indicted for the same wrongdoings.
Zaev - who in February started publishing illegally eavesdropped conversations - faces charges of violence against state officials.
The prosecution has asked that four suspects from the group already in custody should remain in jail, while Zaev has not been detained.
Earlier this week, Zaev accused Prime Minister Nikola Gruevski and the head of the secret service of "unauthorized wiretapping of citizens," and announced protests that would last until the government resigns.

domain: news


text:
Weekend travel advisory
If you're traveling around the borough this weekend, there are some construction projects and events to be on the lookout for.
Irwin Street will be closed on both Saturday and Sunday between West 238th and West 240th streets from 8 a.m. until 6 p.m.
The Bronx Saint Patrick's Day Parade kicks off Sunday, shutting down several other streets from noon until 2 p.m. It all starts with the...

domain: travel


text:
PHOENIX, Ariz. (Sept. 29, 2023) - María Hert Ibarra came to the United States nearly three decades ago in search of better opportunities for both she and her family. For the past five years, she has worked as an EVS assistant at Banner Estrella Medical Center.
The mother of seven children and grandmother of one, is a talented artist who loves displaying her creativity through jewelry and engraved art. These hobbies have helped her connect with her culture and her homeland of Guadalajara, Mexico.
While she has embraced her life in the United States, María does miss her country of origin. She proudly talks about its vibrant culture, the mariachi music, and folkloric dancers. She misses the holiday celebrations spent with her family in Mexico and the exquisite Mexican cuisine that she grew up with - the flavors, spices, and aromas that hold a special place in her heart.
Maria is not only proud of her culture but is proud to say she has a family member that now works with her at Banner Estrella. Her daughter Yuliana recently joined the organization as a phlebotomist – a medical professional who is trained to do blood draws. Maria loves working for Banner Health, not only because of the support she receives from her leaders but also because she takes great pride in her work, ensuring that our patients have a clean and comfortable environment to recover in while they’re at the hospital.
“I am grateful for the opportunities that Banner Health gives me” -said Maria. “I hope to continue working for this organization for many years to come”.
Banner Health is one of the largest, secular nonprofit health care systems in the country. In addition to 33 hospitals, Banner also has an academic division, Banner – University Medicine, and a partnership with one of the world’s leading cancer programs, Banner MD Anderson Cancer Center. Banner’s array of services includes a health-insurance division, employed physician groups, outpatient surgery centers, urgent care locations, home care and hospice services, retail pharmacies, stand-alone imaging centers, physical therapy and rehabilitation, behavioral health services, a research division and a nursing registry. To make health care easier, 100% of Banner-employed doctors are available for virtual visits, and Banner operates a free 24/7 nurse line for health questions or concerns. Patients may also reserve spots at Banner Urgent Care locations and can book appointments online with many Banner-employed doctors. Headquartered in Arizona, Banner Health also has locations in California, Colorado, Nebraska, Nevada and Wyoming. For more information, visit bannerhealth.com.

domain: medical


It was rumored before, but now it is official! The metalcore band Eskimo Callboy officially submitted their brand new released song “Pump It” to the German national selection. The band heated up the rumors before replying to comments about the Eurovision Song Contest and now releasing a 3-minute song. The music video for “Pump It” could already generate over 1.6 million views in less than 3 days since release.
Will Eskimo Callboy “Pump It” for Germany at Eurovision?
The road is still long to Turin, but Eskimo Callboy takes the turbo! We do not have any information about the German national final, which is supposed to take place in early March, but the metalcore band Eskimo Callboy officially submitted their song “Pump It” to the selection. Based on the overall reaction since the release, this makes Eskimo Callboy already one of the frontrunners. The band is already playing sold-out shows in Central Europe and Russia, are on tour with Blind Channel (Finland 2021) and now they wanna get on the biggest stage in 2022!
In a video, they now announced their interest in taking part in the German national final:
The band made their debut in 2010 with a cover of Katy Perry’s “California Gurls” and released since then 5 studio albums. In January they kick off their big tour “HYPA HYPA EUROPEAN TOUR 2022“, but left some space in between in case they go to Eurovision in May!
You can watch their song “Pump It” submitted for the German national final below:
Would you love to see Eskimo Callboy on the Eurovision stage? Let us know! Be sure to stay updated by following @ESCXTRA on Twitter, @escxtra on Instagram and liking our Facebook page for the latest updates! Also, be sure to follow us on Spotify for the latest music from your favourite Eurovision acts. As well as YouTube to see our reactions to the news in the run up to the 2022 contest in Turin!


Power makes it look easy at Baltimore Grand Prix
Sep 5, 2011 | Posted by: roboblogger | Full story: ESPN
With a dominant performance in the inaugural Baltimore Grand Prix, Will Power shaved Dario Franchitti's lead in the IndyCar points race to five with three races to go.
“RaiderNation of Domination”
Since: May 07
Some West Texas County
Keep on winning Will. Show Me The Power!!!!!!!!!!
|Nation+world: Marco wins pole as Andretti cars ...||Jun '13||F1 Funatic||2|
|Narain Karthikeyan, Jules Bianchi, or Adrian Su... (Feb '13)||Feb '13||manoj||1|
|Aussies, Lotus fly at F1 test (Feb '13)||Feb '13||F1 Funatic||2|
|Hunter-Reay charges to first IndyCar title (Sep '12)||Sep '12||Will fan||2|
|Dario Franchitti wins 3rd Indy 500 (May '12)||May '12||TexasRaider||5|
|Franchitti wins Indianapolis 500, his third (May '12)||May '12||TexasRaider||1|
|Dario Franchitti has his third Indianapolis 500... (May '12)||May '12||Sons of Liberty||2|


text:
London) Group C: Austria vs North Macedonia (18:00, Bucharest) Group C: Netherlands vs Ukraine (21:00, Amsterdam) Monday 14 June. UEFA Euro 2020: Austria See Off Debutants North Macedonia To Secure First Ever Euro Win | Football News.
28 Mar European Qualifiers 28/03/2021. L. ROU Romania. Welcome to Sportstar's live coverage of the EURO 2020 Group C encounter between Austria and North Macedonia from National Arena in Bucharest. That was a convincing win for Austria in its Group C opener against North Macedonia in Buchaest. Austria midfielder Konrad Laimer: "We have huge quality in Follow live updates from Austria vs North Macedonia at the conclusion of England vs Croatia. Read more: Austria Euro 2020 squad guide: Full fixtures, group, ones to watch, odds and more. North Euro 2020: Austria churn out late win vs North Macedonia in Group C Michael Gregoritsch and Marko Arnautović both came on as substitutes and scored late to help Austria beat North Macedonia 3-1 Austria vs North Macedonia, Euro 2020: Kick-off time TV channel details, prediction and team news , 3:29pm Christian Eriksen collapse: Simon Kjaer and his team-mates’ protective Austria vs.
AUT Austria. 11 Nov Friendly Matches 11/11/2020. W. MKD North Macedonia. 5-0. LIE Liechtenstein. 28 Mar European Qualifiers 28/03/2021. L. ROU Romania.
The UEFA Euro 2020 returns to the fold with another set of important matches this weekend as Austria lock horns with North Macedonia at the North Macedonia will face Austria in their Euro 2020 Group C opener on Sunday, making their debut at a major international tournament. Group C action of Euro 2020 kicks off on Sunday (June 13) with Austria playing tournament debutants North Macedonia at the National Arena Austria started their European Championship in the best possible way, when Goran Pandev scored North Macedonia's first ever goal in a major UEFA EURO 2020, Austria vs North Macedonia LIVE streaming in India: A pair of defeats by Austria in Euro 2020 qualifying will not deter North See all odds and best bets for Austria vs North Macedonia Euro 2020 Group C with kickoff at 12:00pm ET on Sunday in Bucharest.
· Euro 2020: Austria vs North Macedonia - follow live in-play action and stats. Explore stats from Austria vs North Macedonia at Euro 2020 - this page will update automatically during the game
North Macedonia odds from William Hill Sportsbook, and the over-under Austria 3-1 North Macedonia: Arnautovic and Gregoritsch seal Austria's first Euros win Substitutes Marko Arnautovic and Michael Gregoritsch Austria won their opening game 3 - 1 to claim all the points in their UEFA Euro 2020 game against North Macedonia. Austria vs North Macedonia: Check here for info on how you can watch the game on TV and via online live streams. | Euro 2020. The Balkan country qualified for Euro 2020 via the back door of the Uefa Nations League playoff and meet an Austria side who disappointed five Austria vs North Macedonia Latest Odds.
Jun 13, 2021 · Euro 2020 Austria secured their first-ever win at the Euros after an at ease three-1 victory over North Macedonia. Lainer "Austria" vs "North Macedonia": Euro 2020 result — because it happened - Jun 13, 2021 · Euro 2020: Daily briefingAustria take on North Macedonia as Group C begins at Euro 2020 in Bucharest, Romania.Franco Foda is looking to guide his side to Jun 11, 2021 · Austria vs North Macedonia Euro 2020 Match Preview or Key Statistics 📊. This is the first encounter between Austria and North Macedonia at a major tournament (World Cup and Euros). Their only two previous meetings took place in the Euro 2020 qualifiers, with Austria winning both by a 6-2 aggregate scoreline (4-1 away, 2-1 home). · UEFA Euro 2020 is underway, Austria will face North Macedonia for their next Group C game.
Group C: Netherlands vs Ukraine — 12:30 am IST, Amsterdam 2020 European Austria vs North Macedonia all goals 3-1 and highlight the match Euro 2020Austria vs North Macedonia all goals 3-1 and highlight the match Euro 2020Austria v Austria vs North Macedonia all goals 1-1 and highlight the match Euro 2020Austria vs North Macedonia all goals 1-1 and highlight the match Euro 2020austria v Jun 11, 2021 · Euro 2020: Ahead of clash with Croatia, many questions hang over England; Group C: Austria vs North Macedonia — 9:30 pm IST, Bucharest Monday, 14 June Group C Austria Vs North Macedonia Full Goal And Extended Euro 2020#austria #northmacedonia #pialaeropa2020 #europa2020 #hasilbolatadimalam #hasilpertandingantadimalam Nov 14, 2019 · Austria vs North Macedonia EURO Qualification Date: Saturday, 16 November 2019 Kick-off at 19:45 UK / 20:45 CET Venue: Ernst Happel Stadion (Vienna). With eight games up, Austria have emerged as the front runners to progress from Group G along with Poland. See full list on skysports.com Jun 13, 2021 · Search for: Search. Home Nov 16, 2019 · Austria vs North Macedonia football Betting Tips Read our Euro 2020 betting preview for the football match between Austria vs North Macedonia below.
Football fans can watch this game on a live streaming service should the game be included in the schedule mentioned above. Here we give helpful information for watching this Euro 2020 match that includes the most recent team form, h2h meetings and our game views. Austria secure their first ever win at the Euros after a comfortable 3-1 victory over North Macedonia. Lainer opened the scoring in the 18th minute, guiding · hindustantimes.com - Hindustan Times Euro 2020 Austria vs North Macedonia Live Streaming in India: When and where to watch on TV and online UEFA Euro 2020 Austria vs North … The Group C opener sees Austria take on North Macedonia. James Capps of Freebets.com is joined by football experts Charlie McCann and Graeme Bailey to previe · See all odds and best bets for Austria vs North Macedonia Euro 2020 Group C with kickoff at 12:00pm ET on Sunday in Bucharest Jun 11, 2021 · Group C: Austria vs North Macedonia — 9:30 pm IST, Bucharest.
- 2020 euro draw ukraine vs. north macedonia
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Read more on telegraph.co.uk. Austria; Euro 2020; North Macedonia; Macedonia (Region) North Macedonia (Euro 2020) Jun 04, 2021 · Here's everything you need to know about the 2021 European Championship (UEFA 2020).

domain: sports


Academy of Music | Philadelphia, Pennsylvania
EVENT CANCELLED. Please contact your ticket point of purchase to claim a refund on your tickets.
Come and catch the incredible Opera Philadelphia: Macbeth this coming season! Academy of Music always brings the very best in all kinds of entertainment from music to theatre and other kinds of exciting events for fans to get involved in! Head on down to Academy of Music on Wednesday 23rd September 2020 to be a part of the crowd! Tickets available to book right here, right NOW!
As Opera Philadelphia: Macbeth sets the stage for the event you will truly never forget, the Academy of Music is getting ready to make your evening even better with the greatest quality throughout. Known for it's incredible location in Philadelphia the Academy of Music has become the number one spot for entertainment and September is setting out to be one of the biggest months yet! Joining the unbeatable line-up at Academy of Music on Wednesday 23rd September 2020 is none other than Opera Philadelphia: Macbeth so it's no wonder that tickets are already booking out fast! Join in the fun by grabbing tickets for you, your friends and family! Every event season at Academy of Music aims to blow the attendees away – you won't be disappointed!


View Full Version : Displacement maps - ZBrush 3.5 <-> Cinema 4D
02-01-2010, 08:14 PM
I just have a little problem with exporting and applying displacement maps from zbrush to Cinema 4D.
This is my workflow so far:
• Building the base mesh in C4D
• Build UVs with the automatic assistant from Body-Paint 3D
• Export the mesh as OBJ
• Import the OBJ as tool in ZBrush
• Sculpting on that tool
• Export a displacement map from ZBrush
• Import the displacement map into the displacement-channel of the material
• Apply the material to the mesh
... well, the mesh is just a bit smoother but nothing of the sculpted displacement seems to be in place or even applied. Some bumps and scratches here and there - but no real shape.
I already tried to find some answers via google and checked some tutorial videos on youtube - but I just followed the steps in the tutorials - with no result.
Maybe there are some important settings I missed out?
Hope anyone can give me a hint!
02-14-2010, 05:18 PM
maybe try posting the same question in the c4d forum :thumbsup:
03-01-2010, 03:50 PM
Usually, the problem is either with your program specifically, or with the normal map not being dense enough. In addition, keep in mind that Zbrush flips your UV maps upside down. Place the normal map under a projector in the texture settings, and then change the mode to UVW, and make the Y value -1 (-100%). If that still isn't working (and it sometimes happens when using not using tangent maps) import your normal map into Crazybump as a color map, and export as a normal map. I've gotten great results that way.
03-08-2010, 04:48 PM
Thank you for your answers.
I found a video on youtube which solved my problem with some quite easy settings.
Check out at YouTube (http://www.youtube.com/watch?v=oUx9a4g0lJ0)
Problem solved! =)
Thanks for reading!
03-08-2010, 09:37 PM
nice...thanks for the link :beer:
03-08-2010, 09:37 PM
This thread has been automatically closed as it remained inactive for 12 months. If you wish to continue the discussion, please create a new thread in the appropriate forum.


text:
Nobody knows that but the banks and the home occupier(s), it's the wildcard....Connecticut fares better in historical ratios of forclosure activity than 33 of 50 states in the US...... up to today.............the real issue is the value of home owneraship to You at this time based on your plans, lifestage, life style, income and resources. Everybody allocates a percentage of their income for housing/food/etc...........You have to decide that equation, a very personal choice that I help you evaluate if your are my client... more
Hi, Jeff Granoff here, from GRL & REALTORS, in New Haven. The reason the monthly fee is higher than expected for a condo is because it also includes heat, hot water, and property taxes. In addition, 40% of the monthly fee is tax deductable. If you have any further questions, please feel free to contact me. My phone is 203-494-1337. There are several units currently available. It would be my pleasure to help you find a new home.... more
Well I must be the worst agent in the world. I advise my clients to spend less than what they're qualified by their lender. My advice is always spend as much as you are comfortable with knowing you will be making payments for the next 30 years.
I would caution you about taking home buying shows with a grain of salt. Many of them are partially scripted. And the most popular show 'Househunters' is an outright twisting of the truth. In fact the 'buyers' have already bought a home and they're being shown comparable homes. But for the sake of TV the outcome is known even before they shoot one foot of film.
And for every $1,000 more a buyer spends on a home, the agent profits approximately an additional $10 to $20. And the home STILL has to appraise, the homeowners have to qualify and the underwriter has to approve it all.
Just remember, in the end the decision is yours as to how much you should spend. And if you have an agent that doesn't understand, find another agent.... more
The assessed value is usually 80% of the appraised value. Depending on the area, condition and age of the home should all also take a play in the pricing of a home. I would be more than happy to assist you further on your home search and do a free comparative market analysis of the homes you are interested in. Julie Lucia, Realtor, Showcase Realty, 203-578-5631 firstname.lastname@example.org... more
My best suggestion is to use a mortgage broker. They typically work with a large number of lenders and can usually shop rates. When your credit is pulled an inquiry is noted on your report, when you are mortgage shopping among lenders whithin a short period of time the multiple inquiries for a mortgage usually don't count against you.
Get in touch I have a few excellent brokers I can suggest.... more
There are a lot of options available. There would be much more criteria needed on the home that will suit your needs to even begin.
I suggest you seek the assistance of a Realtor that is familiar with the area such as myself. Give me a call if you need assistance.
Sounds like you're not comfortable with the dual agency issue, and to be honest I am not a fan of it. Tell her you do not agree to it. I know in VA that is an option of anyone - everyone is entitled to their own agent. Tell her you want to have separate agents so you can have the agency representation you're paying for. This is the kind of market where that is understandable.... more
What sort of litigation?
There are some types that are pretty certain to be resolved, and can be resolved fairly quickly.
There are other types that could drag on for years.
You need to get a fairly good idea where along that spectrum your house falls. Best place to start is your Realtor.
Hope that helps.... more
I suggest that you check your purchase contract regarding your $1K deposit as usually this goes towards your cash down payment for the property and helps to determine what amount you will be financing (if it's not a cash purchase). You will receive a credit at closing for the $6K from the seller to assist with your closing costs.
Good luck to you!
Prudential Connecticut Realty... more

domain: finance


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Grammarly is an online tool that analyzes the grammar and spelling of texts written in English. It will help you improve your writing skills and offer suggestions on how to correct any errors. You can change the style, tone, and context of your text. The software also can detect plagiarism.
Grammarly is a grammar checker online that can be used to improve your writing skills. It helps you spot mistakes and correct them instantly. You can use it to write and edit any type of text you want to.
Grammarly’s spell-checker is a fun and smart way to make sure your content is correct. The app scans your text word for word and flags the most common grammatical errors. This includes spelling mistakes punctuation, grammar and spelling mistakes.
The Spell checker is a feature of the full Grammarly extension for Chrome. You’ll see a message appear in your lower right corner when you add the extension. To enable the feature, click the green “C”, button.
In addition to its spell checker, Grammarly offers a number of other features. For example, it gives you insights into sentence length and readability, as well as other important data.
Grammarly utilizes an AI-powered algorithm that checks for grammatical errors in your writing. Contrary to other spell-checkers, Grammarly does not automatically add corrections without your permission.
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Grammarly’s suggestions for tone can assist you in writing more polished, engaging, or effective writing. You can try it for no cost.
Grammarly Business features include several advanced tools that can assist you in writing and sending professional emails. You can check your emails prior to sending them out, review social media posts and make sure spelling and grammar errors are corrected. In addition, you’ll have an expert writer available to you.
There are two kinds of plans offered by the company. The first one is for teams and the second for individuals. Each plan comes with the same options, however with different benefits. For instance, with the first plan you’ll have access to a dashboard which displays various metrics to measure how they’re performing. Additionally, you’ll have access to Grammarly, which is a Grammarly extension for the browser.
It’s not the most feature-rich tool available however it does include a few notable features. These include the snippets mentioned above, and additional notable features such as a plagiarism checker. It also has a central reporting function and an SAML-SSO.
The most fascinating feature is, however, the ability of the software to determine the source of copied text. This is a neat little feature worth mentioning regardless whether you’re a professional writer and/or simply copying content from websites.
The company offers many other tools that can assist you in becoming more productive, not only the plagiarism detection feature. In addition to the plagiarism detection tool, you’ll be able to access a team dashboard along with style guides and a myriad of other tools. You can have up to three users based on your requirements. And, if your team is larger, you can benefit from discounted pricing. Unlike the free version, you’ll have access to your Grammarly Business account on virtually every device including mobile.
Grammarly is a great tool to help you write better. But, it’s not for all. There are a variety of options to assist you in creating better content regardless of whether you’re a college student or an experienced writer.
Ginger is a free grammar checker that offers a lot of helpful features. It can be used to correct grammar and spelling. It supports more than 40 languages and a variety browsers.
Linguix is a powerful writing tool that provides features that improve the quality of your content. It helps you write concise, clear and concise pieces of text. It also comes with SEO features that can aid in increasing brand engagement.
Hemingway Editor is an affordable tool that is easy to use and will aid you in writing better content. It comes with a word association feature that can help you overcome writer’s block. It also lets you upload files and publish to WordPress or Medium.
WordTune is another useful tool to produce more readable content. The program also offers a wide range of options to alter the structure of your sentences.
ProWritingAid is a professional writing tool that will teach you how to write grammatically correct sentences. Its reports include basic metrics, vocabulary tips, and advanced analytics.
Slick Write is another tool that will check your content for grammar and spelling mistakes. However, you can’t get the full capabilities of the program without purchasing its premium version.
Readable is a website-based tool that offers both free and premium versions. Both versions come with basic grammar and plagiarism tests. They also review existing websites to detect common mistakes and offer suggestions to improve.
ProWritingAid is a great tool for indie authors, but it’s also a fantastic option for professionals. The Premium version is the best, even although the free version offers many of the same features.


Dell Precision M6400
Power to go.
- Solidly built, plenty of processing power, room for up to 16GB of RAM, comfortable to use, dual-mode wireless networking, ExpressCard and PC Card slots
- Fingerprint reader isn't standard, modular bay doesn't have a second battery option,
For users who run engineering, design or animation programs, this mobile workstation is a worthwhile choice. It's very fast, and the best part is you won't be shackled to your desk and will be able to use the same machine either at home or in the office.
Price$ 6,440.90 (AUD)
The Precision M6400 is a mobile workstation that offers the latest in fast hardware to crunch data for design, animation and engineering users. Residing in its aluminium chassis are an Intel Core 2 Extreme CPU, NVIDIA Quadro graphics, 4GB of RAM and 500GB of storage.
The physical stature of the Precision is intimidating: it has a high-definition 17in screen, and its full-sized keyboard is convenient for touch-typing and also for number entry, thanks to the dedicated number pad. You also get two pointing devices, so that you can navigate using either the touchpad or a small joystick device.
It's a very comfortable laptop to use, mainly because its palm rest is so roomy and its keys are large, and it also doesn't suffer from any heat issues. We also love the backlight for the keyboard, which makes it a joy to type in the dark. The soft left- and right-click buttons, as well as the soft keyboard keys, ensure that you won't wake your partner if you work late into the night.
Because the unit has two relatively large vent areas, it doesn't get overly warm. This means it can be used without too much discomfort while resting on your lap. Of course, it's too big to use on public transport, but if you use it while at an Internet cafe or while in transit at an airport and you are away from an outlet, its standard battery will last over 2hr 13min. You can quickly check how much battery life remains by pushing a button on the battery. It illuminates a level indicator with five dots; the more dots displayed, the more life the battery has left.
But it's the guts of the machine that are worthy of most discussion. Its score of 112 in WorldBench 6 is a very fast one, and it's due to the machine's speedy Intel Core 2 Duo Extreme X9100 CPU, which runs at 3.06GHz, 4GB of DDR3 RAM, which runs at 1066MHz, the discrete graphics and the 7200rpm hard drive. The graphics are processed by NVIDIA's high-end Quadro FX 2700M chip, which is suitable for use with many CAD, animation and CAM programs. For intensive design and engineering work, this is the chip you want. In the 3dsMax portion of WorldBench 6, the notebook completed a rendering workload in just 311sec, which is approximately 50 per cent faster than a typical mid-range laptop.
Blender 3D completed a rendering job in 58sec, and this is the same time iTunes took to complete our 53min WAV to 192Kbps MP3 conversion. These programs used both CPU cores and pushed them to their limit, and it's the same rendering and encoding time you can expect to get out of a 3GHz PC. So for a laptop, this thing is plenty quick, and there is also an option for a quad-core CPU.
Despite being a workstation model, it doesn't compromise on looks. Its straight lines are elegant, and the array of ports and slots along the edges is logical and spaced nicely for easy access. The chassis is big enough to accommodate both PC Card and ExpressCard slots, with the former on the left side and the latter on the right. We love the slot-loading DVD burner: it not only looks good, it means there are less protruding bits to accidentally break off. It sits in a modular bay, which can be used to house another hard drive, but not a second battery. The spine of the laptop is devoid of any ports, as this is where the vents for the coolers reside.
The keyboard doesn't have any unnecessary shortcut buttons; you'll only find volume and calculator shortcut buttons, along with Function key shortcuts to alter the brightness of the screen and the illumination of the keyboard.
But the best part of the laptop is its screen. The 1920x1200 resolution really is roomy, and it lets you line up windows side-by-side with ease. It's bright enough for use outdoors, and, despite being slightly glossy, it is easy to view in bright rooms. An ambient light sensor adjusts the brightness of the screen depending on your environment. It noticeably affected the brightness level when moving from bright rooms to darkness, and vice versa. It's a convenient little feature that should help reduce eyestrain, especially when working in the dark. If you manipulate the brightness manually, this will override the ambient sensor, but it will initially revert back to the automatic brightness setting for a second before setting at the manual level.
For physical security, the chassis has a steel reinforced cable lock facility, as well as optical and hard drive locks. User security is aided by smart card readers (slot-based and contactless), but a fingerprint reader is not standard.
All up, the Precision M6400 is a worthy machine for working on taxing jobs while at home, in the office or abroad. It's solidly built, has good connectivity options and plenty of processing power.
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First impression on unpacking the Q702 test unit was the solid feel and clean, minimalist styling.
For work use, Microsoft Word and Excel programs pre-installed on the device are adequate for preparing short documents.
The Fujitsu LifeBook UH574 allowed for great mobility without being obnoxiously heavy or clunky. Its twelve hours of battery life did not disappoint.
The screen was particularly good. It is bright and visible from most angles, however heat is an issue, particularly around the Windows button on the front, and on the back where the battery housing is located.
My first impression after unboxing the Q702 is that it is a nice looking unit. Styling is somewhat minimalist but very effective. The tablet part, once detached, has a nice weight, and no buttons or switches are located in awkward or intrusive positions.
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Skrillex and Troyboi had only just released their collaboration “WARLORDZ” in June when not three weeks later they were already teasing another track together. This one would feature Ty Dolla $ign, Lan, and Ludmilla, and it would be called “Malokera.”
Well, the day for “Malokera” to drop is here, and it’s coming out this Friday.
Reno was the sweatiest show I’ve ever played in my life🌊🖤 PS: We are DROPPING this new 🔥 “MALOKERA” FRIDAY
“Malokera” is a swing back toward the hip hop productions that Skrillex had been doing before he dropped the 2-track Show Tracks EP last month.
This one drops tomorrow, so stay tuned!
Photo via Rukes.com


text:
Rooney Mara gets a make-over for 'Dragon Tattoo'
Actress Rooney Mara says she is happy to get rid of her feminine signature look for "The Girl with the Dragon Tattoo"
Actress Rooney Mara says she is happy to get rid of her feminine signature look for "The Girl with the Dragon Tattoo".
She underwent drastic transformation for her role as Lisbeth Salander and according to reports she will have to live with it till at least 2015.
"Before 'Dragon Tattoo', I dressed very much like girls. A lot of blush-colored things. Now I literally roll out of bed and put on whatever is there. I have really enjoyed being a boy this last year," she told US Vogue.
Mara also revealed that she was given a make-over by makeup artist Pat McGrath, costume designer Trish Summerville and hairstylist Danilo. McGrath created 26 different looks for her.
"We went from the white-powdered sick-clown makeup to stitches in the face all the way to greasy, bloody eyes. I instantly knew how I could make her character so different. And then once the hair was cut in that mad shape, I was like, Well, the eyebrows have got to go. And in the end, it would look now and it would look new,"said McGrath.
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domain: artistic


GLSA-200411-29 : unarj: Long filenames buffer overflow and a path traversal vulnerability
Critical Nessus Plugin ID 15777
SynopsisThe remote Gentoo host is missing one or more security-related patches.
DescriptionThe remote host is affected by the vulnerability described in GLSA-200411-29 (unarj: Long filenames buffer overflow and a path traversal vulnerability)
unarj has a bounds checking vulnerability within the handling of long filenames in archives. It also fails to properly sanitize paths when extracting an archive (if the 'x' option is used to preserve paths).
An attacker could trigger a buffer overflow or a path traversal by enticing a user to open an archive containing specially crafted path names, potentially resulting in the overwrite of files or execution of arbitrary code with the permissions of the user running unarj.
There is no known workaround at this time.
SolutionAll unarj users should upgrade to the latest version:
# emerge --sync # emerge --ask --oneshot --verbose '>=app-arch/unarj-2.63a-r2'


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Limited liability companies (LLCs) are becoming increasingly popular among business owners. For a lot of these entrepreneurs, the structure of LLCs brings a lot of benefits to their companies. These are six reasons why you should form an LLC for your small business:
Numerous Tax Benefits
One of the most common reasons why entrepreneurs form LLCs for their businesses is the many tax benefits the company and its owners get. Due to the default pass-through taxation arrangement of LLCs, the company usually does not pay corporate taxes like large corporations. Instead, the company’s income will be reported as part of the owner’s personal income tax return.
If the business owners do not want to pay the self-employment taxes, they may also elect to pass the responsibility of paying taxes to the LLC. However, they should do this as early as the formation of the LLC. In cases like these, the company can decide whether they want to be taxed as a C-Corporation or S-Corporation. This gives the owners the opportunity to decide which will give them more tax benefits.
As already mentioned above, LLCs provide limited liability protection for its owners. What does this exactly mean? Since the LLC is a separate entity on its own, it can file for loans and acquire assets. However, creditors will not be able to go after the personal assets of the owners.
This means that they cannot sue the owners if the company is unable to pay off its debt. There are, however, major exceptions to this rule. But generally, this is the typical arrangement in an LLC.
In comparison, partnerships and sole proprietorships put the owners at high risk. Their personal assets are vulnerable from creditors especially if the business cannot pay the debt on its own.
Easier Estate Planning
Estate attorneys are able to put LLCs in a living trust. Because of this, planning an estate will be much easier and efficient. It also provides tax benefits for the estate. A family LLC, for example, can help decrease the estate taxes that children have to deal with when they receive their inheritance. Distribution of the inheritance will be also less costly because there will be lesser gift taxes.
However, those who want to establish an estate have to tread this topic lightly. It is highly complicated so a qualified lawyer should explain the process well to the client.
Flexible And Versatile Management Structure
LLCs allow the owners more freedom with regards to how they run the company. The owners can agree on a management structure that will work in the best way for the business.
The two most common arrangements are owner-managed LLCs or manager-managed LLCs. Owner-managed LLCs value equal voices of the owners while manager-managed LLCs pass the task of taking care of day-to-day affairs to managers.
Improved Business Credibility
If a business wants to be more credible in the eyes of its partners, networks, and suppliers, converting into an LLC will help a lot in that. LLCs are generally considered as more credible because they see that the owners are bound to their companies as they have made formal commitments to it.
Lesser Restrictions On Ownership And Compliance Requirements
Compared to corporations, LLCs have fewer restrictions on ownership. This is especially true on the matter of who can be an LLC owner, which is quite challenging with corporations. Unlike S-Corporations, there are also fewer guidelines on how many owners an LLC can have.
As to compliance requirements, LLCs fare better when compared to both S-Corporations and C-Corporations. For one, there are much fewer annual requirements that are mandated by the state.
Creating LLCs also require less paperwork. In fact, the process in some states only entails the payment of fees, filing the articles of organization, and making annual filings. This makes everything easier for a busy entrepreneur.
That said, LLCs do not mean that owners should be less dedicated to their job of ensuring that the business flourishes. It is best that the owners draft an operating agreement to guide how the company will be run.
These are some top reasons you should form an LLC. So, once you decide to form an LLC, you need to know how to get LLC approval from your state. In addition to that, you need an employer identification number (EIN). The good news is that you can apply for your EIN number online. So, get started with your LLC and have all the benefits of running an LLC.

domain: law


text:
Many people find it thrilling to renovate their bathroom. This is a task that most people can tackle by themselves and the notion of having a stunning bathroom with a relaxing atmosphere will make it an exciting undertaking. If you are planning to redesign the bathroom, it is possible to be creative One of the ways to come up with ideas is to choose an appropriate theme for your bathroom.
A reason why choosing a theme for your bathroom will be essential when remodeling is because a theme can provide you with an overall color scheme you can utilize. Choosing the right colors for the bathroom is essential when remodeling. You can also avail remodeling services via the internet.
Image Source: Google
You must ensure that the colors are blending together, and the overall theme can help you choose the right colors for the bathroom in general. If you've got an idea of the theme choosing the right items for the bathroom and selecting the right color for it is a lot simpler. The design of the bathroom remodeling project is crucial because it lets you express your personal style in the bathroom.
This is where your personality will be seen. You would like your bathroom to be an area where you feel comfortable and, by having a stunning theme, you can be sure that is the case. If you're vibrant and joyful, you are able to let your character show through. If you're one who is a fan of a modern look, that can shine through also in the bathroom.


text:
Main / Productivity / Patagonia special
Name: Patagonia special
File size: 742mb
Top Gear: Patagonia Special is a full length special that was aired as a two-part episode for the BBC car show Top Gear; the first part was aired on 27 December Summary - Reception - Controversy. 1 Jan - 30 min Watch Top Gear: Patagonia Special 1/4 by Dark Energy on Dailymotion here. 27 Dec Jeremy Clarkson, James May and Richard Hammond arrived in Argentina in September to film the Top Gear Christmas Special. On a ridge, high above the vast, sparsely-populated plains of Patagonia, Jeremy Clarkson is standing with his binoculars craned towards the horizon.
20 Oct Newly released government emails have revealed the chaos as a diplomatic row was sparked by Top Gear's controversial Christmas special in. The Patagonia Special is a two-part Top Gear Christmas special, which aired as part of the show's twenty-second series. The special is the second that Top Gear . 27 Feb - 62 min - Uploaded by Jeremy Clarkson fan club Jeremy Clarkson, James May and Richard Hammond arrived in Argentina to film the Top Gear.
12 Dec - 21 sec - Uploaded by BBC beetersbakery.com The boys are back with a Top Gear Patagonia Christmas special. Comedy All Episodes () · Next · Patagonia Special: Part 1 Poster. Clarkson, Hammond and May embark on a journey to the southernmost point of South America. 4 Apr The filming of the special, in which Clarkson, James May and Richard Hammond drive Top Gear: The Patagonia Special is out now on DVD. 14 Apr - 62 min Top Gear Season 22 Special Episode 1. Patagonia Special Part 1 - All Season 22 episodes. Find Top Gear - The Patagonia Special [DVD]  at beetersbakery.com Movies & TV, home of thousands of titles on DVD and Blu-ray.
Jeremy Clarkson, Richard Hammond and James May travel through Patagonia in sports cars. Most people wouldn't know what you're talking about because the incident had very little coverage, and the show and its hosts are not known in our country. 30 Dec FANS flooded Twitter to defend Top Gear last night - after the broadcast of a special Patagonia episode sparked new fury in Argentina. Read breaking news, in-depth articles and press releases about top gear patagonia special and other automotive topics.

domain: entertainment


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text:
Real Housewives: Ranking The 12 Shadiest Significant Others
Bravo’s most successful franchise is undeniably the Real Housewives reality series. What fans love the most about this show is that many of the women completely open up their lives to viewers, including their sometimes tumultuous love lives. We’ve watched many relationships come and go over the years as the women have dated (or even married) some pretty interesting characters! From infidelity to incarceration, here are 12 of the shadiest significant others who’ve appeared on the show!
12. John Mahdessian
We put John Mahdessian in the last spot on this list because he’s never really did anything too terrible to Real Housewives of New York City star Dorinda, aside from getting into a tiff with her and her friends on camera. To be fair, he tried to make up with Bethenny and does seem to treat Dorinda well, but the fighting with the women and showing up drunk at girls’ nights isn’t cool. We’ll give him the benefit of the doubt though because we know Dorinda is not exactly the kind of woman who’d put up with shady business!
11. Paul ‘PK’ Kemsley
Paul Kemsley, better known as ‘PK’ on The Real Housewives of Beverly Hills, joined the show alongside his wife, Dorit, in season 7 and he didn’t exactly leave a good impression. Remember Pantygate? It dragged on all season long and caused a ton of drama, but no one in the situation looked worse than PK when he admitted to his wife that he was staring up Erika’s skirt! Even worse, he made a creepy comment that he “didn’t mind the view” — gross! While he seems to have learned his lesson and is keeping a lower profile this season, it’ll take a while for him to get back in the audience’s good graces.


text:
Managed to complete my first half marathon in 2 hours 19 minutes
Just signed up for the Tewkesbury half marathon at the end of May!
Back to biking next Sunday though :-)
Well done Andy, I guess the fact that you have signed up for another one means you must have enjoyed it!
Well done mate.
Don’t give up the biking!
Certainly not going to give up the biking – it’s what got me fit in the first place! Need to start training for the FOD Spring Classic soon :-)

domain: hobby


text:
Thom is best known for his Nikon reference books, many of which whose covers are shown below (just click on a cover to get to a detail page for the work).
If you're looking for Thom's book recommendations, click here.
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domain: library


text:
Sgt. 1st Class Dillard Johnson and Staff Sgt. Jared Kennedy of a C. Troop, 3rd Squadron, 7th Cavalry, stand in front of a Bradley Fighting Vehicle in east Baghdad. The NCO's led their unit in a gun battle with terrorists Dec. 14, resulting in four terrorists killed while taking no casualties of their own.
|Date Posted:||12.23.2005 11:51|
This work, Sgt. 1st Class Johnson and Staff Sgt. Kennedy [Image 1 of 221], is free of known copyright restrictions under U.S. copyright law.


text:
US 3607069 A
Abstract available in
Claims available in
Description (OCR text may contain errors)
United States Patent inventors Appl. No. Filed Patented Assignee PROCESS FOR RECOVERING SULFUR AND METAL VALUES FROM SULFUR-BEARING MINERALS 15 Claims, 1 Drawing Fig.
11.8. C1 23/225, 23/130,23/181,75/l0l,260/429J Int. Cl C0lb 17/06 Field of Search ....23/224-225,
Primary Examiner Oscar R. Vertiz Assistant ExaminerG. O. Peters Attorneys-Gerard P. Rooney and Albert L. Gazzola ABSTRACT: A process for recovering sulfur values and concentrating other metal values from pyrrhotite (FeS) by complexing ferrous sulfide in aqueous medium with an insoluble alkylamino polycarboxylic acid chelating agent to form a water-soluble ferrous chelate, hydrogen sulfide and a concentrate of insoluble sulfides of nonferrous metals. The hydrogen sulfide is reacted Claus sulfur dioxide under conventional Clause reaction conditions to yield sulfur. The ferrous chelate, in solution, is treated with an oxygen-free sulfur dioxide whereby the water-insoluble chelating agent is regenerated for recycle. The solution of ferrous bisulfite which forms is processed to yield additional quantities of sulfur dioxide from which sulfur is recovered.
PATENTEDSEP21 9n PYRITE Fe 52 PYRRHOTITE s K r Fe 8. S O
I 2 I I ///UNDILUTED SMELTER ED A k I T 802 GAS OR OTHER R SOURCE OF so I Fe EDTA 2 I I 2 REE I 1 I I RECOVERED BOIL I EDTA Fe(HSO I Fe A I I l I I I I0 t I INVENTORS CHARLES P. BRUEN DONALD H. KELLY CHRISTIAN A.WAMSER BHASKAR BANDYOPADHYAY PROCESS FOR RECOVERING SULFUR AND METAL VALUES FROM SULFUR-BEARING MINERALS BACKGROUND OF THE INVENTION It is known to recover sulfur by the process of roasting pyrite ore in a shaft furnace or a fluidized bed reactor at temperatures of from 650-800 C., in the presence of a reducing agent, wherein the sulfur dioxide produced under this reducing atmosphere is converted to sulfur. This roasting process is used not only to recover sulfur, but also to recover metal values which may be present in pyrite ores. A process such as this is disclosed in U.S. Pat. No. 2,869,999. The use of the roasting process to reduce sulfur from pyrite requires extremely high temperatures over long periods and concomitantly high cost and operating difficulties. As a consequence, for economic reasons pyrite, FeS,, has been decomposed by thermal desulfurization to recover only half the sulfur values. A process such as this, in which pyrite is converted to pyrrhotite (essentially FeS) and sulfur, is an established process and is documented in detail in A Comprehensive Treatise in Inorganic Chemistry, J. W. Mellor, volume XIV, page 213.
The use of water insoluble alkylamino polycarboxylic acid chelating agents for recovering sulfur from pyrrhotite was not known before this invention. It has been found that the ferrous iron in pyrrhotite complexes readily with the insoluble alkylamino polycarboxylic acid chelating agent in the process of the present invention, to form hydrogen sulfide, which is then converted to sulfur, and a soluble ferrous complex from which the insoluble chelating agent may be readily regenerated with sulfur dioxide for reuse. An added feature of this invention is that both the pyrite and pyrrhotite ores, and waste SO gases, which are used in the process of this invention generally are readily available where the invention is to be practiced, such as a copper smelter. Furthermore, because of the substantial total recovery of all of the sulfur in the pyrite ores and of the ancillary utilization of the smelter gas in the process of this invention, which would normally be exhausted to the atmosphere, the incidence of air pollution by this recovery process is reduced.
SUMMARY OF THE INVENTION The process of the present invention relates to the recovery of sulfur from pyrrhotite, which is essentially ferrous sulfide (FeS). The pyrrhotite used in the present process may be derived from the thermal desulfurization of pyrite (FeS or from pyrrhotite ore. The above desulfurization reaction may be conducted in a flying bed pyrite desulfurizing unit usually operating at a linear gas flow rate at 5 feet/second. The present process comprises the utilization of one or more of the following steps:
a. complexing the ferrous sulfide in aqueous medium with a water-insoluble alkylamino polycarboxylic acid chelating agent to form a solution containing the ferrous chelate of the acid, hydrogen sulfide (H 8) and a precipitate of concentrated nonferrous metals;
b. conversion of the evolved H 5 to sulfur by reaction with sulfur dioxide-containing gas (Claus reaction);
c. recovery of the chelating agent by treating the solution of ferrous chelate with an amount of an oxygen-free sulfur dioxide to form the chelating agent and a solution of ferrous bisulfite, under acidic conditions;
(I. Heating the ferrous bisulfite solution to produce sulfur dioxide (oxygen-free) which may be used in (c) above, and a precipitate of ferrous sulfite, and pyrolyzing the ferrous sulfite to produce additional oxygen-free sulfur dioxide and ferrous oxide.
DETAILED DESCRIPTION OF THE INVENTION The pyrrhotite product (FeS) from the thermal desulfun'zation of pyrite (FeS containing small quantities of nonferrous metals such as copper, molybdenum and silver, is digested in aqueous medium with an amount of a water insoluble alkylamino polycarboxylic acid chelating agent, to produce a LII soluble ferrous chelate, liberate hydrogen sulfide and precipitate the nonferrous metals. The amount of chelating agent is that required to react stoichiometrically with the ferrous sulfide in the solution. While more or less than a stoichiometric quantity of chelating agent may be used, it is not preferred. The chelating agent preferably is added incrementally for best results. This, to obtain complete solubility of the ferrous chelate, it is preferred to start with a slurry of the ferrous sulfide (pyrrhotite) in water; then the theoretical amount of chelating agent is added to produce a 5-8 percent suspension of the chelating agent and preferably 7 percent, with thorough mixing. The chelating agent dissolves only to the extent that it reacts with the pyrrhotite to form the soluble ferrous complex. The reaction may be demonstrated using EDTA as follows:
The ferrous iron in the ferrous chelate complex is sensitive to oxidation to the ferric state. This oxidation must be avoided because although the chelate may be regenerated from the ferrous complex with S0 as will be described in more detail below, it is not possible to regenerate the free chelate from the ferric complex by the action of For this reason, it is preferred to conduct the chelation step of this reaction in the absence of oxygen or an oxidizing agent to avoid any significant amount of oxidation. This chelating step may be conducted in the presence of a reducing agent, such as sodium hydrosulfite or sodium formaldehyde sulfoxylate, added intermittently during chelatingas required to maintain the iron in the ferrous state, as indicated by the discharge of the red color of the ferric compound.
The complexing of the insoluble pyrrhotite with the insoluble chelating agent may be conveniently conducted at temperatures above 20 C. up to the boiling point of the solution and preferably between 70 C. and the boiling point of the aqueous solution. It may be conducted at the boiling temperature with good yields. The reaction is carried out in a vessel having a capacity to accommodate the reactants and water necessary for suspending the reactants and for dissolving the ferrous chelate complex.
While subor superatmospheric pressures may be employed, the chelating step preferably is conducted at atmospheric pressures up to about 50 p.s.i.g., since this avoids the use of pressure-type equipment.
ble in this invention. Chelating agents such as ethylenediaminetetraacetic acid (EDTA ethylenediaminetetrapropionic acid (EDTP) and nitrilotn'acetic acid (NTA) are operable in this invention. EDTA because of its widespread availability, high acidity (high value acid dissociation constant) and high ferrous chelate stability constant (high value stability constant) is preferred.
Water soluble alkylamino polycarboxylic acid chelating agents such as N-hydroxyethylethylenediaminetriacetic acid (HEDTA) and ethylenediaminediproprionic acid (EDDP), because of their solubility, are not recoverable from aqueous solution by precipitation and are not desired in the operation of this invention. Although they do complex with ferrous iron and liberate H 5 from FeS, since they would not be recoverable for reuse the cost of the process would become prohibitive.
Other insoluble metal sulfides such as those of copper and molybdenum, CuS and M08 contained in the pyrrhotite are not reactive and do not dissolve in theaqueous solution of ferrous chelate. They are separated from the ferrous iron and concentrated in this step. Silver and gold may also be present in the residue as sulfides. These concentrated metal values are stockpiled for subsequent recovery by known methods of roasting, leaching and selective precipitation of the concentrated metals from the leach solutions. The concentration of these economically important metals which facilitates their recovery, is an ancillary advantage of this process.
The hydrogen sulfide liberated during the chelating step of the present inventive process is reacted with an SO -containing gas to produce elemental sulfur by the well-known Claus reaction, as described in the Encyclopedia of Chemical Technology, Kirk Othmer, volume 13, page 367. The reaction proceeds as follows:
The reaction is conducted in the presence of a catalyst, such as alumina, bauxite, quartz, and the like. The sulfur dioxide used in this reaction may be derived from substantially undiluted smelter gas from the combustion of pyrite, or from oxidative roasting of sulfide ores. If the smelter gas is allowed to become diluted with air or oxygen as it is collected from a copper smelter, it is rendered less useful as a source of sulfur dioxide in this reaction. Substantially undiluted smelter gas containing less than 1 to 2 percent air is operable in this step, the less dilute being preferred. Other sources of sulfur dioxide to produce additional elemental sulfur are available from subsequent reactions as indicated below.
The water-insoluble chelating agent is recovered from the ferrous chelate complex in substantially quantitative yields by treating the aqueous chelate solution, preferably at room temperature, with sulfur dioxide in an amount sufficient to maintain an acid medium having a pH of about 1.0 to 2.0 and preferably about 1.5. The chelating agent precipitates in substantially pure form in the shape of needles. Temperatures of about 50 C. or lower may be used, but room temperature is preferred. As the temperature is increased above room temperature, the solubility of the chelating agent increases and the solubility of S decreases with corresponding lower recoveries of chelating agent. Therefore, elevated temperatures above room temperature are not preferred.
in this reaction, as well, for best results, oxygen must be substantially excluded to prevent oxidation of the ferrous chelate to the ferric chelate. Overall, the reaction proceeds as follows:
recovered by heating the precipitated ferrous sulfite at about.
The solution, after separating off the ferrous sulfite, may be further treated with S0; to insure maximum precipitation of the chelating agent. After filtering off the additional insoluble regenerated chelating agent, if any, the filtrate may again be boiled to recover S0 and additional ferrous sulfite as before. This unique cyclic process of alternatively precipitating the metal sulfite and the complexing agent may be repeated to increase the accumulative recovery of chelating agent. The sulfur dioxide regenerated by decomposing ferrous bisulfite and from pyrolysis of ferrous sulfite, may be divided between the Claus reactor and the chelate regenerator. Additional sulfur dioxide, if needed, may be tapped from a source of substantially undiluted smelter gas.
The ferrous oxide residue from the pyrolysis of ferrous sulfite, may be used in metallurgical processes such as in the production of steel, pig iron and similar products.
As is seen from the above description, the process of this invention is self-contained. However, although substantially all of the chelating agent is recovered and reused, not all is recovered. Additional chelating agent must be added from time to time to make up for that which is not recovered and slight mechanical losses incurred as a consequence of repeated use.
The benefits derived from the process of this invention are many. Substantially all of the sulfur in the desulfurized pyrite is recovered under comparatively mild conditions. The expensive chelating agent is substantially all recovered from the ferrous complex and recycled, thereby rendering the process economically feasible. The sulfur dioxide used for regenerating the chelate is recoverable from the ferrous bisulfite product. Additionally, valuable metals such as copper, molybdenum and silver are concentrated in the residue remaining from the preparation of the ferrous chelate complex above. These residues may be collected and the concentrated metals recovered and separated by conventional known methods.
Referring to the attached chart depicting an overall embodiment using ethylenediaminetetraacetic acid (EDTA), pyrite is thermally desulfurized+l into ferrous sulfide 2 and sulfur 3. The sulfur is recovered and the sulfide is treated with EDTA to yield a soluble ferrous EDTA chelate 4 and hydrogen sulfide 5. The hydrogen sulfide is reacted with $0 under reaction conditions to yield additional sulfur 3. The ferrous EDTA chelate 4 is treated with an oxygen-free sulfur dioxide gas to precipitate regenerated EDTA 6 which is collected and recycled to step 2. The ferrous bisulfite solution 7 which forms, is boiled to yield sulfur dioxide 8 and a precipitate of ferrous sulfite 9. The ferrous sulfite 9 is collected and pyrolyzed to yield ferrous oxide 10 and additional sulfur dioxide 11. The sulfur dioxide products in 11 and 8 are collected for use in converting hydrogen sulfide 5 to sulfur or in regenerating the EDTA 4. Additional sulfur dioxide 13 must be provided to satisfy the total requirements for converting hydrogen sulfide to sulfur and regenerating EDTA.
The following example is intended to illustrate a specified embodiment utilizing the present invention and is not intended to limit the invention thereto.
EXAMPLE 2.2 parts of desulfurized pyrite containing 34.6 percent sulfur is added to a reaction vessel containing parts of water maintained at about 100 C. While stirring the mixture the stoichiometric amount (7.3 parts) of ethylenediaminetetraacetic acid (EDTA) is added. The hydrogen sulfide liberated during the complexing of ferrous iron with EDTA amounts is 0.78 parts in 2 hours. This hydrogen sulfide product is reacted with the sulfur dioxide in undiluted smelter gas at 250 C. in the Claus reaction to produce elemental sulfur. The reaction mixture is then filtered to collect 0.11 parts of residual solid containing concentrated metal values such as copper, molybdenum, etc. This residual solid from each run is stockpiled for subsequent extraction of the metal values. The filtrate containing the ferrous EDTA is then treated with sufficient oxygen-free sulfur dioxide in an agitated vessel at 29 C. for 4 hours to regenerate the bulk of the EDTA. The pH of the solution maintains at about L5 during the reaction. The EDTA precipitated amounts to 7 parts after drying.
The filtrate after filtering off the insoluble EDTA is boiled for about 10 minutes yielding a precipitate of ferrous sulfite and additional sulfur dioxide for recycle.
By this procedure 97.2 percent of EDTA is recovered. Also from the estimated sulfur content of the pyrite, over 99 percent sulfur in pyrite is recovered.
Having thus described our invention, we claim:
1. A process for separating sulfur from a ferrous sulfide ore which comprises reacting said ferrous sulfide in aqueous medium with an amount of a water-insoluble alkylamino polycarboxylic acid chelating agent sufficient to effect formation of a water soluble ferrous chelate of said agent and hydrogen sulfide.
2. The process of claim 1 wherein said reaction is effected at a temperature of about 20 C. to the boiling point of the aqueous reaction mixture.
3. The process of claim 1 wherein the chelating agent contains about up to 4 carbon atoms in the alkyl moiety.
4. The process of claim 1 wherein the chelating agent contains about up to 4 carbon atoms in the polycarboxylic acid moiety.
5. The process of claim 1 wherein the chelating agent is ethyenediaminetetraacetic acid.
6. The process of claim 1 wherein the chelating agent is nitrilotriacetic acid.
7. The process of claim 1 wherein the hydrogen sulfide product is reacted with sulfur dioxide under conditions sufficient to effect production of elemental sulfur.
8. A method of processing a ferrous sulfide ore which comprises the steps of:
a. reacting said ferrous sulfide in aqueous medium with an amount of a water-insoluble alkylamino polycarboxylic acid chelating agent sufficient to effect formation of a water soluble ferrous chelate and byproduct hydrogen sulfide; reacting said ferrous chelate solution with a substantially oxygen-free, sulfur dioxide containing medium at a pH of about 1 to 2 and in an amount sufficient to regenerate said water-insoluble alkylamino polycarboxylic chelating agent and form an aqueous solution of ferrous bisulfite; and
c. separating said chelating agent from the bisulfite solution.
9. The process of claim 8 wherein the aqueous solution of ferrous bisulfite from step (c) is heated to a temperature sufficient to produce sulfur dioxide and ferrous sulfite and the ferrous sulfite is heated at a temperature sufficient to desulfurize said ferrous sulfite to produce ferrous oxide and sulfur dioxide.
10. The process of claim 9 wherein the sulfur dioxide formed is reacted with hydrogen sulfide under conditions sufficient to effect production of elemental sulfur.
11. The process of claim 9' wherein the sulfur dioxide formed is used to regenerate the alkylamino polycarboxylic chelating agent from the ferrous complex.
12. The process of claim 8 wherein the regenerated insoluble alkylamino polycarboxylic chelating agent separated in step (c) is recycled to step (a) for reaction with ferrous sulfide.
13. A process for recovering a water-insoluble alkylamino polycarboxylic acid from an aqueous solution of the soluble ferrous chelate of said acid which comprises reacting said ferrous chelate solution with a substantially oxygen-free sulfur dioxide at a pH of about 1 to 2 and in an amount of said sulfur dioxide sufficient to effect conversion of the ferrous chelate to the insoluble free acid and ferrous bisulfite in solution and recovering said insoluble acid from said solution.
14. A process as in claim 13 wherein the ferrous bisulfite solution is heated to release sulfur dioxide and precipitate ferrous sulfite and collecting the sulfur dioxide and ferrous sulfite therefrom.
15. A process as in claim 14 wherein further recovery of water-insoluble chelating agent from the resulting solution after removal of the ferrous sulfite, is attained by repeating the cycle of treating said solution with sulfur dioxide and collecting the precipitated chelating agent therefrom.

domain: chemistry


text:
5 edition of Bold of heart found in the catalog.
|Statement||by Helen Elmira Waite, illustrated by Jean MacPherson.|
|LC Classifications||PZ7.W132 Bo|
|The Physical Object|
|Pagination||250 p. incl. plates, facsim.|
|Number of Pages||250|
|LC Control Number||40032988|
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Written off the cuff with one finger in the center of the cosmos, Heart of Bold is part memoir, part soliloquy, marking the turnings of the authors life through the prism of a kaleidoscopic pen. Originally created in blog format, this unique compilation charts the life of Author: Sophie Ward Koren.
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