The file-sharing feature in Ventura 13.2 is a powerful tool that makes it easy to share files with other users. Unfortunately, some users have encountered issues with the file-sharing feature, where it stops working unexpectedly. This can be a frustrating experience, but fortunately, a few solutions can be used to get the file-sharing feature back up and running. This blog will discuss how to diagnose and fix these issues so you can get back to using the software as quickly as possible.
Why is your File Sharing not working on MacOS Ventura?
1. Incompatible File Sharing Protocols: One of the most common reasons why File Sharing is not working on MacOS Ventura is because the File Sharing protocols used by the two systems are incompatible. If the two systems do not use the same File Sharing protocol, they will not be able to communicate and share files.
2. Firewall Restrictions: Another possible reason why File Sharing is not working on MacOS Ventura is because of firewall restrictions. Firewalls can block network traffic and prevent computers from communicating with each other.
3. Network Settings: Network settings can also prevent File Sharing from working on MacOS Ventura. The inability of computers to speak with one another and share files arises from their need for network connectivity.
4. Permission Settings: Permission settings on the computers can also prevent File Sharing from working on MacOS Ventura. If the user does not have the correct permissions to access the shared folder, then the File Sharing feature will not work.
Ways to Fix Mac File Sharing that is not Working
Numerous factors could prevent you from enabling File Sharing on your Mac running on macOS Ventura 13.2 or using another computer to view the shared folder on your Mac. Follow the solutions in this section to get your strike File Sharing back to normal, no matter your particular circumstance.
You can first restart your Mac, which will update the operating system and take care of any short-term issues that might prevent Mac File Sharing from functioning as intended. Attempt the following alternatives if this approach fails.
#1. Check the Network Connectivity
The first step in troubleshooting file-sharing issues is ensuring the network connection is stable and working correctly. Ensure all network devices are powered on and the cables are correctly connected. Additionally, check to ensure the connection is not going through a firewall or any other security device.
#2.Check the File-Sharing Settings
The next step is to ensure that the file-sharing settings are correct. In some cases, the settings may have been changed accidentally or maliciously. Ensure the settings are correct and the permissions are set correctly.
All files in that shared folder can have the read-only or read-write permission set.
- Go to Sharing in System Preferences.
- Choosing File Sharing.
- To apply permissions to enclosed items, right-click the folder in the Shared Folders box and select the option.
- Apply for the included items’ permissions.
- Additionally, your improper File Sharing configurations are to blame for the shared folder’s inability to be accessed or updated.
- Check your File Sharing settings to see if you have added the folder to the Shared Folders box, granted the desired user read-only or read-write access to the folder, and checked the “Share files and folders using SMB” box in Options.
#3. Check the File Sharing Protocol
When troubleshooting file-sharing issues, it is essential to ensure that the correct file-sharing protocol is used. If the wrong protocol is used, it may cause problems with sharing.
#4. Update Operating System
It is also important to ensure that the operating system is up to date and that all necessary drivers are installed. If the operating system is not up to date, it may cause problems with file sharing.
If the file-sharing issue persists, it may be caused by a problem with the software. Make sure that the software is up to date and that it is appropriately configured. Additionally, ensure that the software is compatible with the operating system and the protocol used.
#6.Check the Hardware
The hardware may, in certain situations, be the root of the problem. Make the hardware reliable and compatible with the installed operating system and software.
#7.Ensure the File Path is correct
File-sharing problems may result from erroneous or incomplete paths. Verify that the file path is accurate and is not blocked by any security software.
#8.Check the Security Settings
In some cases, the issue may be caused by the security settings. Make sure that the security settings are configured properly and that they are not blocking file sharing. Additionally, ensure the users have the necessary permissions to access the file.
#9.Check the Firewall
Ensure the firewall is not blocking file sharing. Ensure that the firewall is configured correctly and not blocking the file-sharing protocol.
Also Read: macOS Ventura: VPN/DNS Not Working
These are the methods you should implement to fix the broken file sharing feature in macOS Ventura 13.2. If all of these steps are taken, and the issue still needs to be resolved, it may be necessary to contact the software or hardware manufacturer for assistance.


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Here is a small percentage of some of the awesome women of Telemundo.
Thalia Marimar, one of the most famous telenovelas ever created in Mexico also gained popularity in other countries around the world particularly in the Philippines and New Zealand.
Junior Brother: Kerry songwriter and collaborators tread the Opera House boards.
In fact, she looks like she would fit right into a film about a couple of bad girls on the hunt for revenge.
Camila Sodi was born on May 14, 1986, in Mexico City; apart from acting, she is also engaged in modeling.
On a cold January morning, Ellice Littlejohn finds her boss dead with a gunshot to his head and walks away like nothing happened for fear of her own dark past being exposed.

domain: artistic


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Crane Creek Park encompasses a total area of 79 acres of what was once a state park before it was handed over to the Division of Wildlife as part of the Magee Marsh Wildlife Refuge. The park is much the same as it was before the main difference being that the picnic areas and swimming beach have currently been closed.
The park is located on the shores of Lake Erie, providing a coastal environment that is a refuge for hundreds of species of birds including the magnificent bald eagle, waterfowl, herons, gulls, and warblers. The variety of bird species makes Crane Creek State Park a birdwatcher’s paradise. To get to the park, just travel 16 miles from Toledo, which is a city at the western tip of Lake Erie and in the north-central part of the state of Ohio.
As for the topography and distinctive features of the park, the place is mostly marshlands and beach area. The Crane Creek was once a part of the Great Black Swamp, that almost totally disappeared due to extensive lumbering and drainage in a bid to create fertile agricultural land. The park gets its name from the nearby Crane Creek that flows into Lake Erie.
If you decide to visit this stunning park, you can bring your dog with you for fun, exercise, or relaxation. Just be sure to be aware of some simple rules that will prevent any inconvenience to you, other visitors to the park and to other animals. Some of the rules that you must adhere to include keeping your dog on a leash no longer than six feet long, avoid letting your dog wander into park buildings and other areas that are not designated as pet-friendly areas, and it is a good idea to carry some poop bags with you so that you can clean up after your pooch.

domain: geography


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- 2 min read
Maharashtra Tourism tops MoT’s Utsav portal state rankings
The state ranking list was revealed by Ministry of Tourism (MoT) on July 5, 2022, which declared Maharashtra as number 1 on the portal with 10 published live darshan listings and, among the top 10 states with 8 published events and festivals listings. Having innumerable religious places/ temples/pilgrimages, Maharashtra is also known for its religious circuit.
In 2021, when Covid-19 virus was still prevalent in India, Ministry of Tourism (MoT) created and launched a website named utsav.gov.in and called for the content of various events and festivals as well as, live darshan details of temple deities from all the states/UTs. To this, the Maharashtra tourism department promptly responded and shared all the desired details. The state ranking list was revealed by MoT on July 5, 2022, which declared Maharashtra as number 1 on the portal with 10 published live darshan listings and, among the top 10 states with 8 published events and festivals listings.
Having innumerable religious places/ temples/pilgrimages, Maharashtra is also known for its religious circuit. Shirdi, Pandharpur, Tuljapur, Jejuri, Trimbakeshwar, Vani (Saptashrungi) and Siddhivinayak temple of Mumbai are only a handful of religious places that devotees/tourists visit in huge numbers especially during occasions.
During the pandemic, when the devotees couldn’t physically visit these holy places, the temple authorities took up the initiative of online darshan. It became convenient not only for the management but also for the devotees to be able to get a glimpse of the God/Goddess from the comfort of their homes by taking all the safety measures to stop the spread of Coronavirus.
Maharashtra is popularly known for festivals like Pandharpurchi Wari, Ganesh Chaturthi, Gudi Padwa, Dahi handi, Narali Pornima, etc., that are published on the website.
Valsa Nair Singh, Principal Secretary, Tourism department, Government of Maharashtra, said, “I am glad that our department is keeping pace with the digital trend where tourists want to get all the information with a single click. Religious tourism is the oldest form of tourism followed in India and, where Maharashtra has unique religious circuits like Shirdi- Shegaon- Pandharpur, it plays a vital role for us to display them on the national platform. Similarly, festivals are a way of showcasing the culture of our state and are equally important for tourists. As both the aspects are crucial to shaping tourism in the state, we have taken a keen interest in this initiative of MoT.”
She added, “I would like to appreciate the efforts made by MoT for bringing information on festivals and religious tourism of all the Indian states under one roof. This will definitely benefit in attracting more domestic and foreign tourists.”

domain: news


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Caveolin-1 alters the pattern of cytoplasmic Ca2+ oscillations and Ca2+-dependent gene expression by enhancing leukotriene receptor desensitization.
Bottom Line: Here, we show that the scaffolding protein caveolin-1 has a profound effect on receptor-driven Ca(2+) signals and downstream gene expression.Mutagenesis studies revealed that these effects required a functional scaffolding domain within caveolin-1.Our results reveal that caveolin-1 is a bimodal regulator of receptor-dependent Ca(2+) signaling, which fine-tunes the spatial and temporal profile of the Ca(2+) rise and thereby its ability to activate the NFAT pathway.
Affiliation: From the Department of Physiology, Anatomy, and Genetics, University of Oxford, Parks Road, Oxford OX1 3PT, United Kingdom and.Show MeSH
Related in: MedlinePlus
Mentions: Endogenous levels of caveolin-1 were virtually undetectable in Western blots from RBL-1 cells (data not shown), so we overexpressed the GFP-tagged protein to study its impact on Ca2+ oscillations. In non-transfected (wild type) cells, stimulation with LTC4 evoked a series of cytoplasmic Ca2+ oscillations (Fig. 1A), which decreased slightly over time due to receptor desensitization (Fig. 1B) (6). Expression of caveolin-1-GFP substantially altered the pattern of the Ca2+ oscillations (Fig. 1A, dotted trace). The amplitudes of the initial Ca2+ oscillations evoked by LTC4 were now considerably larger than in non-transfected cells (Fig. 1, A and C), but the oscillations ran down more quickly and so were fewer in number over a 600 to 700-s recording period (Fig. 1B). Analysis of the various oscillatory parameters revealed that the total Ca2+ rise associated with each oscillation (area under the spike) was significantly larger in cells expressing caveolin-1-GFP (Fig. 1D); this reflected both an increase in the amplitude of each Ca2+ oscillation (Fig. 1C) as well as an increase in duration (Fig. 1E). Cytoplasmic Ca2+ during each oscillation was therefore elevated for a longer time in the presence of caveolin-1-GFP.
Affiliation: From the Department of Physiology, Anatomy, and Genetics, University of Oxford, Parks Road, Oxford OX1 3PT, United Kingdom and.

domain: literature


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If your club uses mains potable water, it’s in trouble. We talk to environmental solutions expert Tony Hanson about the coming storm and what you can do about it
Imagine everyone in Greater Manchester moving south. That’s 2.8 million souls and it’s the projected number of extra people expected to add to population growth over the next 20 years.
Now imagine the added strain that moving mass would put on land and, crucially, on w


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Shop with Confidence!
We accept Free 30-Day Returns.


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Buy or download Free Tropical Flamingo Pictures in many different backgrounds as well as cartoon flamingos, pink flamingo clip art and beautiful pictures of flamingos and flamingo on a tropical island, no matter what flamingos are beautiful and peculiar birds that many of us are fascinated with.
I have also provided a huge selection if breathtaking pictures of flamingos from all posters where you can get these pictures matted and framed for some of the best prices around, just click on the pictures you love and it will take you right to it so that you can purchase it.
In order to save the clipart pictures that are presented on this page all you need to do is right-click over the image and then select "Save-As" or "Save Picture As” and it will save onto your computer, its real easy.
You, your family and friends will have hours of fun using a variety of fun tropical graphics with flamingos on them that can be used for birthday and luau invitations, appliqués and decorations for a party, name tags, school projects or they’re even great for putting in scrap books for scrapbooking and crafts, use your imagination and there is no end to the fun you can have.
Flamingos are a symbol of the tropics and especially the State of Florida has made this bird very popular as a tropical symbol with a palm tree or two in the background.
It is also popular being used as a Christmas decoration or ornament by putting a santas hat on these colorful bird.
I hope you will be able to find the tropical pictures that you are looking for and have fun with your clipart.
Buy Beautiful Tropical Flamingo Pictures
This incredible selection of Flamingo are from All Posters which allow you to choose the size of the picture as well as picking put framing and matting if you wish!


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Thursday, Jul 11 8:30p
Tannery World Dance \& Cultural Center, Santa CruzScene One / Deanna -The Wreck When I was a little girl my mother didn't read me fairy tales about knights in shining armor who save the little princess - no...
Saturday, Jun 8 8:00p
San Francisco Conservatory of Music, San FranciscoDawn Harms, guest conductor Assad – Brazilian Fanfare Elgar – Cello Concerto Emil Miland, cello Saint-Saëns – Symphony #3 ‘Organ’ Part of BARS’ LGBTQ Composer and Performing Artist Series, w...
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As Great Lakes ice coverage hovers around 80 percent, there’s no shortage of frozen landscapes to be seen.
This week Echo pulls a recent image from a NASA earth observation satellite.
The natural-color image, frames the U.S.-Canadian border and the Niagara River, flowing from a 98 percent frozen Lake Erie in the south to the 76 percent frozen Lake Ontario in the north.
Niagara Falls is visible midway between the lakes.
NASA’s Earth Observatory points out the sharp ice-water boundary near the mouth of Lake Erie.
It isn’t natural, and it’s called an ice boom.
But it’s reduced the amount of ice flowing into the Niagara River since 1964.
This year more than 200 pontoons for the boom were installed Dec. 15 after temperatures in Buffalo, New York hit 39 degrees Fahrenheit a week earlier.
According to the International Niagara Board of Control, the Lake Erie-Niagara River Ice Boom is installed to reduce ice jams and shoreline damage, while also maintaining the electrical power generated from the Niagara River.
Harsh weather forced late removal of the boom last year, and with record temperature lows, the average April 3 boom removal might again be too early.


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News BriefsHurricane Dennis Picking Up Steam, Eyeing Florida Land LOS ANGELES TIMES -- MIAMI
A strengthening Hurricane Dennis swirled menacingly along the southeast coast Friday, kicking up surf in Florida while threatening to blow ashore in the Carolinas early next week.
Forecasters said the storm’s maximum winds could rise to 110 miles an hour or more as it paralleled the coastline on a northward trajectory.
Late Friday the center of Dennis was located about 300 miles southeast of Cape Canaveral, and moving north-northwest at seven miles an hour. Top winds were estimated at 80 miles an hour.
Dennis pounded the northern-most Bahamas on Friday. Especially hard-hit was Great Abaco, which saw the eye of the storm pass over just before sunset. Ham radio operators reporters wind gusts of more than 60 miles an hour, according to forecasters at Miami’s National Hurricane Center.
Computer models predicted the hurricane would gain strength once it cleared the Bahamas and moved out over the warm waters of the Gulf Stream. Those same computers say that the hurricane would likely strike the Carolina coast sometime late Monday or early Tuesday.
Maryland Drought Aids Police in Hunting for Marijuana THE WASHINGTON POST -- The drought that’s aggravating home gardeners, pool owners, and golf course caretakers has been a boon to at least one group: police officers who hunt out marijuana plants.
With the shrubs and underbrush that generally conceal marijuana turning brown in the sweltering heat, carefully tended -- and religiously watered -- pot plants are sticking out like very sore, very green thumbs, law enforcement officials say.
Police in Maryland and Virginia regularly embark on airplane flights over private property and public parks in search of illicitly grown marijuana. Sgt. Kirk Holub, head of the Montgomery County, Md., Police Department’s narcotics division, said that from above, the “emerald green” of marijuana stands out in a field turned barren from lack of rain.
“It’s made it easier to identify the crops. It’s just a lot harder to find cover,” Holub said. This week alone, officials in Maryland have seized more than 100 marijuana plants. Arrests have nearly doubled, from 54 last year to about 100 so far this year.
So far this year, about 2,500 marijuana plants have been found in Maryland, up from 2,200 -- or $4 million worth -- at this time last year.
In Virginia, which hasn’t suffered the same rainfall deficits this summer as Maryland, officials have seized more than 7,500 plants, compared to roughly 10,000 seized in the same period last year, said First Sgt. J.C. Lewis, head of the Virginia State Police Marijuana Eradication Program.
The problem for marijuana farmers has to do with the stubby root structure of their chosen crop. The University of Mississippi’s Mamhoud Elsohly, who researches marijuana for the National Institute on Drug Abuse, the nation’s only legal provider of marijuana for research, said cannabis roots extend a scant six inches into the ground, unlike the roots of, say, cotton plants, which grow far deeper and require less water.
The Catch-22 has attracted the attention of the National Organization for the Reform of Marijuana Laws Foundation, a Washington-based pot-advocacy group. Marijuana growers “know if they go out and water the crops, it’ll draw attention,” said Allen St. Pierre, the group’s executive director, who added that several pot farmers have told him that they are “definitely concerned about their outdoor crops.”


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On-line casino sites generally supply a large video game option, including hundreds of slots, table games, video clip texas hold’em, live gambling enterprise video games, bingo video games, dynamic jackpots, as well as other specialized video games. At Cashmo, we do not simply adjust gambling establishment games to make them available on mobile. We just use online ports games that have actually been designed and constructed with mobile in mind from the very start. That produces a remarkable video gaming experience for our players– and that’s always our leading concern. Obviously, banking transactions are one of the most fragile and also, in the very same time, vital aspects of playing online with actual cash.
Yet an unique treat on this on-line gambling enterprise website isn’t ports, but live casino site games streamed straight from physical Grosvenor casino sites. Offer only applies to gamers who are citizens of United Kingdom. Minutes down payment EUR10, minimum wagering on sport EUR20, req certifying bets at min chances at 1/1.
In Keno, gamers pick numbers from a board that ranges from 1 via 80. The quantity a player wins depends upon the amount of of the randomly attracted keno numbers match the player’s chosen numbers, the amount of numbers the gamer selected initially and also ultimately, the amount the player wagered. The player can inspect the pay table to exercise just how much a wager and also suit mix would certainly win. At Mr Environment-friendly, there is a Keno draw every minute with possible to win on each draw.
Our welcome deal enables gamers to Deposit and Risk ₤ 50 on Live Casino site as well as get a ₤ 5 Bonus on selected real-time gambling establishment video games. When you have actually completed this, you can bet the real-time gambling establishment bonus offer on 21 readily available games from Advancement Gaming. We provide a classic on-line casino video games experience that will make you feel like a high-roller whenever you sign in. Without a doubt, no gambling enterprise online would be complete without timeless on-line roulette video games as well as blackjack variants. 21. co.uk also has a big series of Live Online casino video games like Live Roulette, Live Blackjack as well as Live Poker.
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With the real-time gambling establishment alternative, you’ll have the ability to get in touch with genuine dealers through HD streaming electronic cameras. Forget about computer systems that figure out where the roulette ball will certainly land or what blackjack card will be dealt following. Rather, you’ll have an actual dealership or croupier running the program with genuine cards and also a genuine roulette wheel. With 16 years of experience on top of the on the internet casino market, we at Casino.com have made a decision to utilize our understanding to offer you with all the info you need to end up being an expert yourself. We are no more an on the internet casino site; instead, our new goal is to compare the most effective online casino sites on the marketplace to help you discover what jobs best for you.
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There are promotions offered on different days of the week or throughout specific time periods. You can benefit from rewards on a regular basis, so ensure to look into the Promotions area on our casino website. You will require to register and also open up an account to play at Pink Gambling enterprise. The Gaming Commission calls for all players to register and also pass the KYC procedure. In this manner, you will verify that your info is precise and also you are a real individual entitled to gamble at a UK casino site.
There, you can develop a gambling enterprise account and begin playing. That stated, we have actually evaluated thousands of casinos to figure out how they treat their gamers, and afterwards taken into consideration neighborhood variables for every country with the assistance of regional testers. Gambling enterprises are after that bought from best to worst based upon our searchings for, so you need to be able to find your ideal choice near the top of this list.

domain: game


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If there is one thing that can make or break a garden, it is the tree.
No garden is complete without trees so choosing a tree according to the space available is very important.
Planting the wrong tree in a large pot in your garden, patio, or terrace or balcony is tantamount to inviting trouble.
Most of us urban dwellers do not have enough space to plant such magnificent trees as Gul Mohar, Jacquard, Indian Coral Tree, Indian Lilac and Mango.
However, pomegranates, guavas, apricots, papayas, bottle brushes, and laser stroke perennials, commonly called crepe myrtle, can make room for such small trees of any one color.
If you are short of space and want to plant a flowering tree, Ledger Stroemia will be best for you.
It can also be planted in a large pot or directly in the ground.
They bloom in pink, violet, purple, red, white or maroon flowers during the warmer months.
Pruning at the end of December each year helps control their volume.
They can also be prepared to provide shade in summer, and in winter when they need heat, they do not interfere with the passage of sunlight due to their lightness.
They thrive in the sun and in the shade.
This tree can be grown all over the country, even in the dry days of the monsoon, its flowers are open and fragrant the atmosphere.
If you want your only tree to be fruitful and grow in a hot city like Karachi, then lemons, papaya and chicory are the best choices.
In Lahore, Rawalpindi, Islamabad and Peshawar, there is no better tree than cane, especially the one which is small and can grow in a big pot and stays green all year round.
In the spring season, it will make your house fragrant and its juicy fruits will reward you for all your hard work.
These fruits will be much higher in quality and fragrance than the fruits found in the market.
You may be thinking that after planting a tree in a small place, you will not be able to grow anything else there but that is not the case for example, cannabis, lemons, grapefruit or any other stress fruit, these trees should be pruned in such a way that the trees grow outwards instead of upwards.
In addition, keeping the middle part of the tree clean will improve air circulation, which will also reduce the chances of any disease.
In this way a dense shade tree will be formed.
The branches of this tree, baskets and other such things would be perfect for hanging.
In this cool shade, petunia, fuchsia, fern, orchid and chlorophytum can be grown in pots of suitable size.
In addition, they will look very beautiful.
It is true that most trees do not allow grass to grow around their trunks, even under their shade. But pots can be placed on this empty land to solve this problem.
Unlike permanent grass, these temporary pots can be changed at any time.
Before planting a tree, consider the following:
What would be the height and spread of a mature tree and how deep its roots would be and how far it would spread.
Plant small trees at least 2 to 3 meters away from the house and four walls as their roots can damage the foundation of the house.
Take care of the location of underground water tanks, water and sewerage lines, underground power lines, etc.
Do not plant a tree in a place where its roots affect these things.
If there is even the slightest chance of the tree being tall, do not place it under the power lines so that it does cause trouble later.
If a tree growing in a pot grows too big, hand it over to someone who has a suitable place to plant it and plant another tree to commend yourself for working to improve the environment.

domain: hobby


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Report highlights the growing prominence of mobile shopping and its effect on digital commerce
A new report released by comScore shows that mobile shopping is on the rise. Shopping from a mobile devices is becoming more popular among consumers, and the sales coming from mobile shopping are boosting e-commerce spending numbers. Mobile commerce is still a small percentage of overall digital sales, representing some 11% of e-commerce. Despite this, however, mobile shopping is beginning to have a major impact on the e-commerce space, transforming the way merchants conduct business online.
Digital spending is on the rise among mobile consumers that enjoy shopping for and purchasing products online
The report from comScore shows that digital commerce has seen a major increase in spending thanks to mobile commerce. Consumers are embracing the idea of shopping for and purchasing products online with their smartphones and tablets. As retailers begin adopting better mobile commerce services and platforms, mobile shopping is expected to continue growing and influencing the overarching digital commerce space.
Mobile commerce saw a 47% increase in spending during the second quarter of this year
The report shows that mobile commerce grew by 47% during the second quarter of this year, significantly overshadowing the growth this sector had seen in previous quarters. By comparison, conventional e-commerce spending grew by 10%, while discretionary retail spending grew by just 3%. The report predicts that such growth is not likely to be sustainable throughout the remainder of the year, but mobile commerce is likely to continue gaining attention among consumers whose lives are tethered to mobile devices.
Mobile commerce adoption is on the rise despite certain challenges that consumers have faces in recent years
Mobile commerce has faced many challenges over the years, especially when it comes to the security of a consumer’s financial information. These challenges have slowed adoption somewhat, but consumers have not been dissuaded from shopping online with a mobile device and making mobile payments. The mobile space is likely to continue having a significant impact on e-commerce as a whole, especially as new mobile payments platforms are made available and people use these platforms more regularly.

domain: sociology


text:
|Publication number||US5496487 A|
|Application number||US 08/296,764|
|Publication date||Mar 5, 1996|
|Filing date||Aug 26, 1994|
|Priority date||Aug 26, 1994|
|Also published as||CA2198095A1, EP0777724A1, WO1996006922A1|
|Publication number||08296764, 296764, US 5496487 A, US 5496487A, US-A-5496487, US5496487 A, US5496487A|
|Inventors||Scott W. Capeci, David R. Nassano, Robert G. Welch|
|Original Assignee||The Procter & Gamble Company|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (36), Non-Patent Citations (2), Referenced by (30), Classifications (13), Legal Events (6)|
|External Links: USPTO, USPTO Assignment, Espacenet|
The present invention generally relates to a process for producing a high density detergent composition and, more specifically to an agglomeration process which utilizes existing spray drying towers for purposes of conditioning detergent agglomerates to enhance their flow properties for subsequent packaging and use in a granular detergent product. The process provides an especially useful and economical way in which existing "spray drying tower" detergent plants can be converted to "non-tower" agglomeration process plants.
Recently, there has been considerable interest within the detergent industry for laundry detergents which are "compact" and therefore, have low dosage volumes. To facilitate production of these so called low dosage detergents many attempts have been made to produce high bulk density detergents, for example with a density of 600 g/l or higher. The low dosage detergents are currently in high demand as they conserve resources and can be sold in small packages which are more convenient for consumers.
Generally, there are two primary types of processes by which detergent granules or powders can be prepared. The first type of process involves spray-drying an aqueous detergent slurry in a spray-drying tower to produce highly porous detergent granules. In the second type of process, the various detergent components are dry mixed after which they are agglomerated with a binder such as a nonionic or anionic surfactant. In both processes, the most important factors which govern the density of the resulting detergent granules are the density, porosity, particle size and surface area of the various starting materials and their respective chemical composition. These parameters, however, can only be varied within a limited range. Thus, a substantial bulk density increase can only be achieved by additional processing steps which lead to densification of the detergent granules.
There have been many attempts in the art for providing processes which increase the density of detergent granules or powders. Particular attention has been given to densification of spray-dried granules by post tower treatment. For example, one attempt involves a batch process in which spray dried or granulated detergent powders containing sodium tripolyphosphate and sodium sulfate are densified and spheronized in a Marumerizer®. This apparatus comprises a substantially horizontal, toughened, rotatable table positioned within and at the base of a substantially vertical, smooth walled cylinder. This process, however, is essentially a batch process and is therefore less suitable for the large scale production of detergent powders. More recently, other attempts have been made to provide a continuous processes for increasing the density of "post-tower" or spray dried detergent granules. Typically, such processes require a first apparatus which pulverizes or grinds the granules and a second apparatus which increases the density of the pulverized granules by agglomeration. These processes achieve the desired increase in density only by treating or densifying "post tower" or spray dried granules.
However, all of the aforementioned processes are directed primarily for densifying or otherwise processing "spray dried" granules. Currently, the relative amounts and types of materials subjected to spray drying processes in the production of detergent granules has been limited. For example, it has been difficult to attain high levels of surfactant in the resulting detergent composition, a feature which facilitates production of low dosage detergents. To alleviate such problems, the art and the industry have been addressing processes which entail agglomerating detergent compositions. For example, attempts have been made to agglomerate detergent builders by mixing zeolite and/or layered silicates in a mixer to form free flowing agglomerates. Other developments in this area of the art have provided agglomeration processes which ultimately result in fully formulated compact detergent compositions. As existing detergent plants which are fitted for spray-dried detergents are convened to the modem agglomeration process plants, a need has been identified for techniques and processes which can be easily and economically retro-fitted into such existing plants. It would therefore be desirable to have an agglomeration process for making detergent compositions which is more amenable and economical when implementing into existing spray-drying detergent plants.
Accordingly, there remains a need in the an to have an agglomeration process for continuously producing a high density detergent composition which facilitates conversion of existing spray-drying detergent plants to modem-day agglomeration process plants.
The following references are directed to densifying spray-dried granules: Appel et al, U.S. Pat. No. 5,133,924 (Lever); Bortolotti et al, U.S. Pat. No. 5,160,657 (Lever); Johnson et at, British patent No. 1,517,713 (Unilever); and Curtis, European Patent Application 451,894. The following references are directed to producing detergents by agglomeration: Beerse et at, U.S. Pat. No. 5,108,646 (Procter & Gamble); Hollingsworth et al, European Patent Application 351,937 (Unilever); and Swatling et al, U.S. Pat. No. 5,205,958.
The present invention meets the aforementioned needs in the an by providing a process which produces high density detergent compositions especially suitable for commercialization as a compact detergent product. The process can be easily retro-fitted into existing spray drying detergent-making production plants in that it utilizes existing equipment so as to economize the transition from "tower" based to "non-tower" based detergent manufacturing plants. In the instant process, conventional spray drying towers are used for purposes of conditioning detergent agglomerates produced by mixer/densifying equipment.
As used herein, the term "agglomerates" refers to particles formed by agglomerating more porous starting detergent ingredients (particles) which typically have a smaller mean particle size than the formed agglomerates. As used herein, the term "conditioning" refers to drying and/or cooling agglomerates to assist or enhance flow properties such as free flowability. All percentages and ratios used herein are expressed as percentages by weight (anhydrous basis) unless otherwise indicated. All documents are incorporated herein by reference. All viscosities referenced herein are measured at 70° C. (±5° C.) and at shear rates of about 10 to 100 sec-1.
In accordance with one aspect of the invention, a process for producing a high density detergent composition is provided. The process comprises the steps of: (a) agglomerating starting detergent ingredients in a mixer/densifier such that detergent agglomerates having a density of at least 650 g/l are formed: (b) conditioning the agglomerates in a spray. drying tower so as to enhance the free flowability of the detergent agglomerates; and (c) admixing adjunct detergent ingredients in the detergent agglomerates, thereby producing the high density granular detergent composition.
In accordance with another aspect of the invention, another process is provided. This process comprises the steps of: (a) preparing an aqueous slurry of starting detergent ingredients in a crutcher; (b) agglomerating the starting detergent ingredients in a mixer/densifier such that detergent agglomerates having a density of at least 650 g/l are formed; (c) conditioning the agglomerates in a spray-drying tower so as to enhance the free flowability of the detergent agglomerates; and (d) admixing adjunct detergent ingredients in the detergent agglomerates, thereby producing the high density granular detergent composition. The detergent product produced by the aforedescribed process embodiments is also contemplated by the invention.
Accordingly, it is an object of the invention to provide a process for producing high density detergent compositions which are suitable for commercialization as a compact detergent. It is also an object of the invention to provide such a process which can be easily and economically retrofitted into existing "tower" based detergent-making plants. These and other objects, features and attendant advantages of the present invention will become apparent to those skilled in the art from a reading of the following detailed description of the preferred embodiment and the appended claims.
FIG. 1 is a flow diagram of a process in accordance with one embodiment of the invention in which conditioning of detergent agglomerates and spray drying are carried forth simultaneously in a spray drying tower; and
FIG. 2 is a flow diagram of a process in accordance with another embodiment of the invention in which agglomerating mixer/densifiers are inserted between the crutcher and spray drying tower so as to conveniently convert an existing detergent plant to a modern agglomeration detergent-making facility.
Reference can be made to FIGS. 1 and 2 for purposes of illustrating two embodiments of the process invention described herein. In each embodiment, the process is retrofitted such that a conventional spray drying tower is economically utilized to dry the resulting detergent agglomerates.
With specific reference to FIG. 1, the first step of the process entails agglomeration of starting detergent ingredients 10 in at least one, preferably two or more serially positioned mixer/densifiers 12. Preferably, mixer/densifiers will entail initially treating starting detergent ingredients 10 in a high speed mixer/densifier (not specifically shown in FIG. 1) and subsequently in a moderate speed mixer/densifier (not specifically shown in FIG. 1) so as to form detergent agglomerates 14. It should be appreciated that any variety of mixer/densifiers can be used as long as the desired agglomerates 14 are produced. For compact detergents, the resulting agglomerates 14 will generally have a density of at least 650 g/l or higher. Typical mixer/densifiers include but are not limited to treatment in a high speed mixer/densifier such as a Lo/ dige Recycler CB-30 and then in a moderate speed mixer/densifier such as a Lo/ dige Recycler KM-300 "Ploughshare". Other configurations may include conventional twin-screw mixers, mixers commercially sold as Eirich, Schugi, O'Brien, and Drais mixers, and combinations of these and other mixers. Residence times of the starting detergent ingredients 10 is such mixer/densifiers will vary depending on the particular mixer/densifier and operating parameters. The agglomerates 14 are then fed into a conventional spray drying tower 16 having a counter current or concurrent stream of air, generally from about 0° C. to about 400° C., such that the agglomerates 14 can be conditioned as they pass through tower 16. In this regard, conditioning may entail the step of drying the agglomerates 14 in tower 16 or cooling the agglomerates 14 depending upon the selected temperature of air passing through tower 16.
Optionally, a conventional crutcher 18 can be set up parallel to the mixer/densifiers 12 so that a crutcher mix of liquid detergent ingredients 20 may be fed into tower 16 simultaneously with the agglomerates 14 such that the liquid detergent ingredients 20 are spray dried into granules while the agglomerates are dried (conditioned) in tower 16. In this way, the throughput and flexibility of the process is increased. The liquid detergent ingredients 20 may include a variety of detergent ingredients, but preferably includes at least a detersive surfactant, builder and water. At the bottom of tower 16, agglomerates 14 and spray dried granules formed from the detergent ingredients 20 exit together in stream 22. The agglomerates 14 and granules in stream 22 are then subjected to one or more finishing steps 24 including but not limited to screening, grinding, cooling, admixing additional detergent ingredients, all of which enhance the characteristics of a fully formulated commercialized granular detergent product 26. Typically, the finishing step 24 will include at least a cooling step and or a drying step. Those skilled in the art will appreciate that a wide variety of methods may be used to dry as well as cool the exiting detergent agglomerates without departing from the scope of the invention. By way of example, apparatus such as a fluidized bed can be used for drying while an airlift can be used for cooling should it be necessary.
Reference is now made to FIG. 2 which illustrates another process embodiment of the invention in which starting detergent ingredients 28 are fed to a crutcher 30 so as to produce a fully mixed stream of liquid starting detergent ingredients 32 for input into agglomeration mixer/densifiers 34. As with the previously described process embodiment, the mixer/densifiers 34 produce detergent agglomerates 36 which are fed into a spray drying tower 38 such that they are subjected to a counter current flow of air (from about 0° C. to about 400° C.) for purposes of conditioning the agglomerates 36. The dried agglomerates 40 exiting the tower 38 are then subjected to one or more finishing steps 42 as described above, after which the fully formulated detergent product 44 is produced and ready for commercialization. This embodiment is easily retrofitted into the conventional spray drying detergent-making plants in that the mixer/densifiers can simply be inserted or "piped" between the existing crutcher 30 and tower 38 without removing or otherwise moving large equipment.
Optionally, the processes described in FIGS. 1 and 2 can comprise the step of spraying an additional binder in the mixer/densifiers 12 and 34 to facilitate production of the desired detergent agglomerates. A binder is added for purposes of enhancing agglomeration by providing a "binding" or "sticking" agent for the detergent components. The binder is preferably selected from the group consisting of water, anionic surfactants, nonionic surfactants, polyethylene glycol, polyacrylates, citric acid and mixtures thereof. Other suitable binder materials including those listed herein are described in Beerse et al, U.S. Pat. No. 5,108,646 (Procter & Gamble Co.), the disclosure of which is incorporated herein by reference.
Another optional step contemplated by the present invention includes further processing the detergent agglomerates by adding a coating agent to improve flowability after they exit the mixer/densifiers 12 and 34 used in agglomeration or, in or between the selected mixer/densifiers used as the mixer/densifiers 12 and 34. For example, the coating agent can be added in the moderate speed mixer/densifier of a dual set-up as described previously in which a high speed mixer/densifier is followed by a moderate speed mixer densifier. Such coating agents can also be added further along the process, for example, during the finishing steps 24 and 42. This furthers enhances the condition of the detergent product streams 22 and 40 for use in the final detergent product 26 and 44. Preferably, the coating agent is selected from the group consisting of aluminosilicates, carbonates, silicates and mixtures thereof.
The process of the present invention can incorporate a wide variety of detergent ingredients which ultimately form part of the finished detergent product. Preferably, the starting detergent ingredients include at least a surfactant paste, a detergent builder and optionally, an anhydrous material.
The viscous surfactant paste used in the process has a viscosity of from about 500 cps to about 100,000 cps, more preferably from about 5,000 cps to about 75,000 cps, and contains from about 5% to about 70% and, more preferably from about 10% to about 60%, by weight of water. As mentioned previously, the viscosity is measured at 70° C. and at shear rates of about 10 to 50 sec.-1, preferably at 25 sec.-1. Furthermore, the surfactant comprises from about 25% to about 95%, more preferably from about 30% to about 80% of a detersive surfactant, and the balance water and/or other conventional detergent ingredients.
The surfactant can be selected from anionic, nonionic. zwitterionic, ampholytic and cationic classes and compatible mixtures thereof. Detergent surfactants useful herein are described in U.S. Pat. No. 3,664,961, Norris, issued May 23, 1972, and in U.S. Pat. No. 3,919,678, Laughlin et al., issued Dec. 30, 1975, both of which are incorporated herein by reference. Useful cationic surfactants also include those described in U.S. Pat. No. 4,222,905, Cockrell, issued Sep. 16, 1980, and in U.S. Pat. No. 4,239,659, Murphy. issued Dec. 16, 1980, both of which are also incorporated herein by reference. Of the surfactants, anionics and nonionics are preferred and anionics are most preferred.
The following are representative examples of detergent surfactants useful in the present surfactant paste. Water-soluble salts of the higher fatty acids, i.e., "soaps", are useful anionic surfactants in the compositions herein. This includes alkali metal soaps such as the sodium, potassium, ammonium, and alkylolammonium salts of higher fatty acids containing from about 8 to about 24 carbon atoms, and preferably from about 12 to about 18 carbon atoms. Soaps can be made by direct saponification of fats and oils or by the neutralization of free fatty acids. Particularly useful are the sodium and potassium salts of the mixtures of fatty acids derived from coconut oil and tallow, i.e., sodium or potassium tallow and coconut soap.
Additional anionic surfactants which suitable for use herein include the water-soluble salts, preferably the alkali metal, ammonium and alkylolammonium salts, of organic sulfuric reaction products having in their molecular structure an alkyl group containing from about 10 to about 20 carbon atoms and a sulfonic acid or sulfuric acid ester group. (Included in the term "alkyl" is the alkyl portion of acyl groups.) Examples of this group of synthetic surfactants are the sodium and potassium alkyl sulfates, especially those obtained by sulfating the higher alcohols (C8-18 carbon atoms) such as those produced by reducing the glycerides of tallow or coconut oil; and the sodium and potassium alkylbenzene sulfonates in which the alkyl group contains from about 9 to about 15 carbon atoms, in straight chain or branched chain configuration, e.g., those of the type described in U.S. Pat. Nos. 2,220,099 and 2,477,383. Especially valuable are linear straight chain alkylbenzene sulfonates in which the average number of carbon atoms in the alkyl group is from about 11 to 13, abbreviated as C11-13 LAS.
Other anionic surfactants suitable for use herein are the sodium alkyl glyceryl ether sulfonates, especially those ethers of higher alcohols derived from tallow and coconut oil; sodium coconut oil fatty acid monoglyceride sulfonates and sulfates; sodium or potassium of ethylene oxide per molecule and wherein the alkyl groups contain from about 8 to about 12 carbon atoms; and sodium or potassium salts of alkyl ethylene oxide ether sulfates containing about 1 to about 10 units of ethylene oxide per molecule and wherein the alkyl group contains from about 10 to about 20 carbon atoms.
In addition, suitable anionic surfactants include the water-soluble salts of esters of alpha-sulfonated fatty acids containing from about 6 to 20 carbon atoms in the fatty acid group and from about 1 to 10 carbon atoms in the ester group; water-soluble salts of 2-acyloxyalkane-1-sulfonic acids containing from about 2 to 9 carbon atoms in the acyl group and from about 9 to about 23 carbon atoms in the alkane moiety; water-soluble salts of olefin and paraffin sulfonates containing from about 12 to 20 carbon atoms; and beta-alkyloxy alkane sulfonates containing from about 1 to 3 carbon atoms in the alkyl group and from about 8 to 20 carbon atoms in the alkane moiety.
Preferred anionic surfactants are C10-18 linear alkylbenzene sulfonate and C10-18 alkyl sulfate. If desired, low moisture (less than about 25% water) alkyl sulfate paste can be the sole ingredient in the surfactant paste. Most preferred are C10-18 alkyl sulfates, linear or branched, and any of primary, secondary or tertiary. A preferred embodiment of the present invention is wherein the surfactant paste comprises from about 20% to about 40% of a mixture of sodium C10-13 linear alkylbenzene sulfonate and sodium C12-16 alkyl sulfate in a weight ratio of about 2:1 to 1:2. Another preferred embodiment of the detergent composition includes a mixture of C10-18 alkyl sulfate and C10-8 alkyl ethoxy sulfate in a weight ratio of about 80:20.
Water-soluble nonionic surfactants are also useful in the instant invention. Such nonionic materials include compounds produced by the condensation of alkylene oxide groups (hydrophilic in nature) with an organic hydrophobic compound, which may be aliphatic or alkyl aromatic in nature. The length of the polyoxyalkylene group which is condensed with any particular hydrophobic group can be readily adjusted to yield a water-soluble compound having the desired degree of balance between hydrophilic and hydrophobic elements.
Suitable nonionic surfactants include the polyethylene oxide condensates of alkyl phenols, e.g., the condensation products of alkyl phenols having an alkyl group containing from about 6 to 15 carbon atoms, in either a straight chain or branched chain configuration, with from about 3 to 12 moles of ethylene oxide per mole of alkyl phenol. Included are the water-soluble and water-dispersible condensation products of aliphatic alcohols containing from 8 to 22 carbon atoms, in either straight chain or branched configuration, with from 3 to 12 moles of ethylene oxide per mole of alcohol.
An additional group of nonionics suitable for use herein are semi-polar nonionic surfactants which include water-soluble amine oxides containing one alkyl moiety of from about 10 to 18 carbon atoms and two moieties selected from the group of alkyl and hydroxyalkyl moieties of from about 1 to about 3 carbon atoms; water-soluble phosphine oxides containing one alkyl moiety of about 10 to 18 carbon atoms and two moieties selected from the group consisting of alkyl groups and hydroxyalkyl groups containing from about 1 to 3 carbon atoms; and water-soluble sulfoxides containing one alkyl moiety of from about 10 to 18 carbon atoms and a moiety selected from the group consisting of alkyl and hydroxyalkyl moieties of from about 1 to 3 carbon atoms.
Preferred nonionic surfactants are of the formula R1 (OC2 H4)n OH, wherein R1 is a C10 -C16 alkyl group or a C8 -C12 alkyl phenyl group, and n is from 3 to about 80. Particularly preferred are condensation products of C12 -C15 alcohols with from about 5 to about 20 moles of ethylene oxide per mole of alcohol, e.g., C12 -C15 alcohol condensed with about 6.5 moles of ethylene oxide per mole of alcohol.
Additional suitable nonionic surfactants include polyhydroxy fatty acid amides of the formula ##STR1## wherein R is a C9-17 alkyl or alkenyl, R1 is a methyl group and Z is glycidyl derived from a reduced sugar or alkoxylated derivative thereof. Examples are N-methyl N-1-deoxyglucityl cocoamide and N-methyl N-1-deoxyglucityl oleamide. Processes for making polyhydroxy fatty acid amides are known and can be found in Wilson, U.S. Pat. No. 2,965.576 and Schwartz, U.S. Pat. No. 2,703,798, the disclosures of which are incorporated herein by reference.
Ampholytic surfactants include derivatives of aliphatic or aliphatic derivatives of heterocyclic secondary and tertiary amines in which the aliphatic moiety can be straight chain or branched and wherein one of the aliphatic substituents contains from about 8 to 18 carbon atoms and at least one aliphatic substituent contains an anionic water-solubilizing group.
Zwitterionic surfactants include derivatives of aliphatic, quaternary, ammonium, phosphonium, and sulfonium compounds in which one of the aliphatic substituents contains from about 8 to 18 carbon atoms.
Cationic surfactants can also be included in the present invention. Cationic surfactants comprise a wide variety of compounds characterized by one or more organic hydrophobic groups in the cation and generally by a quaternary nitrogen associated with an acid radical. Pentavalent nitrogen ring compounds are also considered quaternary nitrogen compounds. Suitable anions are halides, methyl sulfate and hydroxide. Tertiary amines can have characteristics similar to cationic surfactants at washing solution pH values less than about 8.5. A more complete disclosure of these and other cationic surfactants useful herein can be found in U.S. Pat. No. 4,228,044, Cambre, issued Oct. 14, 1980. incorporated herein by reference.
Cationic surfactants are often used in detergent compositions to provide fabric softening and/or antistatic benefits. Antistatic agents which provide some softening benefit and which are preferred herein are the quaternary ammonium salts described in U.S. Pat. No. 3,936,537, Baskerville. Jr. et al., issued Feb. 3, 1976, the disclosure of which is incorporated herein by reference.
The starting detergent ingredients of the present process can, and preferably do, also comprise a detergent builder in an amount from about 1% to about 90%, more preferably from about 5% to about 70% and most preferably from about 10% to about 50% by weight. Builders are generally selected frown the various water-soluble, alkali metal, ammonium or substituted ammonium phosphates, polyphosphates, phosphonates, polyphosphonates, carbonates, silicates, borates, polyhydroxy sulfonates, polyacetates, carboxylates, and polycarboxylates. Preferred are the alkali metal, especially sodium, salts of the above. Preferred for use herein are the phosphates, carbonates, silicates, C10-18 fatty acids, polycarboxylates, and mixtures thereof. More preferred are sodium tripolyphosphate, tetrasodium pyrophosphate, citrate, tartrate mono- and di-succinates, sodium silicate, and mixtures thereof (see below). A specific preferred group of builders is selected from the group consisting of citrates, silicates, aluminosilicates and mixtures thereof.
Specific examples of inorganic phosphate builders are sodium and potassium tripolyphosphate, pyrophosphate, polymeric metaphosphate having a degree of polymerization of from about 6 to 21, and orthophosphates. Examples of polyphosphonate builders are the sodium and potassium salts of ethylene diphosphonic acid, the sodium and potassium salts of ethane 1-hydroxy-1,1-diphosphonic acid and the sodium and potassium salts of ethane, 1,1,2-triphosphonic acid. Other phosphorus builder compounds are disclosed in U.S. Pat. Nos. 3,159,581; 3,213,030; 3,422,021; 3,422,137; 3,400,176 and 3,400,148, all of which are incorporated herein by reference.
Examples of nonphosphorus, inorganic builders are sodium and potassium carbonate, bicarbonate, sesquicarbonate, tetraborate decahydrate, and silicates having a weight ratio of SiO2 to alkali metal oxide of from about 0.5 to about 4.0, preferably from about 1.0 to about 2.4. Water-soluble, nonphosphorus organic builders useful herein include the various alkali metal, ammonium and substituted ammonium polyacetates, carboxylates, polycarboxylates and polyhydroxy sulfonates. Examples of polyacetate and polycarboxylate builders are the sodium, potassium, lithium, ammonium and substituted ammonium salts of ethylene diamine tetraacetic acid, nitrilotriacetic acid, oxydisuccinic acid, mellitic acid, benzene polycarboxylic acids, and citric acid.
Polymeric polycarboxylate builders are set forth in U.S. Pat. No. 3,308,067, Diehl, issued Mar. 7, 1967, the disclosure of which is incorporated herein by reference. Such materials include the water-soluble salts of homo- and copolymers of aliphatic carboxylic acids such as maleic acid, itaconic acid, mesaconic acid, fumaric acid, aconitic acid, ultraconic acid and methylenemalonic acid. Some of these materials are useful as the water-soluble anionic polymer as hereinafter described, but only if in intimate admixture with the non-soap anionic surfactant.
Other suitable polycarboxylates :for use herein are the polyacetal carboxylates described in U.S. Pat. No. 4,144,226, issued Mar. 13, 1979 to Crutchfield et al, and U.S. Pat. No. 4,246,495, issued Mar. 27, 1979 to Crutchfield et al, both of which are incorporated herein by reference. These polyacetal carboxylates can be prepared by bringing together under polymerization conditions an ester of glyoxylic acid and a polymerization initiator. The resulting polyacetal carboxylate ester is then attached to chemically stable end groups to stabilize the polyacetal carboxylate against rapid depolymerization in alkaline solution, convened to the corresponding salt, and added to a detergent composition. Particularly preferred polycarboxylate builders are the ether carboxylate builder compositions comprising a combination of tartrate monosuccinate and tartrate disuccinate described in U.S. Pat. No. 4,663,071, Bush et al., issued May 5, 1987, the disclosure of which is incorporated herein by reference.
Water-soluble silicate solids represented by the formula SiO2.M2 O, being an alkali metal, and having a SiO2 :M2 O weight ratio of from about 0.5 to about 4.0, are useful salts in the detergent granules of the invention at levels of from about 2% to about 15% on an anhydrous weight basis, preferably from about 3% to about 8%. Anhydrous or hydrated particulate silicate can be utilized, as well.
Optionally, an anhydrous material may be used in the present process in an amount from about 1% to about 70%. more preferably from about 5% to about 50%, and most preferably from about 5% to about 20%. As used herein, the term "anhydrous material" means any hydratable material which is capable of absorbing water rapidly. Preferably, the anhydrous material is selected from the group consisting of carbonates, sulfates, carbonate/sulfate complexes, and mixtures thereof. While not intending to be limiting, other suitable anhydrous materials include powdered tripolyphosphate, powdered tetrasodium pyrophosphate, titrate, powdered carbonates such as calcium carbonate, powdered sulfates and mixtures thereof. Further, aluminosilicates disclosed in Corkill et al, U.S. Pat. No. 4,605,509 (Procter & Gamble), the disclosure of which is incorporated herein by reference, typically which have been over dried are suitable for use herein. Also, the anhydrous material can be selected from group consisting of absorbent gelling materials, cellulose-based materials and combinations thereof. Suitable absorbent gelling materials are disclosed in Brandt et al, U.S. Pat. Re. No. 32,649 (commonly assigned), the disclosure of which is incorporated herein by reference. Suitable cellulose-based materials are disclosed in Herron, U.S. Pat. No. 5,183,707 and Herron et al. U.S. Pat. No. 5,137,537, the disclosures of which are incorporated by reference. Most preferably, sodium carbonate, magnesium sulfate has been found to be effective in the process described herein.
The starting or entering detergent components in the present process can also include any number of additional ingredients or the process can include the step of admixing such ingredients in the finishing steps 24 and 42 shown in FIGS. 1 and 2, respectively. These include other detergency builders, bleaches, bleach activators, suds boosters or suds suppressors, anti-tarnish and anticorrosion agents, soil suspending agents, soil release agents, germicides, pH adjusting agents, non-builder alkalinity sources, chelating agents, smectite clays, enzymes, enzyme-stabilizing agents and perfumes. See U.S. Pat. No. 3,936,537, issued Feb. 3, 1976 to Baskerville, Jr. et al., incorporated herein by reference. In a preferred embodiment, the process admixes adjunct ingredients selected from the group consisting of bleaching agents, bleach activators, enzymes, polymeric anti-redeposition agents, polymeric dispersants, polymeric soil release agents, chelants, perfumes, dye transfer inhibitors and mixtures thereof.
Bleaching agents and activators are described in U.S. Pat. No. 4,412,934, Chung et al., issued Nov 1, 1983, and in U.S. Pat. No. 4,483,781, Hartman, issued Nov. 20, 1984, both of which are incorporated herein by reference. Chelating agents are also described in U.S. Pat. No. 4,663,071, Bush et al., from Column 17, line 54 throngh Column 18, line 68, incorporated herein by reference. Suds modifiers are also optional ingredients and are described in U.S. Pat. Nos. 3,933,672, issued Jan. 20, 1976 to Bartoletta et al., and 4,136,045, issued Jan. 23, 1979 to Gault et al., both incorporated herein by reference.
Suitable smectite clays for use herein are described in U.S. Pat. No. 4,762,645, Tucker et al, issued Aug. 9, 1988, Column 6, line 3 through Column 7, line 24, incorporated herein by reference. Suitable additional detergency builders for use herein are enumerated in the Baskerville patent, Column 13, line 54 through Column 16, line 16, and in U.S. Pat. No. 4,663,071, Bush et al, issued May 5, 1987, both incorporated herein by reference.
In order to make the present invention more readily understood, reference is made to the following examples, which are intended to be illustrative only and not intended to be limiting in scope.
This Example illustrates the process of the invention which produces free flowing, crisp, high density detergent composition. Two feed streams of various starting detergent ingredients are continuously fed, at a rate of 1400 kg/hr, into a Lo/ dige CB-30 mixer/densifier, one of which comprises a surfactant paste containing surfactant and water and the other stream containing starting dry detergent material containing aluminosilicate and sodium carbonate. The rotational speed of the shaft in the Lo/ dige CB-30 mixer/densifier is about 1400 rpm and the mean residence time is about 5-10 seconds. The contents from the Lo/ dige CB-30 mixer/densifier are continuously fed into a Lo/ dige KM-600 mixer/densifier for further agglomeration during which the mean residence time is about 6 minutes. The resulting detergent agglomerates are then fed to a 10 ft. diameter spraying tower (residence time 15--30 seconds. 200°-300° C.) and then to an airlift for cooling. An additional side stream of liquid detergent ingredients are fed from a conventional crutcher into the tower, as well. The crotchet mix contains a surfactant, a detergent builder, water and other adjunct detergent ingredients. The detergent agglomerate granules (wherein e ratio of granules to agglomerates is 60:40) are then screened with conventional screening apparatus and subjected to a grinding o ration resulting in a uniform particle size distribution. The composition of the detergent agglomerates exiting the airlift is set forth in Table I below:
TABLE I______________________________________Component % Weight______________________________________C14-15 alkyl sulfate/alkyl ethoxy sulfate 30.0Aluminosilicate 37.8Sodium carbonate 19.1Misc. (water, perfume, etc.) 13.1 100.0______________________________________
Additional detergent ingredients including perfumes, brighteners and enzymes are sprayed onto or admixed to the agglomerates/granules described above in the finishing step to result in a fully formulated finished detergent composition. The relative proportions of the overall finished detergent composition produced by the process of instant process is presented in Table II below:
TABLE II______________________________________Component (% weight)______________________________________C14-15 alkyl sulfate/C14-15 alkyl ethoxy sulfate/C12 29.2linear alkylbenzene sulfonatePolyacrylate (MW = 4500) 2.7Polyethylene glycol (MW = 4000) 0.6Sodium Sulfate 6.7Aluminosilicate 30.2Sodium carbonate 25.0Protease enzyme 0.3Lipase enzyme 0.3Minors (water, perfume, etc.) 10.0 100.0______________________________________
The density of the resulting detergent composition is 760 g/l, the mean particle size is 459 microns.
Having thus described the invention in detail, it will be obvious to those skilled in the art that various changes may be made without departing from the scope of the invention and the invention is not to be considered limited to what is described in the specification.
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|US3842888 *||Feb 1, 1973||Oct 22, 1974||Colgate Palmolive Co||Apparatus for introducing ingredients into a spray drying tower|
|US3882034 *||Feb 11, 1974||May 6, 1975||Colgate Palmolive Co||Simultaneous formation of expanding borax particles and spray dried detergents|
|US4005987 *||Sep 30, 1974||Feb 1, 1977||Metallgesellschaft Aktiengesellschaft||Process for drying moist materials, particularly crystalline solids containing water of hydration|
|US4244698 *||May 2, 1978||Jan 13, 1981||The Dow Chemical Company||Method for drying magnesium sulfate|
|US4261958 *||Apr 11, 1978||Apr 14, 1981||Pevzner Ilya Z||Process for the production of sodium aluminate|
|US4482630 *||Nov 21, 1983||Nov 13, 1984||Colgate-Palmolive Company||Siliconate-coated enzyme|
|US4487710 *||Mar 1, 1982||Dec 11, 1984||The Procter & Gamble Company||Granular detergents containing anionic surfactant and ethoxylated surfactant solubility aid|
|US4806261 *||Apr 11, 1988||Feb 21, 1989||Colgate-Palmolive Co.||Detersive article|
|US4818424 *||Apr 29, 1988||Apr 4, 1989||Lever Brothers Company||Spray drying of a detergent containing a porus crystal-growth-modified carbonate|
|US4846409 *||Sep 28, 1987||Jul 11, 1989||Bayer Aktiengesellschaft||Process for the preparation of granules|
|US4894117 *||Apr 28, 1988||Jan 16, 1990||Colgate-Palmolive Company||Process for manufacturing high bulk density particulate fabric softening synthetic anionic organic detergent compositions|
|US4919847 *||Jun 3, 1988||Apr 24, 1990||Colgate Palmolive Co.||Process for manufacturing particulate detergent composition directly from in situ produced anionic detergent salt|
|US4946653 *||Feb 1, 1983||Aug 7, 1990||Bayer Aktiengesellschaft||Process for the simultaneous classification and regulated, continuous discharge of particulate material from fluidized bed reactors|
|US5108646 *||Oct 26, 1990||Apr 28, 1992||The Procter & Gamble Company||Process for agglomerating aluminosilicate or layered silicate detergent builders|
|US5133924 *||Nov 2, 1989||Jul 28, 1992||Lever Brothers Company||Process for preparing a high bulk density granular detergent composition|
|US5139749 *||Jun 22, 1990||Aug 18, 1992||Tas, Inc.||Fluidized calcining process|
|US5160657 *||Mar 19, 1990||Nov 3, 1992||Lever Brothers Company, Division Of Conopo, Inc.||Detergent compositions and process for preparing them|
|US5198145 *||Dec 6, 1991||Mar 30, 1993||Fmc Corporation||Dry detergent compositions|
|US5205958 *||Mar 18, 1991||Apr 27, 1993||The Clorox Company||Zeolite agglomeration process and product|
|US5366652 *||Aug 27, 1993||Nov 22, 1994||The Procter & Gamble Company||Process for making high density detergent agglomerates using an anhydrous powder additive|
|AU118692A *||Title not available|
|EP0351937B1 *||Apr 27, 1989||Feb 9, 1994||Unilever Plc||Detergent compositions and process for preparing them|
|EP0451894A1 *||Mar 25, 1991||Oct 16, 1991||Unilever N.V.||High bulk density granular detergent compositions and process for preparing them|
|EP0510746A2 *||Apr 7, 1992||Oct 28, 1992||THE PROCTER & GAMBLE COMPANY||Process for preparing condensed detergent granules|
|GB1517713A *||Title not available|
|1||Naviglio and Moriconi, "Detergents Manufacture," Soap/Cosmetics/Chemical Specialties, Sep. 1987, pp. 34-37, 54-56.|
|2||*||Naviglio and Moriconi, Detergents Manufacture, Soap/Cosmetics/Chemical Specialties, Sep. 1987, pp. 34 37, 54 56.|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US6121229 *||Jun 5, 1997||Sep 19, 2000||The Procter & Gamble Company||Process for making a detergent composition by non-tower process|
|US6136777 *||Jun 5, 1997||Oct 24, 2000||The Procter & Gamble Company||Process for making a detergent composition by non-tower process|
|US6150323 *||Jun 5, 1997||Nov 21, 2000||The Procter & Gamble Company||Process for making a detergent composition by non-tower process|
|US6172034 *||Jun 5, 1997||Jan 9, 2001||The Procter & Gamble||Process for making a detergent composition by non-tower process|
|US6211137 *||Jun 5, 1997||Apr 3, 2001||The Procter & Gamble Company||Process for making a detergent composition by non-tower process|
|US6211138 *||Jun 5, 1997||Apr 3, 2001||The Procter & Gamble Company||Process for making a detergent composition by non-tower process|
|US6391844 *||Jun 5, 1997||May 21, 2002||The Procter & Gamble Company||Process for making a detergent composition by non-tower process|
|US7910533||Mar 22, 2011||The Procter & Gamble Company||Solid laundry detergent composition comprising anionic detersive surfactant and calcium-augmented technology|
|US7910534||Aug 16, 2006||Mar 22, 2011||The Procter & Gamble Company||Solid laundry detergent composition comprising alkyl benzene sulphonate and a hydratable material|
|US8129323||Aug 16, 2006||Mar 6, 2012||The Procter & Gamble Company||Solid laundry detergent composition comprising alkyl benzene sulphonate, carbonate salt and carboxylate polymer|
|US8933131||Jan 11, 2011||Jan 13, 2015||The Procter & Gamble Company||Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same|
|US9193937||Feb 17, 2012||Nov 24, 2015||The Procter & Gamble Company||Mixtures of C10-C13 alkylphenyl sulfonates|
|US20030203832 *||Apr 15, 2003||Oct 30, 2003||The Procter & Gamble Company||Low organic spray drying process and composition formed thereby|
|US20060263402 *||May 19, 2006||Nov 23, 2006||The Procter & Gamble Company||Oil encapsulation|
|US20070042926 *||Aug 16, 2006||Feb 22, 2007||Roberts Nigel P S||Process for preparing a solid laundry detergent composition, comprising at least two drying steps|
|US20070042927 *||Aug 16, 2006||Feb 22, 2007||Muller John Peter E||Solid laundry detergent composition comprising alkyl benzene sulphonate and a hydratable material|
|US20070042928 *||Aug 16, 2006||Feb 22, 2007||The Procter & Gamble Company||Solid laundry detergent composition comprising an alkyl benzene sulphonate-based anionic detersive surfactant system and a chelant system|
|US20070042931 *||Aug 16, 2006||Feb 22, 2007||Roberts Nigel P S||Solid laundry detergent composition comprising anionic detersive surfactant and highly porous carrier material|
|US20070042932 *||Aug 16, 2006||Feb 22, 2007||The Procter & Gamble Company||Solid laundry detergent composition comprising alkyl benzene sulphonate, carbonate salt and carboxylate polymer|
|US20080045435 *||Aug 15, 2006||Feb 21, 2008||Somerville Roberts Nigel Patri||Solid laundry detergent composition comprising anionic detersive surfactant and calcium-augmented technology|
|US20110166370 *||Jul 7, 2011||Charles Winston Saunders||Scattered Branched-Chain Fatty Acids And Biological Production Thereof|
|US20110171155 *||Jul 14, 2011||Thomas Walter Federle||Intermediates And Surfactants useful In Household Cleaning And Personal Care Compositions, And Methods Of Making The Same|
|EP1754776A1 *||Aug 19, 2005||Feb 21, 2007||The Procter and Gamble Company||A process for preparing a solid laundry detergent composition, comprising at least two drying steps|
|WO1997034991A1 *||Mar 12, 1997||Sep 25, 1997||Henkel Kommanditgesellschaft Auf Aktien||Method of manufacturing free-flowing granular washing or cleaning agents|
|WO2003093119A1||Apr 16, 2003||Nov 13, 2003||The Procter & Gamble Company||Paperboard carton having an audible locking sound|
|WO2007020608A1 *||Aug 17, 2006||Feb 22, 2007||The Procter & Gamble Company||A process for preparing a solid laundry detergent composition, comprising at least two drying steps|
|WO2011088089A1||Jan 12, 2011||Jul 21, 2011||The Procter & Gamble Company||Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same|
|WO2012112828A1||Feb 17, 2012||Aug 23, 2012||The Procter & Gamble Company||Bio-based linear alkylphenyl sulfonates|
|WO2012138423A1||Feb 16, 2012||Oct 11, 2012||The Procter & Gamble Company||Compositions comprising mixtures of c10-c13 alkylphenyl sulfonates|
|WO2016053080A1||Jul 16, 2015||Apr 7, 2016||Sime Darby Malaysia Berhad||Powder form of methyl ester sulphonates (mes) and process for producing the same|
|U.S. Classification||510/444, 510/323, 510/349, 510/352|
|International Classification||C11D11/00, C11D11/02, C11D17/06|
|Cooperative Classification||C11D11/0082, C11D11/02, C11D17/065|
|European Classification||C11D11/00D, C11D17/06H, C11D11/02|
|Jan 12, 1995||AS||Assignment|
Owner name: PROCTER & GAMBLE COMPANY, THE, OHIO
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:CAPECI, SCOTT W.;NASSANO, DAVID R.;WELCH, ROBERT G.;REEL/FRAME:007300/0272
Effective date: 19940826
|Sep 24, 1996||CC||Certificate of correction|
|Aug 30, 1999||FPAY||Fee payment|
Year of fee payment: 4
|Sep 24, 2003||REMI||Maintenance fee reminder mailed|
|Mar 5, 2004||LAPS||Lapse for failure to pay maintenance fees|
|May 4, 2004||FP||Expired due to failure to pay maintenance fee|
Effective date: 20040305

domain: chemistry


text:
The Warriors made it a goal to get younger all around the roster where they could, but especially at the center position. By letting the likes of David West, JaVale McGee, and Zaza Pachulia walk they opened the door for Damian Jones to finally get some valuable playing time on an NBA court.
He got more than just playing time, he actually was the Warriors’ starting center at the beginning of the season. While he showed flashes of his athletic potential, he ultimately struggled against the league’s more talented centers. His season came to end with a pectoral injury suffered in the loss to the Detroit Pistons earlier this season.
Jones is already under contract for next season, and his rehab will be closely monitored as he’ll look to have a role with the team next year (whether that is a starting role remains to be seen). Golden State wants to get young at the center position, but next season might be Jones’ final shot at proving his worth.


Thank you for your enquiry regarding the delivery bikes in Southgate and concerns from local residents.
Motorcycles are allowed to park for free in our on street pay and display bays which has been written into the Traffic Order for a number of years. This has never been an issue in the past but over the last 18 months we have received complaints/concerns about parking in these bays (including dedicated motorcycle bays) across the whole of the borough in areas where eateries can be found, not just in Southgate.
The Council’s parking contractor (NSL) continues to visit the location on a regular basis and enforce those parked in contravention, such as on the footway and will continue to do so despite the challenges faced as they ultimately return some time after the officer has left.
To find a solution to this growing issue we have established contacts with some of the key operators in the sector, other Council Departments and the Police to look at alternative options for motorbikes to park. In the meantime enforcement will continue.


text:
Jamiroquai Mix by JaBig. The Best Acid Jazz Soulful Deep House Lounge Music Remix Playlist
Fronted by lead singer Jay Kay, Jamiroquai were initially the most prominent component in the earlys London-based acid jazz movement, alongside groups such as Incognito, the James Taylor Quartet, and the Brand New Heavies. Subsequent albums have explored other musical directions such as pop, rock and electronica.
Jamiroquai have sold more than 35 million albums worldwide and won a Grammy Award in We're doing our best to make sure our content is useful, accurate and safe. If by any chance you spot an inappropriate comment while navigating through our website please use this form to let us know, and we'll take care of it shortly. Forgot your password? Retrieve it. Get promoted. Powered by OnRad. Think you know music? Test your MusicIQ here!
In Lyrics. By Artist. By Album. Discuss the Space Cowboy Lyrics with the community: 0 Comments. Notify me of new comments via email. Cancel Report. Create a new account.Zlatan ibrahimovic wife instagram
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Know any other songs by Jamiroquai? Don't keep it to yourself! Add it Here. Watch the song video Space Cowboy. Space Cowboy [Radio Edit]. Space Cowboy [Classic Radio Remix]. Space Cowboy [Album Version]. Space Cowboy [Classic Club Remix].
Space Cowboy [Instrumental]. Space Cowboy [Instrumental][Mix]. Michael J. Have you ever. Gibson the Rockstar Cat. Hidden Cities City's T…. David Gagne. Capitol Hill. David Farrell Melton.
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No customer reviews. There are 0 customer reviews and 1 customer rating.48000 after tax ireland
Unlimited One-Day Delivery and more. There's a problem loading this menu at the moment. Learn more about Amazon Prime. Back to top. Get to Know Us.Ev ery thing is good. Oh, I'm here ag ain. I'm glad I've found, Oh. I can re ly on.
Space Cowboy (Classic Radio)
This is the ret urn. Say, at the speed of che eba. Oh, you and I go dee per. Ooh- hoo Oh, and green. I'm co min' down. I can see clea rly. He's glad. Oh, that he found. I'd do with out him. Ev ery thing. Now that he's aro und. Sing online now. My friends are close at hand and all my in hi bit ions have dis app eared with out a trace. I'm glad I've found, Oh some bo dy who I can re ly on. This is the ret urn of the space cow boy in ter pla ne ta ry good vibe zone.
Say, at the speed of che eba Oh, you and I go dee per ba by, I have to get high to get by hit 'em! I can see clea rly so high in the sky a man with psy che de lic pic ture frames has hap pin ess to shade his eyes. He's glad Oh, that he found some bo dy who he can re ly on. Say, at the speed of che eba Oh, you and I go dee per ba by, I'll have to get high to get by.
Ev ery thing ev ery thing is good and brown now that now that he's aro und Oh- oh! Ev ery thing ev ery thing ev ery thing is so good and brown. Now that he's aro und now that he's aro und hey, now that he's aro und. Ev ery thing ev ery thing ev ery thing is so damn good and brown.
Now that he's aro und now that he's aro und hey! Say, at the speed of che eba Oh, you and I go dee per hey, ba by, I'll have to get high to get by, yeah.
Search for more songs. So happy to have discovered Lucky Voice. We'd never tried karaoke before, but this is so much fun!Space Cowboy is the first excerpt taken from the band's second album "The Return of the Space Cowboy". It is interesting to note that the edit of the single lasting 3. The versions of "Kids" and "Journey to Arnhemland" featured on several of the releases are the regular album versions.
This version is similar to the UK release but comes in a slimline jewel case. Some copies of this edition are said to have "Space Comboy" written on the spine instead of "Space Cowboy". Spain got a special edition housed in a carboard sleeve, just like the UK. It is on this release that the famous remixes of the track by David Morales first appeared. Specially for the US, the word "cheebah" has been erased from the chorus of the radio edit but not on the album version or on the remixes.
Space Cowboy (Jamiroquai song)
Beforehand, Sony distributed domestic singles with a promo sticker. The CD comes in a case with no insert.
This very scarce release uses the artowrk of "Stillness in Time". The first track is not stated as being a remix, it just says "Space Cowboy". This is the first UK Jamiroquai release promo or otherwise following the bands transition to Columbia records in early This 12" features the great "Stoned Again" version otherwise only seen on the Japanese "Space Cowboy" album and a special slightly longer edit version of the track.
This promo surfaced shortly before the release of "Stillness in Time" to promote the remixes of Space Cowboy featured on the single. The release year stated on the record is very likely wrong: it was pressed in and not This white label vinyl promo first surfaced in March This 12 inch vinyl one-sided promo first surfaced in February On the label of the vinyl it uses the widely used Jamiroquai font and the buffalo-man image, albeit back-to-front.
On 10 May the official Jamiroquai website at Jamiroquai. This stunning remix has been taking the clubs in London by storm in recent weeks. With Dave Morales's Space Cowboy classic club mix on the b-side it's going to be one gem you'll want to have in your record bag or iPod at all times.
In addition to this 12" vinyl release, UK digital download stores e. The Stoned Again remix originally appeared on the UK 12" vinyl release in Toggle navigation. European release 1.
Space Cowboy 3. Kids 5. European Maxi release This version is similar to the UK release but comes in a slimline jewel case. Journey to Arnhemland 5. Space Cowboy - Demo Version 4.
UK release 1. Australian release 1. Japanese release 1. US release It is on this release that the famous remixes of the track by David Morales first appeared. Space Cowboy - Radio Edit 3. Space Cowboy - Classic Radio Remix 4. Space Cowboy - Album Version 6. Space Cowboy - Classic Club Remix 7.The single additionally contained remixes by David Moraleswhich further put the single in club circulation.
The original iteration was recorded with the band's regular bassist Stuart Zender and uses a slap bass technique during the chorus. This version is commonly known as the "Stoned Again Mix" and was largely the version played on radio when the single was released.
The full "Stoned Again Mix" was a B-side on the 12" vinyl single, and a shorter 'radio edit' is the version included on the band's 'Greatest Hits' album, High Times: Singles A lengthy rendition of this version is usually the one performed live, sometimes extended to as much as telve minutes with additional instrumental parts, including wind instruments not on any recorded version.
The album version is noticably different; it is considerably longer with a different bassline played not by Stuart Zender but by an artist credited as "Mr. X" in the album sleeve notes.Devicenet cable length limit
Years later Zender himself on Instagram has revealed that the bass player who played on the song is Paul Powell. Cowboy Bebop scriptwriter Keiko Nobumoto said in an interview that the song "Space Cowboy" was one of the inspirations for Cowboy Bebop. It was directed by Vaughan Arnell and Anthea Bentonand mainly featured Jay Kay dancing around a blue room with multiple versions of him and the other band members appearing and disappearing.
Occasional breaks show the band members against a blacklight with marijuana-leaf motifs. The video makes use of motion control photography to allow a seemingly-continuous shot as the camera pans around the room. In America, another version of the video replaced the leaves with daisieswithout Jay's consent.
A video of the David Morales remix also exists. From Wikipedia, the free encyclopedia. Acid jazz funk. This section does not cite any sources. Please help improve this section by adding citations to reliable sources. Unsourced material may be challenged and removed. August Learn how and when to remove this template message.
Official Charts Company. Retrieved 18 March Anime News Network. Retrieved 29 August Retrieved 23 December Ultratop Retrieved 26 November Retrieved 30 May Les classement single. Swiss Singles Chart. Discography Gig in the Sky Radio Silence. Categories : singles songs singles Jamiroquai songs Music videos directed by Vaughan Arnell Songs about cannabis Songs about drugs Songs written by Jason Kay.
Hidden categories: CS1 Icelandic-language sources is Articles with short description Short description matches Wikidata Use dmy dates from June Use British English from June Articles with hAudio microformats Articles needing additional references from August All articles needing additional references Singlechart usages for Flanders Singlechart usages for France Singlechart usages for Scotland Singlechart called without artist Singlechart called without song Singlechart usages for Switzerland Singlechart usages for UK Singlechart usages for UKdance Singlechart usages for Billboarddanceclubplay Singlechart making named ref.Jamiroquai has always been a consistent proposition.
Entertainment Weekly : " Uncut : 3 stars out of 5 - "Jay Kay returns with another blast of super-slick soul No idle nostalgia broker, Jamiroquai is a funk-making machine with a bright future in the past Rolling Stone : 3 Stars out of 5 - " It's not exactly irresistible, but, really, what's the point of resisting it?
COVID Because of processes designed to ensure the safety of our employees, you may experience a delay in the shipping of your order. Thank you for your patience and understanding. We are grateful for your business and hope you are staying safe and healthy! Detailed Site Map of Links.
High Times: Singles CD.
Add to Cart. Radio Song previews provided courtesy of iTunes. Hey Floyd Song previews provided courtesy of iTunes. Jamiroquai also appears in this compilation Tracks of Disc 1 1.
Waiting For Tonight 2. I'm Outta Love 3. Genie in a Bottle 4. Here with Me 5. How To Save A Life 7.
Space Cowboy (Classic Radio)
Dancing In The Moonlight 8. Sunrise 9. This Ain't a Love Song That's Not My Name Play That Funky Music Lady Marmalade Shake Your Body Down to the Ground September Best Of My Love Pretty Little Liars 7.
Game of Thrones Popular Movies 1. Star Trek Beyond 6. Captain America: Civil War Popular Celebrities 1. Gina Rodriguez Popular Videos 1. The Man Who Saved Central City 3.
Day One of Twenty-Two Thousand, Give or Take 4. Game on, Charles 5. Three Queens, Two Tigers 6. Download the TV Guide app for iPhone, iPad and Android. One hundred 14-yr-old children were observed over 1 yr to find out if caries incidence and caries progression could be predicted in a low prevalence child population by means of well-known caries related factors.
The mean caries incidence was low (0. In only eight out of 35 children progressing lesions were demonstrated. Independent variables at baseline examination were caries prevalence, sucrose intake, fluoride exposure, oral hygiene, saliva secretion rate, and salivary concentrations of mutans streptococci and lactobacilli. A weak but statistically significant correlation was demonstrated between caries incidence and caries prevalence.
No other significant correlations were shown. It was concluded that caries activity could not be predicted in this population. Low disease prevalence was a major reason for the weak correlations. Create File See comment in PubMed Commons belowCommunity Dent Oral Epidemiol.
Klock B1, Emilson CG, Lind SO, Gustavsdotter M, Olhede-Westerlund AM. Author information1Bohuslandstinget, Partille, Sweden. AbstractOne hundred 14-yr-old children were observed over 1 yr to find out if caries incidence and caries progression could be predicted in a low prevalence child population by means of well-known caries related factors.
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domain: entertainment


text: I have to disaggree with the above commenter. I think that would look good on anyone. I would maybe make the bangs a little longer, but sideswept bang wont make your face look fuller. I think the layers will also slim your face down as well. it will be cute. if you do it, please post pics!!

domain: design


text: An array of novel and interventionist species conservation and ecosystem management strategies have been proposed and, in some cases, pursued in recent years: assisted colonization, ecosystem engineering, Pleistocene rewilding, de-extinction, frozen zoos, gene-drives, and conservation cloning. At the same time, the idea that the Earth has entered a new geological age in which humans are the dominant force on the planet has been rapidly gaining proponents. These two trends are connected. Accelerated rates of ecological change caused by human activities are what endangers so many species and creates the need for more interventionist conservation; and that we have entered a period of natural history defined by humanity’s influence is thought to create a responsibility to correct past wrongs as well as provide license for more actively designing the ecological future. We must take a more “hands-on” approach if we want to conserve species in the Anthropocene (Minteer and Collins; Camacho et al.; Donlan et al., “Re-Wilding North America”), and we need to become comfortable with that since we are now living in the Anthropocene (Marris; Ackerman; Ellis).


I’ve recently been experimenting with creating a 3D touch probe that I would like to use for things like engraving on non flat surfaces (that need to be scanned first). To find the center in holes when setting work origin etc. So I designed a DIY version of such a touch probe which I posted earlier on the forum in one of the DIY module threads:
The video just shows a continuity test and that the principle works. Still needs some small improvements but already quite satisfied with this so far.
The design files (OpenSCAD) can be found here:
It still lacks some documentation and pictures or video on the assembly. I’ll keep updating as I further work on the design.
A visualization of the design:
Of course, a next step is to have it talk with the Snapmaker so it can be used as an alternative probe (like the inductive sensor in the printhead). For this some hardware and software is needed. Since I’ve had some ESP32 devices laying around and this already has a CAN controller on board, I just needed a CAN transceiver to get it connected to the SnapMaker.
The current state of the code is to be found in this repository:
It’s a platformIO project so should be very easy to get started with if someone wants to experiment with it.
Again, still very rough and needs a significant amount of extra work (and some documentation like the wiring scheme, although simple). For now I can use my DIY probe perfectly when the printhead is connected to the controller as I can send messages with the right CAN Packet ID to indicate if it touches the bed yes or no when doing a Z-probe (G30) command or running the bed calibration. Haven’t checked yet if G38 works.
When the CNC head is connected it doesn’t work unfortunately as the G30 command doesn’t really do anything. To be investigated how that could be made to work. Might need a change in the code of the module and/or controller.
Some weirdness I’ve seen so far: between reboots the ID linked to the bed sensor (3D printhead) has been 0x605 and 0x604 . Still need to figure out how and where the ID is decided and how to know which one it should be.
To be continued. Any ideas and suggestions are definitely welcome