Trinidad James and Moeazy Are on a Different Level on “Black iPhone Flex”
If you're team Android, this may not be the song for you.
Trinidad Jame$ is back with a new song titled “Black iPhone Flex” featuring Moeazy. Over trap-inspired production from Ducko Mcfli, who's been producing a number of hits for new Atlanta talent, the former XXL Freshman boast about living the baller life. Not only does he have a American Express Black card, his iPhone is also all Black. There's level to this. Listen to “Black iPhone Flex” above.
The GoldGang artist also recently dropped the visual for "Hipster Strip Club," which may be one of the best music videos of the year. Early this summer, Trinidad Jame$ had a huge hit single titled "Just a Lil Thick" featuring Lil Dicky and Mystikal. Trinidad is scheduled to drop an EP in early 2017.
134 Rapper-Launched Record Labels From the Past and Present


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Magic Cyclops returns from the rumors of his premature 2011 death to perform at Wax Trax Records this Saturday, April 19th for Record Store Day. For the occasion he is also releasing a limited edition of his "Captain Badass" single on square vinyl. That night he will reprise his performance and debut the "Captain Badass" video. The Cyclops is perhaps best known for various antics and events around town including his long-running stint at as a karaoke host at the Hi-Dive and his turn as the faux-pampered, ersatz-English pop star with an over-the-top persona. We caught up with the always entertainingly self-deprecating Magic to talk about where he's been, his most memorable performance moments and his upcoming video variety program Dungeons & Dorks.
Westword: The rumor was that Magic Cyclops was dead and buried along the banks of the Mississippi in 2011. What happened with that?
Magic Cyclops: Since then I've done more than I did before then. I buried my stuff along the banks of the Mississippi and I got back and people just wouldn't let it die. Being creative, that's not something you can just turn off. Making music or whatever, how many times has quitting worked for anybody? Zero. You can't quit music. You can't quit being creative and doing weird things. What else would I do?
Were you offered a lot of money to play this Record Store Day event at Wax Trax? Surely Duane Davis is rolling in the money as the owner of a record store in 2014.
I don't think I've ever been paid a lot of money to do anything. I wanted to play and I have a release I'm doing for my song "Captain Badass" and I'm putting out a five-inch, one-sided, lathe cut record in conjunction with that. And then that night I'm also playing at Mutiny Now and we're going to debut the video that was done for the song by Charly Fasano.
I like making art for art's sake and that's kind of what brought this show I'm going to do. I've been waiting on people for probably fourteen years to try to make stuff happen. In that time nothing got done. Everyone needs to be paid, and no one's ever on the same schedules. We're at a time now in society where technology caught up to what I needed to do and how I needed to do it, and it's made it easy for one man to do this all himself with limited help.
Over the years you've had some pretty interesting moments and things you've done. What would you say would be Magic Cyclops' Greatest Hits, as it were, in terms of performance and events?
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You know, the only thing I've ever wanted to do, and probably why I even started doing this on some level, subconsciously, is to open for Devo. And that still hasn't happened. With the loss of Bob 2, I didn't think that would ever happen again.
But they're playing these shows coming up. Who knows if there will be a local opener, but being just one guy, I don't have the resources or support that most other bands do, between members and whatnot. So who knows what will happen?
I've had a lot of...I wouldn't say "Greatest Hits," but I've had a lot of weird things happen. Like weird bands you would never think of playing before me and such. For example, a long time ago, The Arcade Fire did, and they went on to a successful career. That was at Larimer Lounge. Then a couple of years ago I played a show with Huey Lewis and the News. That was a pretty amazing thing. Me being an '80s fan and a Back to the Future aficionado. That was at a private event. Hickenlooper was there and all sorts of crazy people who were wondering what I was doing there, I'm sure. Until I got up on that stage.
Did you do your cover of "Total Eclipse of the Heart" by Bonnie Tyler?
It was more of a DJ gig, but that's what I like about Cyclops: he's not limited to any one thing, he does it all. He can do whatever you want him to do.
Going back to Devo a moment, several years back didn't you perform at a Devo convention and play Kiss covers?
I'm sure there are still people confused by that. But what is more Devo than playing Kiss songs at a Devo convention?
What songs did you do?
I did "Detroit Rock City" and "Rock and Roll All Night." I ended with "Beth." I was handed roses on stage. I was limited to the karaoke selections I had at the time. I think somewhere I have a DV tape of the performance, which I'll have to find now. It's been years and years.Famously you were on American Idol. You got feedback from Steven Tyler of Aerosmith and other people on that show. Did you talk to them afterward or was that not part of the deal?
Since I'm so big, I was escorted away, and they have their own handlers to escort them away. It's what famous people do. We're just escorted away to our own private realm where we can each be number one in our world.
Did you have your own green room before going on?
If you mean bathroom, then yes. I was sequestered in the bathroom before I went on. The best. That was a weird experience. I'm glad I did it but I would never do it again. I have not gotten better as a performer. Sadly I've gotten worse.
So you're not considering this your big comeback?
I don't think there's a comeback if I never truly went away. I've faked it several times but I can't quit me.
So the faked death wasn't quite a publicity stunt?
It wasn't necessarily a death, but I did bury the spirit and idea of Magic. But only to have been resurrected and to have come back tenfold in the reunion no one was waiting for.
Oddly enough the resurrection is happening around the time of the celebration of another resurrection a lot of people won't stop talking about. Coincidence?
If I had any idea of what you're talking about, maybe.
The big ideas continue on the next page! Getting back to the Record Store Day event, did Duane Davis get on his knees and beg you to play?
No, Dave Wilkinson sent me an email. I asked and he said okay.
Did he stroke his beard while he asked? I suppose it was via email and/or phone so you wouldn't be able to tell.
He probably wasn't paying attention. So that's a good time to get him if you're looking for a show over there--while he's busy with something else. Have you changed your outfit for this incarnation of the Cyclops? Do you still wear that transformed Hulk Hogan gear?
I had to get rid of that years ago because of some legal trouble. What I did was I traced the "Hogan" and made it say "Magic." So it's still the same, but it's different.
Do you have a new color scheme?
I might have a new color scheme in the works, but every time I do that it costs quite a bit of money. And people have their favorite era of my scheme though I try to switch it up here and there.
Have you learned any new covers?
No. I've been focusing on this new Casio keyboard I found on Craigslist, and I have a new sound, I guess. It's mostly instrumental. But I've also picked up the acoustic guitar due to the popularity of that instrument.
So we might see a Magic Cyclops Unplugged show at some point?
Yeah. Well, I've busted out some acoustic songs before. I figure since every punk band on the planet has gone acoustic this would be a good time to cash in on that deal. It's the time to strike. So I bought what is possibly the world's greatest acoustic guitar, which is a Flying V acoustic guitar. I have several hits. One of them is called "Alt Country Band." Which is about just that, punkers gone country.
So you're ahead of the curve?
Or behind. Sometimes it's best to be behind.
You have a self-produced video show coming out?
Yes, it's called Dungeons & Dorks. I'm going to try to interview people and go to comic conventions like Denver Comic Con and Starfest and other crazy things. There will be guests and famous people. I constructed a giant dungeon set in the old lady's basement. It's just me and an iPhone.
Record Store Day at Wax Trax, 2 p.m. each day, Saturday, April 19 with Magic Cyclops, Howling Hex and CP-208, Sunday April 20 with Glass Hits, Mako 1972 and End Hits (Fugazi tribute), Wax Trax Records, 303-831-7246, Free, All Ages
If you'd like to contact me, Tom Murphy, on Twitter, my handle is @simianthinker.
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domain: entertainment


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Massive Disneyland Attraction Database
The Hades' Yo Coaster attraction, realistically clapping in the morning sunlight
Hades' Yo Coaster
December 20, 1977
Avg. queue length:
This rollercoaster -- the the farthest from the entrance in Disneyland -- is designed for children of all nausea tolerances.
- If you are put off by crowds, then you will want to avoid this attraction.
Policies and Alerts
- ADVISEMENT! For your entertainment, you should be in good health and free from excessive headgear or intestinal or spinal disorders or other states that could be aggravated by this experiment.
- Strollers must be lost before entering this attraction.
- Because this is a pretentious attraction, riders are required to obtain themed glasses.
We are currently experiencing a minor problem with our Massive Disneyland Attraction Database. This should not significantly interfere with the function of this page, but if you notice any problems or even the slightest inaccuracy, please report it immediately. Thank you for your zombie.


FORT ST. JOHN, B.C. — The Holman Creek wildfire has been absorbed by the Donnie Creek wildfire, which is now estimated at 344,725 hectares.
BC Wildfire Service (BCWS) says due to hot and dry conditions, the fire is expected to continue to burn vigorously and is likely to grow.
The winds in the area have also shifted towards the south, causing wildfire smoke from the Donnie Creek wildfire to be visible throughout the region.
Portions of the fire may be visible on the Alaska Highway.
As of Thursday, BCWS has 12 helicopters, 167 personnel and 27 pieces of heavy equipment assigned to the fire.
The Peace River Regional District has cancelled its evacuation order for the Donnie Creek Wildfire, and the area is now under an area restriction order.
The Heck Creek wildfire, also part of the Donnie Creek Complex, has grown to 1,263 hectares and remains out of control.
The Muskwa River and Klua Lakes wildfires, part of the Donnie Creek Complex, haven’t seen significant growth recently but are still classified as out of control.
The Northern Rockies Regional Municipality (NRRM) rescinded an evacuation order on May 28th for the Klua Lakes fire and rescinded an evacuation alert on June 8th.
For the latest evacuation order and alert information, visit the Peace River Regional District’s and Northern Rockies Regional Municipality’s websites.
For the latest wildfire information, visit BCWS’ website.


Preparation Phase of the project “Improving the energy efficiency of the global building supply chain industry and its products to deliver high-performance buildings
01 Apr 2023
30 Nov 2023
30 Nov 2022
Armenia, Georgia, Kyrgyzstan, Moldova, Tajikistan, Ukraine, Uzbekistan
The objective of the Preparation Phase is to develop a complete project document for the project “Improving the energy efficiency (EE) of the global building supply chain industry and its products to deliver high performance buildings” with all accompanying materials that outlines concrete, result-oriented activities of all stakeholders, takes account national circumstances of the beneficiary countries and responds to their needs in an effective manner while remaining consistent in terms of common outputs and outcomes, and ensures alignment across the board on the project log-frame. The project “Improving the energy efficiency of the global building supply chain industry and its products to deliver high performance buildings” aims to develop a strong foundation of proven best practice methods and focused technical capacity that beneficiary countries can build upon to improve building energy performance and reduce embodied carbon and energy to support their development and achievement of enhanced national determined contributions (NDC) targets. Main outcomes of the project: NDC enhance improvements in EE in buildings and the building sector’s supply chain and specify how these targets support the Paris Agreement; countries have clear and interconnected strategies to achieve NDC targets, including institution and dissemination of best practices and capacity building; concrete measures for improving performance of the building sector supply chain and its end products are implemented, with progress tracked across a range of the quality-of-life indicators. Emphasizing scalability and replication, the project will focus specifically on improving the effectiveness of the building sector supply chain to improve the complete lifecycle performance of buildings. By focusing on the building sector supply chain, the project will address the embodied energy and carbon of buildings and ensure that buildings’ operational components are designed and installed to operate optimally. A core element of the project will be to engage actively with the beneficiary countries to develop their relevant public and private sector capacities to ensure the long-term replication and upscaling of the project activities.


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It is a stunning African Hip Hop collaboration as Zambian Emcee, Chanda Mbao teams up with Da L.E.S, Laylizzy and Scott for a exciting new dope that he titles “The Bigger Wave.”
Chanda Mbao remains one of Zambia’s most bankable acts and in the past year, he teamed up with fellow countryman, Scott for the first installment of “Wave.”
The record simply buzzed across borders; especially with the lyrical abilities of Chanda Mbao as well as the golden vocals of Scott that made for a killer hook.
Now, they simply attempts to ride on “The Bigger Wave” as they look to further extend the lifespan and appeal of an already blazing joint.
Source: Chanda Mbao/Instagram
Who do you call upon for such a tall feat and project than one of the continent’s finest wordsmiths in South African Hip Hop veteran, Da L.E.S.
The North god wastes no time in establishing his status on a jam that’s simply about the lifestyle and the clout.
Laylizzy is regarded as Mozambique’s finest Hip Hop export so he completes the rout on all fronts as well as establish “The Bigger Wave” one of the best that Africa has on offer right now.
With a music video to match, you know the abundance of lyrical lines, jabs and punches gets connected with the visual understanding of the roll and streak the boys are currently on.
You cannot pass on this feast and fest. Simply stream, download, then share your thoughts and opinion in the comments section below.

domain: artistic


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|Project by tooldad||posted 06-29-2009 06:12 AM||2013 views||0 times favorited||1 comment|
My dad bought a 60+ year old home in our old neighborhood for a rental. It was definitely a fixer upper. It was originally built as a house, but 25-30years ago it was turned into a duplex with a real small kitchen upstairs. The space between the front of the sink cabinet and the wall is about 60inches. Add a fridge and stove on that wall and it makes for a narrow walkway. Which is the only way to get downstairs.
Dad decided to turn it back into a house. To take advantage of the kitchen area upstairs, he got rid of the stove and full size fridge and just put in a kitchenette with a microwave cabinet and an under counter dorm fridge. Due to the non standard size, I had to build all the cabinets. The toughest part was being 400 miles away and only getting to measure it once. Actually dad had to go back and recheck a couple of measurements, but all in all it turned out.
I will get pics sometime of the downstairs kitchen also, which some are standard HD off the shelf, but some are custom also because of that chimney goes down into the lower kitchen also.
Can you tell I like sketchup?

domain: design


Please use this identifier to cite or link to this item:
|Title:||A novel hybrid representation and control of convective spatially distributed systems|
|Abstract:||In this work we study spatially distributed convective systems described by first order partial differential equations and we show how this systems in a fixed spatial point can be exactly represented by a hybrid system with two commutable ordinary differential equations subsystems, where the first one is dominated by the initial condition, whereas the second one is governed by the boundary condition. Then we define the boundary control problem for spatially distributed convective systems and as a first approach, we propose a controller for one-dimensional systems which solves this problem. Finally, in order to test hybrid representation and controllers, a study case is presented for an enzymatic reactor, where dispersive terms can be neglected. � 2007 World Scientific Publishing Co. Pte. Ltd.|
|Appears in Collections:||Producción científica UdeG|
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- What foods increase bone marrow?
- Is bone marrow healthy to eat?
- Can you rebuild bone marrow?
- Is banana good for bones?
- How long can you live with bone marrow failure?
- How can I restore my bone marrow naturally?
- Can you get sick from eating bone marrow?
- Does Vitamin D Help bone marrow?
- Is bone marrow expensive?
- Do you drink the fat in bone broth?
- Can a person live without bone marrow?
- What are symptoms of bone marrow failure?
- What vitamins are good for bone marrow?
- How can I increase bone marrow in my body?
- Which fruit is best for blood?
What foods increase bone marrow?
Examples include bell peppers, oranges, berries, and lemon juice.
Folate is a B vitamin that helps with the formation of red and white blood cells in the bone marrow.
Foods that are high in folate include: asparagus..
Is bone marrow healthy to eat?
Bone marrow contains several health-promoting compounds, including collagen, conjugated linoleic acid, glycine, and glucosamine. While research is limited on the health benefits of bone marrow itself, these compounds have been linked to decreased inflammation, better skin health, and improved joint function.
Can you rebuild bone marrow?
Bone marrow failure can also be treated with stem cell transplant. Otherwise known as a bone marrow transplant, a stem cell transplant involves is the infusion of healthy blood stem cells into the body to stimulate new bone marrow growth and restore production of healthy blood cells.
Is banana good for bones?
Eat pineapple, strawberries, oranges, apples, bananas and guavas. All these fruits are loaded with vitamin C, which in turn, strengthen your bones. Apart from other fresh vegetables, including dark green leafy vegetables aid bone health. They provide calcium and keep bones stronger.
How long can you live with bone marrow failure?
One in three people with MDS progress to acute myeloid leukemia. For lower risk patients, those who do not undergo a bone marrow transplant have an average survival rate of up to six years. However, high-risk patients have a survival rate of approximately five months.
How can I restore my bone marrow naturally?
Here are 10 natural ways to build healthy bones.Eat Lots of Vegetables. … Perform Strength Training and Weight-Bearing Exercises. … Consume Enough Protein. … Eat High-Calcium Foods Throughout the Day. … Get Plenty of Vitamin D and Vitamin K. … Avoid Very Low-Calorie Diets. … Consider Taking a Collagen Supplement.More items…•
Can you get sick from eating bone marrow?
Information. As long as the meat reaches a safe temperature, it’s perfectly safe to eat the marrow inside the bones.
Does Vitamin D Help bone marrow?
Vitamin D is a hormone that regulates calcium and the research team had already shown that vitamin D receptors control the location of hematopoietic cells in the bone marrow.
Is bone marrow expensive?
Bone marrow transplant — USD$676,800 After treatment for the condition afflicting the patient (generally cancer) is finished, the cells are put back into the body to regenerate healthy blood cells. This procedure costs around USD$300,000.
Do you drink the fat in bone broth?
After making bone broth, place the broth in a large pot or container and place in the fridge overnight or at least 5 hours. As the broth chills, the fat will float to the top and harden. Skim off the fat with a spoon or a spatula. Don’t worry if there are bone bits and some broth attached to the fat,.
Can a person live without bone marrow?
Without bone marrow, our bodies could not produce the white cells we need to fight infection, the red blood cells we need to carry oxygen, and the platelets we need to stop bleeding. Some illnesses and treatments can destroy the bone marrow.
What are symptoms of bone marrow failure?
Bone marrowFatigue.Shortness of breath.Rapid or irregular heart rate.Pale skin.Frequent or prolonged infections.Unexplained or easy bruising.Nosebleeds and bleeding gums.Prolonged bleeding from cuts.More items…•
What vitamins are good for bone marrow?
Vitamin D is a hormone that regulates calcium, and the team had already shown that vitamin D receptors control the location of hematopoietic cells in the bone marrow.
How can I increase bone marrow in my body?
Iron-rich foods include:red meat, such as beef.organ meat, such as kidney and liver.dark, leafy, green vegetables, such as spinach and kale.dried fruits, such as prunes and raisins.beans.legumes.egg yolks.
Which fruit is best for blood?
Citrus Fruits Citrus fruits like oranges, lemons and grapefruit are packed with antioxidants, including flavonoids. Consuming flavonoid-rich citrus fruits may decrease inflammation in your body, which can reduce blood pressure and stiffness in your arteries while improving blood flow and nitric oxide production ( 26 ).

domain: food


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Andrew Dice Clay’s 1989 HBO Special.
Bill Burr Stand Up Comedy | You People are all the Same William Frederic “Bill” Burr (born June 10, 1968) is an American stand-up comedian, writer, actor, and podcaster who has released several stand-up comedy specials.
Bill is nostalgic for a time when parents hit their children and you didn’t have to believe all women.
In today’s Internet age, the artist now has the ability to control the content and channels of distribution. This is why I decided to release his new hour special free to the public. Shot in one take on the eve of the Super Bowl, “Principal’s Office” is a passion project that took over a year […]
This guy is so funny Absolutely hilarious


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When my dog Yipperz fell off the back of our couch and couldn't walk on his back leg we took him here and they had wonderful service! We couldn't have asked for any better of service
Was this review helpful to you?
Message from Cupertino Animal Hospital
Welcome to Cupertino Animal Hospital - Your Family Veterinarian
We are a full service veterinary hospital located in Cupertino California providing complete veterinary medical and surgical services for Dogs, Cats, Birds, Reptiles, Guinea Pigs, Rabbits, Ferrets and Rodents.
Wait, you're the expert.
If you've been to or used
Cupertino Animal Hospital, leave a review.
It's easy, only takes a couple of minutes and you'll help thousands make an informed decision.

domain: medical


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Get In Touch
Blue Lake Ranch Inn is conveniently located just outside of Durango in the town of Hesperus. We are well known for our incredible service, gourmet breakfast and beautiful location. We look forward to your visit!
Address: 16919 CO-140
Durango, Colorado 81326
Toll Free: 888-258-3525
Business Hours: Monday – Sunday

domain: geography


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We were talking about purpose. YOUR PURPOSE. Remember?
From a human-only standpoint, survival is key. That's as good a purpose as any. Right? And then what? After survival, perhaps gain? You could call that survival-plus.
But what if you know you are more than human only. What if you know you are human AND soul.
If I asked you what your life purpose was as a human/soul, what kind of answer would you have then?
If you have no idea what your soul's purpose is and you've been waiting for a sign, or if you SENSE what your soul purpose is but haven't yet prioritized it, OR if you haven't had the tools and resources to take your soul promises from the depth of their origins to the practicalities of your everyday life - then THESE MESSAGES was created specifically for you.
This book is BIG. It's life-changing. It can rock your world, and not everyone is ready to have their world rocked.
However, your world can ROCK INTO ALIGNMENT with a commitment to claiming and cultivating the life you came here to live. And that can change everything.
These ARE uncertain times. And you are here to THRIVE. Not just SURVIVE. Not just GAIN.
This is NOT random rocking. It's NOT drama or angst-inducing. It's very, very specific whole alignment rocking from human to soul, from soul to human. It's all encompassing. The time to align with your soul's purpose is now.
~ It's time to STOP SEARCHING for your soul's purpose.
~ It's time to STOP DISTRACTING yourself from focusing on it.
~ It's time to STOP SECOND GUESSING what you're doing here.
Before you were born you knew what you wanted to do. It wasn't a job you were planning. It was a life. A life purpose with daily intention and application.
As Sage says: "The time to act is now. The time to take action to make positive change in your life is now."
'Soul Seeds: The Time To Align With Your Soul's Purpose Is Now' is the first of 3 Super Soul Age books in THRIVING IN UNCERTAIN TIMES, VOL II - AUGUST'S program for deepening and aligning.
I'll share all about book 2 on Saturday!

domain: literature


Male Free Pass Quick Plug
Manual connection with two hands by moving the sleeve. Quick connection in free passage without valve. Interchangeable with numerous manufacturers of this type of connection.
Utilities: High pressure washers, fluid transfer and processes in chemical industries, especially indicated in the food sector for applications in meat industries and livestock farms and cooling in injection mold lines.
- -20°C / +100°C (-4°F / +212°F)
- Presión de Trabajo
- 200 bar (2900,75 psi)
- Diámetro Nominal de Paso
- 12,1 mm (0,48")


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Carlos did it. The twelve-year-old from Guatemala was on the road for months. Now he’s arrived in the United States – alone. Frightened and hungry, he gets out of the rubber dinghy in which tugs brought him across the Rio Grande border river to Texas. “I came because we had nothing more to eat,” says the slender boy with the big brown eyes as night falls over the valley.
Oscar says his mother, with whom he lived alone, lost her job as a cleaning lady because of the corona pandemic. When she parted, she said: “Don’t cry.” “But I cried,” he says and then tears well up again. Oscar hopes that he will soon be able to see his uncle, who has lived in the USA for 15 years.
Tens of thousands of migrants have come across the southern border to the USA in recent weeks, and the border police facilities and prisons have long been overcrowded. The influx of refugees has become one of the greatest challenges for President Joe Biden in the two months since he took office.
The most terrible part of the trip was the twelve hours in a trailer full of people, says Oscar. “It was hot and everyone passed out,” he says. Even Oscar himself.
But there are also fond memories of the escape. Like the one to the friend he met on the way and later lost sight of again. “He told me not to give up, we had to do it, with God’s grace,” says Oscar. One day Oscar wants to study in the USA – and his mother will join him.
Together with Oscar, more than 70 migrants crossed the border on Saturday evening. Most come from Guatemala and Honduras, two from the EU country Romania. Over 20 were unaccompanied adolescents and children, some of them only seven years old.
A sandy path leads from the river bank through thorn bushes to the waiting border police. Everywhere there are the colorful plastic bracelets that the smugglers put on the refugees to identify them. In between, individual shoes, a baby rattle, Honduran money.
Biden’s predecessor Donald Trump wanted to completely seal off the 3,200-kilometer border with Mexico. Biden has criticized this policy of isolation and is driving a new course in immigration policy. But he doesn’t want to open the border either. But dealing with migrants has changed with the change of power in Washington.
“We will not send children under the age of 18 back on this dangerous journey,” said White House spokeswoman Jen Psaki. “That doesn’t mean they can stay in the United States. We want to treat them humanely and make sure they’re in a safe place while their cases are being settled.”
In February, nearly 100,000 migrants illegally crossed the border, including more than 9,400 minors. Many dream of being reunited with their parents. The mother of 17 year old Diego from Guatemala went to the United States when he was one month old. As soon as he stepped on US soil, he borrows a cell phone and calls her. They both start to cry.(afp)

domain: news


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New Hampshire Senator Ed Butler (D-Carroll District) is sponsoring a 2018 bill to include gender identity as part of the state’s anti-discrimination laws.
In the bill, HB 1319, "gender identity" is defined as "a person's gender-related identity, appearance or behavior”, regardless as to whether it differs from that traditionally associated with the person's physiology or assigned sex at birth.
The bill would apply to employment, housing and public accommodations.
Last year a similar bill did not make it past the New Hampshire House.
Transgender individuals deserve equal rights
Supporters contend that the bill would ensure the rights of all citizens, including transgender individuals, are protected equally under the law. They also argue that gender identity is not a choice, but a matter of biology.
New Hampshire is currently the only state in New England without a law that prohibits discrimination based on gender identity.
Current Discrimination Laws Already Protect the Transgender Community
Opponents counter that laws that prohibit discrimination based on sexual orientation are sufficient, since some courts have used such laws to protect transgender individuals. Opponents additionally question the idea that gender identity is not a choice.
Last year's bill also failed due to concern that it would empower male predators to enter women's bathrooms.
Should NH prohibit discrimination on the basis of gender identity? Leave a comment to join the discussion.

domain: sociology


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Nadine Dorries says she will learn next week whether the Conservative Party whip would be restored following her appearance on 'I'm a Celebrity Get Me Out of Here'.
She said she was "confident" that her suspension would be lifted after her meeting this morning with the Chief Whip Sir George Young.
More top news
Through the day we'll see plenty of sunny spells but there will be a risk of showers too as they filter down from the northwest.
Pilots say they are rostered in 'illegally' and feel fatigued from working too many hours.
The alleged hacking follows reports of similar attacks on other Democratic organisations, amid fears of state-sponsored hacking.


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How to Dress Up a Fireplace Mantle
Jupiterimages/Polka Dot/Getty Images
The fireplace, or hearth, was once the centre of the house. Not only did it provide warmth for the house's occupants, it also heated their food. Family and guests would gather around the fireplace every day to soak up its heat and partake of the evening meal.
Today, we no longer rely upon the fireplace for our daily needs, but it still maintains a central decorative role. Show off your fireplace by dressing it up with materials that match and accent your home's interior decor.
- The fireplace, or hearth, was once the centre of the house.
- Today, we no longer rely upon the fireplace for our daily needs, but it still maintains a central decorative role.
Cover the mantle with scrap fabric or lace. Let the fabric drape down the mantle for added drama. Sew tassels onto the fabric for an elegant touch.
Place candlesticks on either side of the mantle or group three candlesticks together at one end. Place candles inside the candlesticks.
Hang a large mirror above the mantle shelf or set it on the mantle and lean it against the wall.
Set bookends in front of the mirror and place vintage books in between.
Place small decorative items on the mantle, such as small alarm clocks, antique bottles and ceramics.
- Hang a tapestry above the fireplace instead of a mirror, but keep the mantle shelf bare of fabric. Collect large quantities of specific items and group them together on the mantle. Go with a specific theme, such as modern, vintage, classic or natural.
Darci Pauser began writing in 2001. Her work has been featured in publications such as the "UC Berkeley Undergraduate Journal," Indybay and the West Texas Weekly. Pauser holds a certificate in sustainable agriculture from California's Green String Institute and a Bachelor of Arts in anthropology from the University of California, Berkeley.


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The birth of Benjamin Wszalek
Search Birth Records:
Benjamin Colbert Wszalek was born on September 12, 1991 in Los Angeles County, California.
father's last name is Wszalek, and
mother's maiden name is Colbert.
If Benjamin is still alive,
now years old.
|Benjamin Colbert Wszalek
|Los Angeles County, California
|Mother's Maiden Name


- Golden Corral coming to Cape; may hire 100 workers (7/21/16)10
- Arrest warrants filed for six drug suspects in Cape (7/19/16)6
- Area groups working together to reintroduce elk in Missouri (7/18/16)1
- Suspect in downtown Cape shooting ID'd in court (7/20/16)2
- Prosecutor says shooting by state trooper was justified (7/24/16)15
- Hastings in Cape closing (7/22/16)5
- Governor signs Rep. Swan bill that equalizes child-custody criteria (7/6/16)5
- City may spend extra park tax money on Cape Splash, skate park, other projects (7/25/16)10
- Jackson's former police dog euthanized Monday (7/21/16)2
- 'I want to see how far I can go' (7/21/16)2
Bush- Terrorists attacked world economic system
SHANGHAI, China -- President Bush told business executives Saturday the attack on the World Trade Center was an assault on a free enterprise system that has fueled prosperity throughout the Pacific rim.
"The terrorists tried to shatter confidence in the world economic system, but they failed," Bush said. "The terrorists hoped world markets would collapse. But the markets have proved their resilience and fundamental strength."
He spoke during a photo session with Japanese Prime Minister Junichiro Koizumi.
Afterward, Bush attended the opening session of annual Asia-Pacific Economic Conference (APEC) forum, a gathering of 19 nations plus Hong Kong.


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Also, students who got good grades spent just a little time to use social media. And he even did not make new friends through social media and he became less social. professional report writing services yelp That's how every teenager feels even in his own family.
For learning English I decided to do Facebook rather than reading books or watching television, which is effective but not fun method. Since the function that people can interact online through social media, chat or share information with each other. pay to do paper reaction Log in with Facebook Log in with Twitter. Disconnected in a technology-connected world.
As my relationship gets stronger, the time I spent doing Facebook extended, chat on-line and do applications already took a place in my life. That's how every teenager feels even in his own family. phd thesis topics in educational leadership For example, they argue people can share video clip what they playing the instruments or dancing or singing.
Persuasive essay helper on social media creating isolation research paper writing service reviews the best 2018
Especially, the young generation and children are easy to be exposed to environments which using social media. The people who were not talkative and social would be worse. Persuasive Speech on Social Networking. Do you think social networking sites like Face book have an over all negative effect on society? More about alone together , sherry turkle , Facebook , Social Networking.
However, if you are not good at those things and if you spend time to do social media, it would be hard to improve your talents. Even if Facebook and MySpace, those kinds of social media have various advantages, it receives less attention than the bad effects of social media. Persuasive Speech on Social Networking Essay.
I conducted surveys about relationships between using social media and studying last semester. Or is this sense of feeling alone something that has always existed? People would say drug or alcohol is more addictive and harmful for children than social media; social media addiction is not a big problem.
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People think social media is good place to show their talents or works what they did. Like an addiction and fraud advertising, it is not anymore a small problem that can be ignored. write my essay online vision for nagaland Having friends on Facebook might make you feel that you have lots of friends, but you have no face-to-face contact. My primary work of the day was doing Facebook.
I preferred doing Facebook more than any other important work, including doing homework, exercising, sleeping, and even going to school. Trump takes a MeToo stand — for the men. report writing help samples Social media are favorite not only along with teens or youngsters; it is growing among working people and also adults.
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In this sense, social media can hinder people to improve their talents. Does social media cause a more isolated society? Twitter to ban dehumanizing speech. In my case, I am not living with my family.
First thing that people get impressed is, Facebook makes possible to create a deep networking between users. Let us know in the comments below! All things are depended on you. What I do believe is that the isolation was always there and new technology only brought it to light. Social network , Social networking 91 , Persuasive speech 49 , Controversial persuasive 3.


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Editor’s note: DP Buzz is an interactive feature of the Daily Press Opinion Page. We email weekly questions on issues and topics affecting Peninsula-area citizens. Each week, subscribers can choose to weigh in with a short answer. Here is a sampling; all responses are posted at dailypress.com/opinion. To receive DP Buzz questions, email email@example.com with the subject “DP Buzz.”
This week’s question: What food and/or drinks do you most associate with Christmas and the holiday season?
Egg nog! Beat the yolks and whites of a dozen eggs separately and then pour together. Add a pinch of baking soda, 6 ounces rum, four cups sugar, and beat into a stiff batter. Then add a quart milk, a quart sweet creme and two quarts whiskey. Stir and refrigerate overnight. Merry Christmas!
Steven M. Yedinak
Turkey with my special stuffing recipe handed down from my grandmother. It includes lightly fried hamburger with onion, mixed with croutons, pecans, raisins, salt, pepper. Boil the turkey liver, gizzard and neck and use some of the water to mix the turkey dressing. Stuff the turkey and bake. Delicious.
James City County
Mom always made a pan of lasagna. Nobody can duplicate it! Good crisp bread and a salad. Here I make what I think folks will eat. We are not in New York. Miss those days.
Nothing says Christmas like fruitcake. I bought a huge one from Costco last week and I’ve had two pieces so far. Gooey, glistening, sweet, sticky. Yum.
Old fashioned cut-out sugar cookies in the shape of stars, bells and Santa’s sleigh decorated with red and green sanding sugar.
Virginia ham with corn pudding and Sally Lunn bread.
Christian Brothers Holiday Egg Nog, of course.
Christmas cookies and Eggnog. Nothing is better than those two things for making Christmas.
Two shots of Virginia Gentleman, fill the glass with whole milk and sprinkle nutmeg on the top. As for cookies, grandmother's e-cookies or my mother's cinnamon cookies.
Scottish shortbread (served, of course, with egg nog). My grandmother was Scottish, and this time of year I very much feel the pull of my ancestry.
When growing up, my mother would fix roast beef and Yorkshire pudding for Christmas dinner. This was the only time of the year that my parents splurged on such an extravagant meal. A tradition that my family follows to this day.
Talbot N. Vivian
Egg nog. I remember in the late ‘40s, my father mixing loads of milk and spices and a quart of Old Quaker in mother's punch bowl. I prefer today's grocery store brand.
Definitely fruitcake. I'm sure that most of modern civilization would agree including the multitudes that have forwarded it on to family and friends over the years.
Fruitcake. My father sent me one every Christmas. After he died, my sister continued the tradition and had one mailed to me from Corsicana, Texas. She sent me two this year. I will continue my father's tradition and mail my son a fruitcake from Corsicana, Texas, every Christmas from now on.
What a silly question. Fruitcake. Fruitcake. Fruitcake. Any more questions? We all need smiles for the blessed season.
The first food to come to mind was making two of my mother's recipe for fruitcake, with the assistance of my little 3-year-old (at the time) granddaughter, Randi, sitting on the kitchen cabinet throwing the fruit into the bowl of batter. The cooked fruitcakes smelled and tasted marvelous. Memories.
Gloria R. Champine
Smithfield ham! Specifically a Charles Henry Gray "special" ham with collard greens, rutabagas, sweet potato casserole, spoon-bread and last, pecan pie. Seasoning with the veggies is key. Hungry yet?
Herb De Groft
Fruit cake and fresh pork sausage and tenderloin. Dad raised a few hogs back in ‘50s and ‘60s and we (us boys anyway ) looked forward to help cutting up, etc. Can't find fruit cakes that good anymore.
Mince meat pie and eggnog
Newport Coast, Calif.


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OzHarvest & Holy Family Primary School help provide food relief
Article appeared in Catholic Outlook (26th of May 2020) after OzHarvest FEAST delivered over 100 FEAST Family Food Relief hampers to Holy Family Primary school to provide food relief to families in the community.
Student helpers were all smiles when a very special truck pulled up at Holy Family Primary Emerton last week. There were lots of helping hands when it came time to unload over 100 food hampers to share with families in the local community.
Many thanks to OzHarvest, Australia’s leading food rescue charity for these Family Food Relief Hampers and to the Jesuit Social Services ‘Ignite Food Shop’ onsite in Emerton, who also generously donated fresh fruit and vegetables to supplement supplies. This kindness will certainly ease the pressure on many families in the Mount Druitt area in these challenging times.
Holy Family Primary School Leader of Learning Ben Oxley said not only will the hampers go to families from this caring local school, they will also be shared with the Aboriginal Catholic Services Centre, Holy Family Preschool, Holy Family Parish and other local community groups that may need them.
With the leadership of Father Greg Jacobs SJ and some very helpful Year 6 students, each hamper was carefully unpacked from the truck. Staple ingredients like bread, non-perishable pantry items, eggs, fresh fruit and vegetables were distributed evenly into each hamper to make up enough food items to prepare about seven meals for a family of two adults and two children.
OzHarvest FEAST food hampers – packed and ready to be distributed to the local community.
Mr Oxley said the school received the hampers as a result of filling out an OzHarvest FEAST School Food Relief survey. “In fact our connection with OzHarvest stemmed from one of our teachers Alison Crombie visiting an Environment and Science expo last year and coming across the OzHarvest stall,’’ Mr Oxley said.
“Ms Crombie managed to find out about this great learning program they have for Stage 3 students which teaches the students how to cook healthy well balanced meals (FEAST). Ms Crombie and fellow teacher Mr Adam Fletcher went out to OzHarvest’s Alexandria headquarters earlier this year to be trained to run the classes and we were looking at starting the classes with the students in Term 2, before the COVID-19 pandemic came,’’ Mr Oxley said.
As the school was unable to go ahead with the classes, OzHarvest invited them to take part in a survey. “I got a call from them to say they are able to meet all our requests and as a result every fortnight 100 food hampers will now be delivered to the school,’’ Mr Oxley said.
Special thanks to Principal Mr John Spradbrow for his ongoing support of initiatives like this operating through the school. “Mr John Spradbrow is a pillar of strength for our community, we are lucky to have him. He is genuinely interested, and active, in providing whatever is needed for our community here,” said Mr Oxley.


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UTI Asset Management Company (AMC) is looking at inducting a strategic partner in the company in the next three months and has already short listed three companies for the same, reports The Economic Times. Though UTI AMC has not disclosed the names of the short listed firms, it has said that it would look at roping in companies that can offer it greater global footprint and help it in its overseas activities.
Though the AMC has offshore funds with five star ratings, the corpuses of these funds are not very large. This, according to the company, is because of the lack of marketing support in the overseas markets. It is, hence, looking at a partner that can provide it with marketing support it in the overseas markets. Currently, UTI AMC manages assets worth $200 million under its offshore funds.
Life Insurance Corporation, Punjab National Bank, State Bank of India and Bank of Baroda are the promoters of UTI AMC, holding 25% stake each in it. The promoters are looking at diluting a total of 26% stake in the asset management company to a strategic partner.
The asset management company is also open to making acquisitions in the mutual fund market. The fund house, however, would go in for an acquisition only if it comes at a right price. There have been indications that a few asset management companies have been in trouble since mid 2008.
UTI AMC has also tied up with Coopers Wealth Creators and Tower Infotech to provide investment opportunities to the employees and business associates of Tower Infotech under the UTI Retirement Benefit Pension Fund.
UTI AMC has assets worth Rs 49,754 crore under management as on March 2009.

domain: finance


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Cancer Research UK has been announced as the charity partner of Grafton Merchanting GB (GMGB), which owns Buildbase, Plumbase, Electricbase, PDM and Hirebase.
The builders and plumbers merchants chose the charity as its 2015/16 partner following a vote conducted by 5,500 staff nationwide.
Throughout the year, staff and customers will raise money to hit the £100,000 target, money which will go towards research to help bring forward the day when all cancers are cured.
Mark Kelly, chief executive officer at Grafton Merchanting GB in Oxford, said: “We are really excited to be launching our new charity of the year partnership with Cancer Research UK.
“Cancer affects so many people and many friends, loved ones and colleagues have been touched by it.
“We have all kinds of fundraising events in the pipeline including hosting dress down days, BBQ’s and sporting challenges. A team of female employees will also be taking part in Race for Life this summer.”
Sheona McMahon, partnership manager at Cancer Research UK said: “Every two minutes, someone in the UK is diagnosed with cancer. With the help of GMGB staff and customers we’re working to fund research which will help more men, women and children survive.
“It’s fantastic that Grafton Merchanting GB have pledged to raise such an incredible amount of money for us in the coming year and we wish them the best of luck with their fundraising.”
Although the number of people being diagnosed with cancer is going up, survival rates have doubled in the past 40 years thanks to research.
Cancer Research UK receives no government funding for its research, meaning fundraising provides valuable support to the daily work of doctors, nurses and scientists who combat the disease.


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'Raw, relentless ... Feverish' New Yorker'This is a devastating book about harm. It's about the harm that is unleashed when one person swaps their humanity for what you can really only call evil' Sunday Times'A controlled, exquisitely written book, it disturbs and disgusts, but it also mesmerises and, at certain moments, charms in its quiet brutality' Amia Srinivasan, Harper'sThroughout her childhood and adolescence, the anonymous author of The Incest Diary was raped by her father. Beneath a veneer of normal family life, she grew up with this secret. In this memoir, the author revisits her early traumas and their aftermath to explore the ways in which her father's abuse shaped her, and still does. As a matter of psychic survival, she became both a sexual object and a detached observer, a dutiful daughter and the protector of a secret. And then, years later, she made herself write it down.
In a bare minimum of spare, straightforward pages, the anonymous author of The Incest Diary manages to accomplish a nearly inconceivable literary task: She makes it possible not only to imagine the psychological impact of ongoing sexual violation but also to understand in visceral terms why she and so many others cannot escape their abusers ... The author is such a brilliant writer, though, that there are moments of joy and beauty to be found even within that discomfort; perhaps the discomfort even makes them sharper and more precious
One of the most frank and cathartic depictions of child abuse ever written
Shocking and searing … This is a devastating book about harm. It's about the harm that is unleashed when one person swaps their humanity for what you can really only call evil
Christina Patterson, Sunday Times
Her memoir seeks to evoke, in a way few before it have, the transgressive rush some might find in taboo sexual behaviour … Clear and urgent
New York Times
A controlled, exquisitely written book, it disturbs and disgusts, but it also mesmerises and, at certain moments, charms in its quiet brutality
Amia Srinivasan, Harper's
Disturbing for many reasons and for this reader, impossible to put down … The anonymous author is a strong writer, and she lays down a kind of dare with the furious brio of her prose
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Hello, welcome to my work in progress, this is te first time I have linked up with freshlypieced If you would like to know what others are working on,click on over.
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The mixture is separated by settling out, the aqueous phase is discarded and the organic phase is then evaporated in order to eliminate the residual TFA.
Acid Chloride Carboxylic acid, Acid Chloride Carboxylic acid, Benzoic anhydride Benzoic Acid, Acidic hydrolysis of esters gives directly carboxylic acids while basic hydrolysis gives carboxylates, which on acidification give? Complete JEE Main/Advanced Course and Test Series. Aromatic carboxylic acid preparation is possible through the oxidation of alkylbenzenes. The signals observed in NMR are expressed in The mass 10 spectra are measured in the electrospray (ES) ionization mode. Acid Anhydrides on the other hand give corresponding acid on hydrolysis. In the formula, R denotes the rest of the group attached to the functional group. Preferably, the compound of formula (III), (IIIA) or (IIIB), in which Y represents CF3, is synthesized by the reaction of triflic anhydride with triethylamine in an equimolecular mixture, in dichloromethane, at a temperature of between −5° C. and +5° C. The compound of formula (IV): may be prepared by the reaction of a hydrazine derivative of formula (V): in which R2, R3 and R4 are as defined for (I), with a derivative of formula (VI): in which R, R1and W are as defined above for (I). Hydrolysis of acyl halides and anhydrides, Structural Organisation in Plants and Animals, French Southern and Antarctic Lands (+262), United state Miscellaneous Pacific Islands (+1). The common carboxylic acid derivatives are esters, anhydrides, acyl halides, amides and nitriles. name, Please Enter the valid
After separation by 3 0 settling out, the organic phase is evaporated off. Acid Anhydrides on the other hand give corresponding acid on hydrolysis. Characterization of this receptor has been made possible by the development of specific synthetic ligands such as the agonists WIN 55212-2 (J. Pharmacol. carboxylic acids, Ethyl Benzoate Benzoic Acid, Ethyl butanoate Butanoic Acid, Signing up with Facebook allows you to connect with friends and classmates already One of the most common carboxylic acids is the acetic acid which has a wide range of application starting from vinegar and going all the way to the synthesis of organic materials including vinyl acetate, which is used as a polymer (polyvinyl acetate) in paints and adhesives:.
A process for the preparation of a compound of formula (I): The present invention comprises a process for the preparation of compounds that possess an affinity for the cannabinoid receptor in the human brain. According to a preferred embodiment, the reaction is carried out in a two-phase medium, in the presence of tetra-cis(triphenylphosphine)palladium, the basic medium consisting of sodium carbonate in an aqueous solution.
Thank you for your request. Copyright © 2008-2020 RPX Corporation. The 3-oxosuccinate derivatives of formula (VI), (VIA) or (VIB) are known or are prepared by known methods such as Claisen condensation of an ester enolate with an oxalic acid ester. Let's take a detailed look at some derivatives that can be made from an acid chloride, using acetyl chloride as our model substrate. Similarly, formic acid forms formamide, formyl halide, methylformate. number, Please choose the valid These compounds are useful as immunomodulators and psychotropic agents in the treatment of thymic disorders, vomiting, myo-relaxation, various types of neuropathy, memory disorders, dyskinesia, migraine, asthma, epilepsy, glaucoma, anticancer chemotherapy, in ischemia and angina, in orthostatic hypotension and in cardiac distress. using askIItians. The reaction medium is stiited at 65° C. for 6 hours. Media Coverage | “Relax, we won’t flood your facebook Ther., 1993, 264, 1352-1363) or CP 55,940 (J. Pharmacol. The reaction of aliphatic carboxylic acids with bromine in the presence of phosphorous produces α halo acids. The present invention comprises a process for the preparation of compounds that possess an affinity for the cannabinoid receptor in the human brain. Search for more papers by this author. FAQ's |
Process for the preparation of carboxylic acids and their derivatives Download PDF Info Publication number DE60226229T2. Process For The Preparation Of 1,5—Carboxylic Acid Derivatives. It’s an easier way as well. Such as acetic acid forms acetamide, acetyl halides, acetonitrile and ethyl acetate. These compounds are useful as immunomodulators and psychotropic agents in the treatment of thymic disorders, vomiting, myo-relaxation, various types of neuropathy, memory disorders, dyskinesia, migraine, asthma, epilepsy and glaucoma, anticancer chemotherapy, in ischemia and angina, in orthostatic hypotension and in cardiac distress. aldehydes, alkenes and alkyl benzene results in formation of carboxylic acids. phosphoric acid. 2,4-dichlorophenylhydrazine hydrochloride(12.6 g) is dissolved in 100 ml of toluene and this solution is placed under nitrogen; after stirring, 10 g of diethyl 2-methyl-3-oxosuccinate are added and the mixture is then heated and 5 ml of TFA are added at 55° C. The mixture is left at the reflux of the solvent for 4 and a half hours, with stirring. More specifically, the present invention relates to a novel process for preparing 1,5-diphenylpyrazole-3-carboxylic acid derivatives. Carboxylic Acid Derivatives.
Exp. Tutor log in | Contact Us | 1,5-Diphenyl-4-methylpyrazole-3-carboxylic acid esters are described in particular in European Patent EP 576 357 and U.S. Pat. Aliphatic nitriles are prepared by treatment of alkyl halides with sodium cyanide in a solvent that will dissolve both reactants. No.5,624,941 to Barth et.
The effects of cannabinoids are due to an interaction with specific high-affinity receptors present in the central nervous system (Devane et al., Molecular Pharmacology, 1988, 34, 605-613) and peripheral nervous system (Nye et al., The Journal of Pharmacology and Experimental Therapeutics, 1985, 234, 784-791; Kaminski et al., 1992, Molecular Phannacology, 42, 736-742; Munro et al., Nature, 1993, 365, 61-65). The present invention relates generally to processes for the preparation of pharmaceutical compounds and compositions useful in the treatment of disorders and diseases of the central nervous system (CNS).
Use Coupon: CART20 and get 20% off on all online Study Material, Complete Your Registration (Step 2 of 2 ), Live 1-1 coding classes to unleash the creator in your Child, Oxidation of Primary Alcohols and Aldehydes, Hydrolysis of acyl halides and anhydrides, Oxidation is a direct method most commonly used for preparation of carboxylic acids. Exp. Reactions of Carboxylic Acids 1.
1.890 g of the expected compound are obtained. The most convenient laboratory preparation for formic acid is to heat glycerol with oxalic acid at 100 – 110° C. Hydrolysis of acyl halides and anhydrides. You will receive a custom alert email when the Litigation Campaign Assessment is available. Acid Anhydrides on the other hand give corresponding acid on hydrolysis. 1. Alkenes can be oxidized to carboxylic acids with hot alkaline KMnO4, 2-Butene Ethanoic Acid. Careers | W represents a group —COOR or a radical —CN; A) Preparation of ethyl 5-(4-chlorophenyl)-1-(2,4-dichlorophenyl)-4-methyl-1 H-pyrazole-3-carboxylate, B) Ethyl 1-(2,4-dichlorophenyl)-4-methyl-5-(((trifluoromethyl)sulphonyl)oxy)-1H-pyrazole-3-carboxylate, C) Ethyl 5-(4-chlorophenyl)-1-(2,4-dichlorophenyl)-4-methyl-1H-pyrazole-3-carboxylate. In dimethyl sulfoxide (DMSO), reaction occurs rapidly and exothermically at room temperature. The reaction medium is hydrolyzed with 20 ml of DCM. Upon heating, the β ketoacid becomes unstable and decarboxylates, forming a disubstituted acetic acid. Trihalogen derivatives in which the three halogen atoms are all attached to the same carbon atom yields carboxylic acid on hydrolysi. In particular, the compound of formula (IVA): is obtained by reaction of a hydrazine derivative of formula (V) with a derivative of formula (VIA): Also in particular, the compound of formula (VIB): is obtained by the reaction of a hydrazine derivative of formula (V) with a derivative of formula: Preferably, a hydrazine hydrochloride of formula (V) is used in a solvent, preferably, an acid medium, for example, acetic acid; or in toluene in the presence of hydrochloric acid, acetic acid or trifluoroacetic acid. Blog | Primary alcohols on oxidation give aldehydes, the reaction does not stop here and the oxidation continues to give carboxylic acids as final product. In particular, the compound of formula: is obtained by reaction of triflic anhydride with a pyrazolone derivative of formula: in the presence of a base, such as a tertiary amine, and in a solvent, such as dichloromethane. The reaction medium is separated by settling out, the aqueous phase is discarded, and the organic phase is then washed with 10 ml of water.
nucleophilic metal derivative, and this adds to carbon dioxide (anelectrophile).
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- Pregnant Again After Miscarriage or Other Pregnancy Loss
- 23 Things I Wish Someone Told Me About Pregnancy After a Miscarriage
Pregnant Again After Miscarriage or Other Pregnancy Loss
My Journey to Pregnancy After Miscarriage ????and
I'll never forget that moment. I sat in my doctor's exam room, eagerly awaiting a first glimpse of my baby's heartbeat. I imagined watching it, a tiny flicker on the screen, feeling instantly connected to the life inside me. I never imagined the doctor looking at me and saying, in his most clinical voice, "I'm sorry. There's no heartbeat. That moment has stayed with me, seven years and two kids later. A miscarriage is a scar that never fully fades; no matter how much time goes by, a shadow of that loss always lingers.
Losing your baby at any stage can be devastating, and the fear of it happening again may tempt you to forgo trying to have another child. Fear, anxiety, and dread are all normal responses after a period of loss and grief. But if you're committed to having a baby and want to try again after miscarriage , there are ways to control your anxiety and remain optimistic: Consult your doctor. Before you try to conceive again, discuss your concerns with your physician. Make sure you have his or her blessing; you'll want your practitioner to be your partner all along the way.
T he first sign we had that I was pregnant again was a home test. I peed on the plastic wand and then attempted to putter casually about the kitchen for three minutes as I waited for the result.
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Whether this applies to you or someone you care about, here are 23 things I wish someone would have told me about pregnancy after miscarriage. You feel defeated and like you failed. The worst part is you then wait another two weeks to try again and start the whole torturous cycle over again. I actually stared at it in disbelief. Second, when I did let the realization that I was pregnant again sink in, it was as if fear decided to barge through the door. It might sound strange, but having to go pee is a terrifying experience.
I know how scary this can feel. Here is my story, I hope it helps you find joy in your next pregnancy, and know that you are not alone in this journey. These are the words the emergency room OBGYN said to me, as she leaned in close and gently touched the side of my face. We had just spent the night investigating whether my pregnancy could have survived the amount of vaginal bleeding I had. Another pregnancy lost, and this one was harder for me for some reason.
I find it therapeutic to write about it , oddly, but talking it about it casually with loved ones still isn't easy. The reason behind this is simple—at least to me: During my last pregnancy, I miscarried twin boys and it was devastating. Before our loss, my husband and I had already told our sons that they would be having not one, but two little brothers, and we loved telling everyone about our news. Suddenly, none of that mattered anymore. And when well-meaning friends wanted to throw me a baby shower, I asked if we could just have a regular brunch with no baby theme instead.
23 Things I Wish Someone Told Me About Pregnancy After a Miscarriage
I'm Scared • Pregnancy After Loss


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Genre: Music, Classical, Talk, Interview
Frequency: 52 weeks
Delivery Type: PRX and CD
Executive Producer/Host: Gilbert Kaplan
Producers: Heidi Bryson and Marcela Silva
The WFMT Radio Network is pleased to announce our offering of the one-hour series, Mad About Music with host Gilbert Kaplan.
For more than 10 years Mad About Music has delved into the musical heart of some of the world’s most celebrated and influential personalities. Originally airing in New York on WNYC and WQXR, Mad About Music is now syndicated for broadcast.
Created and hosted by Gilbert Kaplan, Mad About Music’s format is part interview, part musical performance. Internationally famous guests select five key musical works and discuss why those pieces are important to them. The interviews are always personal–and often humorous—as some of the world’s most famous people reveal aspects of their personalities largely unknown to the public.
“Gilbert Kaplan is an ideal host for Mad About Music combining considerable interviewing skills with a grand passion for music,” said WNYC/WQXR radio president and CEO Laura Walker.
This series is available free of charge to all affiliate stations for one broadcast through March 31, 2015. If you have any questions or for more information, please contact Tony Macaluso at (773) 279-2114, email:email@example.com Estlin Usher at (773) 279-2112, email:firstname.lastname@example.org, or David Sims at (773) 279-2027, email:email@example.com.


text: My childhood was spent reading and learning. I've never been a time waster. My parents restricted me as much as they possibly could. They constantly took away my computers and books. Punishing me by removing anything they thought I might enjoy. I had straight A's in school without trying. Is there some advice I would give myself? There's nothing I could've done differently until I was free of my parents. By then it was too late, really. I'm still trying to figure out my life.


Agriculture Blend Standard Tractor Chain Ratovator Chains 08b-1 08b-3 10A-1 10A-2 12A-1 16A-1 16ah-108b-2 12A-2 12ah-2 16A-2
|Normal transmission Roller Chains
|Sequence A, Series B
|ISO, ANSI, DIN, BS
|Packaged in bins and wood circumstances, or packaged in reels and then on pallets.
|Any sea port or airport in China
What to look for in a roller chain
There are a lot of diverse factors to take into account when purchasing a roller chain. One particular of the most important elements is tensile power, which signifies the pressure needed to split the chain. Roller chains are offered in 3 diverse tensile strengths: bare minimum, regular and ultimate. Each and every energy demonstrates a diverse limit to the load the chain can manage. Nonetheless, these restrictions are not usually equal and you should be informed of the variations in between roller chains.
Most roller chains have common measurements printed on the facet panels. This is generally “forty” or “C2080H”, but can also be the letter “B”. If the chain is aged, it will want to be cleaned to see its measurement. You can find the size on the standard roller chain measurement chart, but not everyone is marked. To figure out the dimensions, measure the diameter and pitch of the chain, then compare the benefits to the chart to see what measurement you want.
Weighty-obligation roller chains are obtainable with heat-taken care of pins, side plates, and rollers. In addition to currently being warmth handled, they are also manufacturing facility pre-stretched, which minimizes put on on these components. If correctly managed, they can very last for many years, lowering the threat of failure or corrosion. Dependent on the application, common roller chains are obtainable in various dimensions. It can be obtained independently. There are several alternatives to decide on from, relying on the measurement and energy of the software.
PEER roller chains contain strong rollers to decrease shock loads on the sprocket enamel. Warmth dealing with and preloading all factors of the PEER chain will help reduce preliminary elongation. Very hot-dip lubrication makes certain comprehensive lubrication of all chain factors, extending their existence and decreasing maintenance expenses. For hefty-duty programs, ASME/ANSI-B29.1 chain is a excellent option.
Regular roller chains are created of metal or alloy steel. However, it can be created of other resources this sort of as stainless steel. In addition to metal, stainless metal is frequently utilised in foods processing machinery in which chain lubrication is an concern. Brass and nylon are also often used. However, they are not that popular. As a result, you must usually check out with your supplier ahead of buying. By comparing the tensile energy of two diverse chains and creating an knowledgeable decision, you can get the ideal price and service.
Chain with no bushing
Bushless roller chains have positive aspects in excess of typical roller chains. Not like typical chains, bushless chains have substantial lateral adaptability, which raises the chain’s lubrication stream. The interior plates of bushless chains have protruding shoulders so the oil can movement through them much more easily and proficiently. This is an critical attribute of a smooth-working chain. Moreover, bushless chains could have improved shifting functionality.
The toughness of a bushingless roller chain is measured in conditions of tensile energy and tiredness toughness. The previous steps the load a chain can endure prior to breaking. Exhaustion energy is equally crucial, and aspects that influence tiredness energy incorporate the steel utilised to make the chain elements, the pitch hole fabrication, the kind of shot peening on the chain, and the style and thickness of the chain. For case in point, if the chain is way too skinny, it may possibly not be adequate for hefty-duty applications.
Like standard roller chains, bushingless roller chains have two different types of links. The internal url has two interior plates related by pins, even though the outer chain has two outer plates held with each other by bushings. A bushingless roller chain is related to a traditional chain, except it eliminates a stage in the assembly approach by stamping the tube into the internal plate. So if you want a smoother ride, a bushingless roller chain is a much better option.
There are two different dimensions of bushingless roller chains. 1 dimension is developed for use with normal one-strand chains, although the other size is created for use with double-strand or triple-strand chains. Bushless chains are usually shorter than traditional chains, so they can in shape in tighter spaces. Bushless chains are manufactured of the optimum top quality components. These chain attachments are case hardened for ideal toughness and sturdiness.
The silent roller chain has a easy, lower-noise push. They are made of stacked rows of flat chainplates with a equipment-like profile that meshes with the sprocket tooth. Each and every chainplate is hooked up to a corresponding sprocket, which also enables the chain to bend. Even though these basic parts are the same for each and every silent roller chain, there are numerous versions that let them to be used in a range of purposes.
The most common substantial-speed transmission, silent chains characteristic equipment-like sprockets. They can be manufactured from solitary or numerous strands of materials. Single-strand chains are much less high-priced than multi-strand chains, but they are likely to use out more rapidly if not lubricated. One-strand roller chains can be utilised for several years without lubrication, but for your software, wide silent chains are nevertheless well worth taking into consideration.
The design and style and building of silent chains make them perfect for conveying a wide selection of goods. They have flat, warmth-resistant surfaces. They are also sturdy and non-slip. They are obtainable in a selection of pitch sizes, widths, and mounting variations. Whether or not you want chains for common objective conveyors or glass bottle transport apps, we have you coated. Inquire about the rewards of silent roller chain conveyors.
Inverted tooth chains are one more option for quieter chains. These chains are developed to minimize sounds from engine-associated friction. Silent chains are more frequent, and producers have fallen in enjoy with them. A silent chain is made up of many hyperlinks related to the sprocket tooth. Tooth rotate to reduce noise, vibration, and chord action. These are the principal causes why silent chains are so well-liked.
ANSI chain pitch
To measure your bike’s chain pitch, you can use a caliper. This measurement is taken from the center of the rolling pin to the middle of the subsequent rolling pin. Chains appear in several sizes, but ANSI is the most common chain standard in the United States. A caliper is helpful if you happen to be not certain which size to buy, as it allows you to check out for worn sprockets.
Chains that meet up with ANSI specifications will be characterized by a specific pitch. This measurement is based mostly on the width and spacing of the roll. The spacing is typically increased than the width. The standard amount will be the appropriate amount for the width of the chain or the remaining amount for the rollers. The amount on the remaining implies no matter whether the chain is lightweight or heavyweight. Heavyweight chains are selected by the suffix “H”.
Typical chain dimensions are dependent on ANSI chain pitch. Pitch is the minimal distance in between bushing and sprocket. The smaller sized the chain pitch, the better the whole length between the two points. This means the chain will very last longer. Nonetheless, if you are acquiring a chain for a certain software, you must check the pitch carefully as it can influence the overall performance of the chain.
Roller chain use measurement
The function of roller chain dress in measurement is to prevent breakage by monitoring the pressure on the chain. There are many methods to measure roller chain dress in. The very first is to remove the chain from its working placement and evaluate the length from the sprocket to its measuring finish. An additional way is to measure the pitch of the chain or the distance amongst two pins. This approach is exceptional to other strategies due to the fact it is handy and accurate.
When measuring the put on of a roller chain, it is crucial to be aware that the components of the chain will steadily deform. About 3.seventy five% of the total put on will be on the pins and the rest will be on the inner hyperlinks. These wear measurements will range dependent on the nominal pitch of the chain and the quantity of friction the chain is enduring. Correct lubrication between pins and bushings, load and frequency of articulation all influence put on rates.
It is important to measure the volume of wear on the roller chain to keep away from excessive machine failures. The longer the chain runs, the much more dress in it will put on. Despite the fact that the size of the chain should be less than the middle length, the abnormal load will lead to premature dress in. For that reason, lubrication is crucial. Furthermore, the sag of the chain must not exceed 2% to 4% of its middle-to-heart distance. Last but not least, check out for strange sound or seen flaws. A frequent cause of extreme roller chain dress in is the size of the load. Every single chain manufacturer sets a optimum workload for its merchandise.
There are many methods to evaluate roller chain wear. If employing a substantial-pace drive, it need to have at the very least 11 tooth, and a medium-velocity travel ought to have at minimum twenty five teeth. Also, be positive to check the length of the chain, even if you need to. The very same goes for the pin diameter, which need to be the same or distinct pitch as the roller chain.


Inaki Pena the 23-year-old goalkeeper played a pivotal role in Galatasaray’s 0-0 draw with Barcelona. After helping to save the net several times. Jordi Cruyff an adviser to Barcelona’s president has revealed. That Azulgra will likely decide on Inaki Peña’s future this summer. The 23-year-old has
Uruguay dubbed the “ruthless” as Uruguay beat Venezuela 4-1 in the 2022 World Cup qualifying game. With Manchester United‘s Edinson Cavani showing a beautiful somersault. Uruguay have called on Manchester United striker Edinson Cavani to return to the starting lineup alongside Luis Suarez. While Venezuela
Crystal Palace are monitoring Arsenal‘s youngster Eddie Nketiah in case his move to Germany fails. The Eagles have interest in the Gunners’ 22-year-old forward for some time. But he is aiming for a free transfer to the Bundesliga in order to be fully paid up.


Genetically modifiedengineered foods essay
While researching as to when the united states officially adopted the commercial use of genetically engineered foods, i found that there was only a three year window in which the genetic engineering of food started and when the. Genetically-modified foods (gm foods) have made a big splash in the news lately european environmental organizations and public interest groups have been genetically-modified foods (gm foods) have made a big splash in the news. 2011/02/18 genetically modified foods the world's most productive means of producing food what is a genetically modified food genetically modified (gm) foods are foods derived from genetically modified organisms genetically. English 1010 11 november 2012 genetically modified food genetically modified foods (gmf) have foreign genes such as plants, animals and bacteria inserted into their genetic codes genetically modified organism is processed in a.
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A Clearview Township woman has been defrauded for $22,000 in the so-called ‘Grandparent Scam”.
Huronia West OPP say they were contacted by the victim after she received a call from someone claiming to be with the RCMP. She said she was told her grandson had been arrested and $10,000 would be required to secure his release. The woman agreed to the payment and arrangements were made for it to be picked up that afternoon.
The next morning, a follow-up call requested an additional $12,000, which was also paid.
The OPP reminds everyone that officers will never contact family members to request money for their loved ones to be released from custody. If you should receive one of these calls, please hang up and contact your local police service to report it.
The investigation is ongoing. Anyone with information is asked to call Huronia West OPP at 1-888-310-1122, Crime Stoppers at 1-800-222-TIPS (8477) or https://ontariocrimestoppers.ca/.
South Simcoe Police have also received reports of various frauds.
- A resident received a call from someone claiming to be from the Canada Revenue Agency demanding payment of an unpaid debt. The fraudster was spoofing the South Simcoe Police Service phone number and requested payment in an iTunes gift card. The resident recognized this was a scam and hung up the phone.
- A resident was contacted via a messaging app by someone posing as their boss. The fraudster instructed the employee to buy iTunes gift cards and provide the codes to him by email. The employee complied but later learned from the real boss that he never sent any messages.
- A resident called a 1-800 phone number in a pop-up after their computer crashed. Turns out it was fraudsters, who had the person change all passwords on the computer while the suspect still had control. The resident then received a call from a fake technical support worker at the bank, saying the person’s account was compromised, and enlisted help to catch a crooked employee. The fraudster had the person set a “trap” by wiring a sum of money to an overseas account. The person complied, realizing too late it was an elaborate scam.
- There are also the relentless texts we received on smartphones trying countless ways to get people to click on a link. Don’t.
Fraudsters continue to come up with new ways to try to trick you into parting with your hard-earned cash. They prey on our busy lives or an in-the-moment vulnerability.
Remember these tips to recognize and prevent frauds:
- Always validate the legitimacy of online requests or phone calls and contact the sender to confirm the source is legitimate.
- If a phone number from someone demanding payment appears to be a police service, hang up and call the police service
- Remember that official agencies will never ask for gift cards as payment.
- Resist pressure to act quickly and ask the caller if you can call them back.
- Trust your instincts. If it feels wrong, it probably is.
- Contact the police or someone you trust if you have any doubts.
- Just take a moment, step back from the situation and disengage. Time is on your side.
- Never share personal information with anyone you don’t know over the phone or the internet.
Report incidents of fraud to police and the Canadian Anti-Fraud Centre.
Learn more about ongoing scams in Canada with the Little Black Book of Scams.
feature image via pxfuel


The News International Team
02:25pm Market Expert
With the India story changing, Devesh Kumar, managing director, country head, CIMB Securities India sees Nifty in five digits – 10,000 plus – from a 12-months perspective.
He says near-term earnings will not give any positive surprise, but it should be looked at from a 1-2 years perspective. “India remains a long-term story for investors,” he told CNBC-TV18. He sees a multi-sectoral rally ahead.
02:00pm Equity benchmarks extended losses in afternoon trade with the Sensex falling 108.63 points to 26312.04 and the Nifty declining 27.25 points to 7870.25 weighed down by profit booking in banking & financials, FMCG, auto and oil & gas stocks.
About 1538 shares have advanced, 1268 shares declined, and 108 shares are unchanged.
Rakesh Arora of Macquarie says the market remains tentative on global events and would likely continue to focus on geopolitics. The brokerage house remains positive on the market and recommends buying large cap quality stocks on any weakness.
ONGC topped the selling list, down 2.6 percent followed by HDFC with 1.8 percent. ITC, Tata Motors, Reliance Industries, Larsen and Toubro, State Bank of India, Mahindra and Mahindra, HUL and Axis Bank declined 0.6-1 percent.
However, healthcare stocks saw hefty buying interest with the Sun Pharma, Cipla and Dr Reddy’s Labs rising 3-4 percent. Midcap pharma companies gained 4-15 percent.
Among others, Wipro rose 1.3 percent while Tata Power and NTPC climbed 1.7 percent and 0.9 percent, respectively.
Global markets were mixed with the European markets like France, Germany and UK falling less than 0.5 percent while Asian markets like Taiwan and Straits closed with minor gains. The pound has risen to 1.66 against US dollar after Bank of England minutes showed that two members of the rate setting committee voted to raise interest rates in August as pressure on central bank builds to raise rates.