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Resene paint systems fire ratings. You can reach us at 8668847594.
NAFFCO provides fire retardant paint that will protect the structure of your building during a fire.
Fire rated paint for plywood. Our range of paint can be applied to steel structures concrete and more for a high level of protection. Protect your building as much as you can and build with Chicago Flameproofs fire resistant plywood today. National Construction Code NCC Volume One Specification C110 and A24 of the Building Code of Australia.
Meets new Fire Regulations standard. Another advantage of the product is its user-friendliness. A range of FR Birch products are available for Railway applications under EN45545-2.
Thermoguard Timbercoat is a durable fire protection paint for interior and exterior timber surfaces. 50 out of 5 stars 3. Rust-Oleum 248903 12-Ounce 2000 Degree Flat Black Automotive High Heat Spray Paint.
Firetect Fire-Poof 5 gal. White Flat Latex Intumescent Fireproofing Flame Retardant Paint Coating for Wood. Firetect WT-102 1 gal.
Fire Resistant Paints and Coatings for Wood and Timber. We supply cementitious paint that can protect your structure for up to 4 hours. Fire retardant varnishes for wood and timber are clear protective coatings which protect and beautify the natural appearance of the surfaceNow available in wood stain colours as well they are ideal for fireproofing any size area of exposed wood beams boards MDF veneer etc.
FLAMEPROOF PLYWOOD – Packing quantities may vary with timber manufacturer. Painting fire treated plywood from Chicago Flameproof is completely fine. The listed Resene paint systems over the listed substrate have been fire tested using a cone calorimeter in accordance with ISO 5660 to determine Group Classification in accordance with New Zealand Building Code NZBC Verification Method CVM2 Appendix A.
Fire-retardant plywood for use in specialist regulated environments. Timber and wood are extremely flammable and for that reason we make sure that we stock a wide supply of timber and wood fire resistant paints and coatings for use on wood and timberThe risk of fire is a huge factor when it comes to health and safety so make sure that you are as protected as possible. Plywood is composed of layers of wood glued together and its used often in home and commercial roof assemblies.
A unique range of fire-retardant professional wood finishing products formulated to upgrade or maintain the fire-rating of a wide variety of wood-based substrates including veneered panels solid hard- and softwoods plywood MDF and wood-composite boards. If a solid coat is desired some end users report that a high quality oil based stain blocking primer provides the best moisture shield and can help. As it can be applied on wood with a brush or a spray machine.
Plywood is fire proofed making it flame retardant to Euroclass C or B. Plywood Resene Aquaclear Semi-Gloss Resene Aquaclear Semi-Gloss 3 coats SR 12 sqmL 3 NZBC FAR3981 26mm Metrapanel Pre-primed Resene Fireguard SR 1 sqmL Resene SpaceCote Low Sheen SR 16 sqmL 1-S NZBC 1 NCC FH5334. 50 out of 5 stars 17 24995 249.
Fire Ratings of Resene Paint Systems. Fire rated means the plywood is pressure-treated to prevent fire ignition over a period of time–30 or 90 minutes. This avoided the cost of sprinklering the concealed spaces.
Firetect WT-102 5 gal. Black Flat Latex Intumescent Fireproofing Flame Retardant Paint Coating for Wood. R10 R1 R7 and HL12 and 3 are all provided for.
FlameOFF Fire Barrier paint can also be a good option to increase a wood structures fire rating as long as natural wood look is not relevant. Structural steel is the most commonly protected material but protection can include other materials such as sheet metal sheetrock composite panels and interior woods. Now that you know the answer to the question Is fire resistant plywood paintable please feel free to give Chicago Flameproof a call with any other questions you may have.
Fire Retardant Birch Plywood is available ex stock carrying a full CE1 Mark for structural use a standard not achieved by third party treatments. Amazons Choice for fire resistant paint. Latex Paint Additive 202 Flame Retardant – Fire Proofing Agent for Paint – 1 Gallon.
Fire-retardant coatings are available in clear and white finishes. White Flat Latex Intumescent Fireproofing Flame Retardant Paint Coating for Wood. Fire rated and fire retardant are two different classifications so its important to know the distinctions.
Please do not worry. Where a solid colour is required one or two coats of alkyd paint can be applied over the clear or white f ire-retardant coating with only a small increase in the flame -spread rating. Many end users report that they have successfully applied paint and stains to our fire retardant lumber and plywood products.
This plywood has been treated with fire retardant. Reports are that penetrating oil stains are likely to perform best. 60 minutes Fire Resistance in certain instances Expands to create a barrier insulating wood from heat and.
As its name might suggest our fire treated plywood is fire resistant. Class 0 furniture-grade fire retardant wood coatings. 47 out of 5 stars 3553.
Fire Retardant Spray for Fabric Wood Thatch More – Class A Flame Retardant Spray -Eco Safe – NFPA 701- ASTM E84-5 Gallon Pail of DRI-ONE by Desert Research Institute Inc. Our fire treated plywood can be used in the exact same way as untreated plywood is used yet it has so many more amazing benefits. FlameOFF Fire Barrier Paint is an intumescent paint that can be applied to most building materials.
BS EN Class B s1 d0 BS Class 1 Class O Surface Spread of Flame Can also achieve 30. Ideal for film sets theatres exhibitions and TV sets and all projects requiring safety and certification. Click here if you require coloured fire-retardant paints for wood and timber.

domain: chemistry


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Due to changes in the JobKeeper and JobSeeker schemes this article, originally posted 19 June 2020, has the below updates:
The Federal Government Economic and Fiscal update on Tuesday 21 July 2020 announced the extension of the JobKeeper and JobSeeker scheme with new rates and revised rules. For more information about these changes please see our recent Technical Update.
To stay up-to-date with COVID-19 related stimulus measures, please see Australian Government Coronavirus (COVID-19) Stimulus Measures.
We’ve seen fundamental changes to the Australian business environment in a short period as a result of COVID-19, with many business owners asking – what’s next?
While restrictions begin to ease in Australia, it’s evident that for business, risk will remain for some time – especially for high-risk industries. The sudden change to business environment we felt in March, doesn’t quite work in reverse. While we are seeing green shoots as businesses reopen, a return-to-normal will be slow and gradual and we will likely see sluggish economic activity as a result of the recession we are now in.
Over the past few months, we’ve seen many businesses go from panic, to information overload to an understanding of how they will make it through. Yet, while most businesses can see themselves making it through now, many aren’t thinking too far into the future.
With many relief packages – both public and private – ending in September, there’s a growing concern that without a transition plan, many Australian businesses deferring payments will now face a ‘debt (or fiscal) cliff’, and if unprepared, won’t survive.
While it’s true that Directors need to be planning for the here-and-now, they must also plan to deal with their accrued debts and assess whether they will make it past this debt cliff.
In this article, we take a recap on what’s happened, analyse the debt cliff that’s coming and direct businesses to rethink a way forward, to come out the other side.
This guide is focussed on building resilience and how to recover from a crisis, offering general guidance for companies on where to focus as we begin to look beyond the initial impact of coronavirus.
A quick recap
It’s important to understand what’s just happened, to understand what’s coming.
The panic phase | 12 March -22 March
As COVID-19 cases started growing, the government responded by enacting social distancing measures, restricting movement of its citizens and enforcing closures of certain businesses.
As this unfolded the response from our clients and businesses generally was concern and even a hint of panic. By mid-March our clients started to see revenues falling and many businesses were forced to close. The rising cases, rapid slowdown in economic activity and uncertainty of the situation was causing a lot of concern and this was reflected on the ASX, with the All Ordinaries bottoming in March (after a peak only a month earlier).
At this time, we were advising our Partners and clients on the use of Safe Harbour, risks of insolvent trading and restructuring options. There was genuine concern for solvency of many clients and contacts we spoke with. Those in tourism, retail, hospitality, sports, entertainment, hotels, accommodation and education were most impacted.
The information overload phase | 22 March, through to 7 April
As COVID-19 cases were rising and the economic impacts were rapidly emerging, the Government (and other stakeholders) announced new support measures almost every other day. We were beginning to see the evidence the Pandemic was having on trading revenue. Businesses went from panic, to a holding stage with cautious optimism as new measures were explained. The discussions we were having around Safe Harbour and insolvency were no longer critical, with the announcement of the suspension of insolvency laws until September.
During this time, our conversations were around understanding support measures, encouraging clients to build cash flows and understand their runway. As more measures were announced and understood many businesses came back from the brink – but only in terms of short term cash flow.
The realisation phase | 28 April
With the government announcing plans to ease restrictions, and government and other stakeholder support measures now released, some businesses were starting to see revenues stabilise and new norms understood – with the ability to now comprehend and forecast for the immediate future.
This was the first time businesses were able to forecast with some level of confidence since the Pandemic swept Australia. Most businesses were able to trade through on a cash flow basis for 6 months because of liability deferrals and Jobkeeper assistance. However, there were exceptions, with COVID-19 being the impetus for Australia’s first major corporate collapse, seeing business failures including Virgin, Tigerlily, Techfront, and Colette, who all went into Voluntary Administration.
A debt cliff coming
The next phase | September 2020 will be a critical juncture for business
With public and private institutions pumping money into business and households to reduce the financial impact of the Pandemic, many businesses have found they can carry on. However, while this is positive, very few businesses are looking beyond the six month period which ends in September.
Businesses need to remember that the stimulus money is only temporary. We’re yet to see if the Government will take a phased approach to cutting off these measures. So far it’s looking unlikely.
Some economists believe that Australia is in a position to be government-supported through a long, slow recovery stating that a sudden stop to government support could be detrimental to the economy.
At the same time, business debts are ‘ballooning’. Debts such as ATO debt, rent, payroll tax and loan repayments continue to accrue.
There is a security blanket that will be ripped out from under them in September… can businesses trade out the other side?
What other factors will impact recovery?
At the peak of the debt cliff are the various economic scenarios that are interdependent to Australia’s recovery, including: consumer behaviour, the recession, the health and safety of people and risk of further shutdowns to all, or parts of industry and community.
With Australia now in its first recession for 29 years, there will be higher unemployment rates – it’s predicted these will go into the double digits before sitting at around seven percent. It’s projected that house prices will decrease and this, coupled with COVID-19 concerns will likely drive lower consumer spending and economic activity. While restrictions begin to ease, trading won’t return to normal, but the pace of business will be gradual.
While the threat of COVID-19 remains in our community, there’s also material risk for individual businesses. For specific businesses that require close person to person contact – such as manufacturing, real estate and construction – extra precautions to keep people safe will impact efficiency, but limit the risk of more shutdowns. For businesses, there may be periodic shutdowns if cases occur amongst staff, or clusters emerge in the local community – or worse still if a second wave community outbreak were to occur – seeing a ‘w’ shaped economy return, rather than a ‘v’.
These considerations need to be factored into scenario plans alongside the debt cliff.
An industry perspective
It’s expected that while the shutdowns caused widespread pain for many industries others have fared better. This table looks at who benefited, who will bounce back and who is at most risk of longer tem pain.
Rethink: are you prepared for the debt cliff?
Businesses need to be planning now for the cliff and looking ahead to profitability or solvency once support measures expire. It’s also important to consider the other factors impacting recovery. This will mean a rethink on the way businesses do business. There are number of considerations your business should be looking at now to avoid falling from the debt cliff, including:
- When will your ATO / Payroll tax debts increase? Currently, deferrals end in September
- When will your bank debts increase? Loan repayment deferrals for mortgages and SME loans will end or moving to interest-only shortly
- When will landlord payments be due? Landlord / tenant code of conduct expires in September
- Will you be trading while insolvent? The insolvent trading moratorium ends September
- Will you have enough cash flow to pay staff? Job keeper expires in September
- Do you owe employee entitlements? These continue to accrue while on stand down
- How long will the goodwill last?
Watch the latest webinars from our experts across Australia, as they discuss the needs for your business now.
The top four things you can be doing now
Businesses must be looking at strategies that will see them through such as:
- Businesses need to accept and understand the debt cliff and begin pre-planning. Some businesses will fail if they are not planning for the repayment of their deferred liabilities
- Engage with stakeholders early and assess options. Stakeholders are more receptive to early intervention over late intervention and will look more favourably on you
- Constantly review your business models. As we move forward, some businesses will need to restructure to survive
- Continually assessing the macro and micro impacts is critical – there is still a high level of uncertainty. This includes the global impact which has the ability to impact local businesses.
As businesses begin to open up, there is optimism in the business environment. To ensure businesses put themselves in the best position beyond recovery, it’s important they plan beyond September. If you would need advice on your business, cash flow, solvency or business model, contact your local Partner today.

domain: news


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A group of protesters on Thursday stormed the Eagle Square, Abuja, throwing the area into confusion with fear-stricken workers scampering in various directions.
A correspondent of the News Agency of Nigeria, who was caught in the confusion, reported that the situation obstructed traffic flow as motorists were forced to either stand still or run into one another.
NAN also reports that the protesters blocked all major routes leading into the National Assembly, with the confusion getting even worse when security threw tear gas canisters in a bid to disperse the protesters.
The cause of the protest is still uncertain, but a Police source said that the protesters were members of the Islamic Movement of Nigeria.
NAN reports that members of the group stormed the National Assembly Complex, Abuja, on Tuesday, with some of them scaling its fence to force their way in.
Reports had indicated that the protesters disarmed some policemen stationed at the gate of the complex, injuring some of them in the process.
A Police source has also confirmed that 40 members of the group were arrested after the Tuesday clash with security personnel, with some of them set to be arraigned in court. [PUNCH]

domain: sociology


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College – July 17
Theodore Cox, a graduate of Mt. Lebanon High School, has been named to the spring dean’s list at The College of Wooster. Cox, a senior sociology major, achieved a grade point average of 3.65 or above.
Joseph Marcone and Alexander Conroy of Bethel Park were named to the spring dean’s list at Berklee College of Music.
The following students in the College of Arts & Sciences at Washington University in St. Louis were named to the spring dean’s list: Nathaniel Aidan Blecher of Upper St. Clair, and Michael Bowen Liu, Diya Damodaran Nagaraj and Bo Peng, all of Mt. Lebanon.
Jenna Smith of McMurray is one of nine Marietta College students who recently studied abroad for two weeks in Australia. The trip was part of an educational program set up by the College’s Athletic Training program. The trip also provided an opportunity to meet one of Australia’s most highly respected athletic trainers, Dr. Jenny McConnell. The group attended several lectures with McConnell and her colleagues, observed in a trainer’s room before a Bears rugby match and learned new tape-strapping techniques.
Smith is a graduate of Mt. Lebanon High School.


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Wedding Lightroom Presets » On Sale » from $15.00 now. Edit pictures like a Pro! Very easy to use. 1-Click automated install. Purchase now and Download in 5 seconds Showcase Your Creativity And Inspiration With Custom Wedding Invites. Add A Personal Touch And Stand Out From The Crowd With Personalized Wedding Invites WI Presets use the current (2012) process and Adobe Standard Profile. Please check if your camera platform is compatible with these camera calibration profiles before purchasing. For better result please adjust exposure, contrast & temperature to achieve your desired look 50 Premium Wedding Lightroom Presets. Requires: Lightroom 4 or better. Works with: DNG, TIFF, PSD, JPG, RAW. Adding a professional finish to your images will be a piece of cake with this massive Lightroom presets pack, which includes 50 different presets for enhancing your wedding photos Wedding Inspiration. Presets for Lightroom. Best @WI Presets Pack. More Details >>. Advertising & Promo. Your posts in @WI Instagram
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Mar 30, 2020 - 100 stunning FREE Lightroom presets--guaranteed to enhance your photos. Find the perfect preset for your needs Oct 30 2018. This witchy halloween wedding inspiration (Binding Ceremony) was inspired by both the modern witch and a twist of the 1800's Salem witch era. We wanted to create an elegant & romantic Halloween wedding theme that resonated with brides who want to have a uniquely different take to their wedding Review: Signature Edit's Clean & Classic Lightroom Presets. by Jes + Chris November 23, 2019. November 23, 2019. Read more. Business Tips Marketing Tips Photography Business Weddings
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Some people can say photography is not art. They say you don't need a special talent to be a photographer, you just need a camera then photography can't be art or everybody with a smartphone should be an artist!. Photography is the most accessible of the arts. As I wrote in my first post, I believe you have to make some decisions when you take a picture, so, for me, photography is a kind. .sleeklens.com Back during the days when I worked in a darkroom to produce my black and white and color prints, I loved going to galleries to see other photographers' work for inspiration
Here are our other favorite wedding photos we absolutely loved from the PRETTY community! Enjoy these 20+ photos as inspiration for your next wedding photoshoot. All of these gorgeous photos featured on this page were edited in Lightroom and/or Photoshop using Pretty Presets & Actions. Captured by the talented Arlene Garcia Wedding Text Presets - Wedding Text Presets Pack is a versatile After Effects template that contains 40 gorgeously designed and elegantly animated in and out text presets. They're so easy to use and they can be quickly added on to your TV shows, commercials, promotions, events, presentations, slideshows, special occasions, romantic moments, wedding & anniversary videos A number of our presets serve the moody artist well and are ideal for moody wedding photography, emotive portraiture, editorial/fashion photography and landscapes, dramatic flat lays, or rich contrast food and product photography. Moody presets within our collection include: TERRAIN, WOLF PACK, LXC, and BASECAMP Wedding Lightroom Presets Vol. 2. These wedding photography presets feature 22 different professional presets to help your wedding photos stand out. Taking the perfect wedding photo has never been easier. 44. Perfect Skin Presets. If you have trouble getting the skin tones in your photos looking the way you want these presets can help This wedding photography shot list template is meant to be comprehensive but is by no means exhaustive. If you've got an idea for a creative, unusual photo, the couple is game, and you're able to sneak it in to a hectic schedule, go for it! Check out this list of creative wedding shots for a little extra inspiration
Presets; The Photo Argus. Photography Blog. Inspiration. Inspiration. Wedding Cake Pictures and Tips. July 5, 2021 · Emily Smith. Prominent on the list of modern-day wedding staples, wedding cakes provide a unique opportunity for wedding photographers. Wedding cake pictures allow photographers to showcase their creativity, and they also. 10 Best Wedding Presets in 2020. This is the list of the best wedding Lightroom presets in 2020 suitable for all photography wedding styles taken at any season and lighting. These free presets emulate the editing of famous wedding photographers like Jose Villa, Corbin Gurkin, KT Merry and John Dolan. 1. Vintage Love Wedding Lightroom Presets Editing should be easy and fun! Our free preset is all you need to create a beautiful, cohesive and outstanding look Best wedding lightroom presets 2020. Over 100000 Happy Customers and 4000 Five Star Reviews. Visual Flow Lightroom Presets are beautiful refined presets for professional wedding and portrait photographers. Lightroom Wedding Presets compatible with all versions of Adobe LR including LR Mobil
Lightroom presets for wedding photography. Zürich-based photographer Sascha Kraemer is a master storyteller, and his Oh Yes Presets capture the epic romance associated with many of the sprawling destination weddings he's documented around the world. These aren't your standard, cookie-cutter wedding presets; they're all about tapping into honest memories and creating something timeless Get that perfect portrait or wedding photo look again and again by quickly combining customizable Lightroom presets. Edit anywhere, anytime. Work seamlessly on any device, by importing your presets to desktop, mobile, and web versions of Lightroom Wedding presets. A collection of wedding presets is a must for every cameraman. These also work well for real estate and building images. When curating the collection of free Lightroom presets to download, these 10 free preset ideas were the inspiration
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There are many presets available for purchase, but there are also some that you can download for free. This collection contains Top lightroom presets collection that includes Lightroom Filters for Instagram, Wedding, Portrait, Travel and Landscape photography. You can use any of these Presets in Lightroom CC, Lightroom Classic CC, Lightroom. The Wedding Collection is a 5-Part (Garden Party, Light & Airy, Painted Desert, Sundrenched, and Black & White), Wedding Preset series containing 136 Lightroom Presets and comprised of some of the most popular classic and modern lightroom wedding presets and editing styles A comprehensive collection of 30 presets created specifically for editing wedding photos. This bundle allows you to quickly add a professional and cohesive finish to all of the beautiful images from the happy couple's big day. — Film Wedding Lightroom Presets. Add film inspired romance to images quickly with these 30 film inspired Lightroom. Our desktop presets provide an easy way for you to create professional edits and execute Studio McGee's signature style with as little as one click. Each of these presets is designed to achieve a specific aesthetic and compliment a variety of design styles and lighting conditions. Compatible with Adobe Lightroom Classic CC, Adobe Lightroom CC. Rustic Wedding is a must-have collection of professional presets for wedding, event and portrait photography. Whether you are a pro or an amateur, RW presets for Lightroom and Photoshop (Camera Raw) will speed-up your post-processing and help you get stunning results with a single click
editing class + wedding preset pack. everything you need to edit a full wedding day. i'll walk you through my entire editing process, from culling to export. includes over 5 hours of video and 10 presets April 20, 2019. Lost In Love. We adore photographing wedding styling especially when it's by the girls at Creating Beautiful. Shades of pink paired with contrasting black candles and gold accents, pampas grass and turned out rose petals, these are just a few of our favourite things! Enjoy and we hope you get some wedding style inspiration Boho Wedding Lightroom Presets Pack for desktop and mobile. The Boho presets are ideal for creating vivid contrasting photographs outdoors and in the home. Warm terracotta tones and light greens prevail. The pack includes 10 mobile and 10 desktop Lightroom presets. Lightroom presets are one-click filters to make your photo look a certain way or. Kami Olavarria is a wedding photographer based in San Diego, California. Servicing the local area of San Diego and the surrounding areas. Often provides services for weddings across the U.S. and worldwide. Specializes in journalistic, candid storytelling paired with fun, enthusiastic directing to produce natural and emotional wedding photography

domain: artistic


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New York Country Jam coming to NYS Fairgrounds
Thu, 20 Jun 2013 20:13:00 GMT —
A slew of national and up-and-coming country acts will hit Central New York this summer for the second annual New York Country Jam. The event will run from July 12-14 at the New York State Fairgrounds and will be headlined by Chris Young and Dancing with the Stars winner Kellie Pickler.
Several tribute bands kick the festivities off on Friday, July 12, including Tim McGraw and Garth Brooks tribute bands.
Saturday features country-fusion artist Uncle Kracker and Billy Currington, who has ten top ten country hits to his credit. Sunday has LoCash Cowboys, Kellie Pickler, Easton Corbin and Chris Young.
The full schedule and list of performers can be found here.
The inaugural Country Jam was held in Bouckville, in Madison County, but the organizers say most of the tickets sold were to people in Syracuse. The decision to move the event to the State Fairgrounds makes it more convenient to the majority of ticket buyers.
Tickets are $59 for a day or $99 for the whole weekend, and can be purchased here. Active military and first responders can get tickets two-for-one at the gate.

domain: geography


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The promising career of Springbok and Lions wing, Aphiwe Dyantyi, hangs in the balance. The 2018 World Rugby Breakthrough Player of the Year has formally been charged with a doping offence after testing positive for multiple anabolic steroids and metabolites.
The South African Institute for Drug Free Sport confirmed to SABC News that the player’s B sample also returned an adverse analytical finding in a doping test on the 2nd of July this year. Institute for Drug Free Sport CEO, Khalid Galant, says Dyantyi faces a lengthy ban if found guilty.
“The World Anti-Doping code framework for sanctions on anabolic steroids is still the same. So the framework stipulates four years sanction if the athlete is found guilty. So the process going forward now in terms of the charge, the athlete can either accept the charge with a guilty plea or he can contest the charge with a not guilty plea and he will then produce defence in front of an independent tribunal panel,” says Galant.
Watch related video:
Meanwhile the Human Rights Commission (SAHRC) says it has informed Springbok-lock Eben Etzebeth that it’s investigating him for allegedly racially abusing a man at a pub in Langebaan on the Cape West Coast. The alleged incident happened last week.
Etzebeth is part of the Springbok squad selected to play in the World Cup in Japan. Western Cape Commissioner Chris Nissen says they will make an assessment based on the complainant’s version of events.
“On the assessment of the complaint, obviously the commission will have to make a decision for us. It says we have to investigate but at this point it’s an alleged against somebody; that complaint will follow up and obviously we need to give all parties the opportunity because we have to be fair to everybody,” says Nissen.

domain: law


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Transition elements having partly filled d-orbitals exhibit several interesting properties. For example, they exhibit variable oxidation states, form coloured complexes with different anions and neutral molecules and show paramagnetic behaviour. Transition metals and their compounds also possess catalytic properties. Some of the important properties of transition metals are discussed below:
All transition elements are metallic in nature. Transition elements exhibit typical metallic properties such· as lustre, high tensile strength, ductility, malleability and high thermal and electrical conductivity. They show gradual decrease in · ·, electropositive character in moving from left to right. The . metallic bonds in transition metals are quite strong. This is due to the greater effective nuclear charge and the large number of valence electrons. Due to the presence of strong metallic bonds, the transition metals are hard, possess high densities and high energies of Atomisation. Atomisation energies of the first transition series are represented graphically in Fig. 19.1.
It may be observed that atomisation energies exhibit the maxima at about the middle of the series. It indicates that interatomic interactions become stronger with increase in half filled d-orbitals.
Most of the transition elements have densities higher than 5 g cm-3, the highest being that of iridium (22.6 g cm-3) . Scandium has the least density among transition metals.
MELTING AND BOILING POINTS
The melting and boiling points of transition elements are generally very high. This is due to strong metallic bond and the presence of half-filled d-orbitals in them. Due to these half-filled orbitals, some covalent bonds also exist between atoms of transition elements. Because of stronger interatomic bonding, transition elements have high melting and boiling points.
In moving along the period from left to right, the melting points of these metals first increase to maximum and then decrease regularly towards the end of the period. In any row the melting points of these metals rise to a maximum at.
The ionization energies of transition elements are higher than those of s-block elements but lower than p-block elements. In a particular transition series, ionization energy increases gradually as we move from left to right However, the relative difference of ionization energy values of any two consecutive d-block elements of particular period is much smaller than those of s- and p-block elements. Reason. The increase in ionization energy is primarily due to increase in nuclear charge. As the transition elements involve the gradual filling of (n – 1) d-orbitals, the effect of increase in nuclear charge is partly cancelled by the increase in screening effect. Consequently, the increase in ionization energy along the period of d-block elements is very small.
Table 19.2. Some Physical Properties of the First Row Transition Elements
The ionization energies of 3d-transition series are given in Table 19.2 and graphically represented in Fig. 19.2.
Fig. 19.2. Ionization energies of first transition series.
Significance of lm1hafn Energy Values
The magnitudes of ionization energies give some indication of the energy required to raise the metal to a particular oxidation state. From the knowledge of values of ionization energies of the metals it is possible to rationalize the relative stabilities of various oxidation states. For example. the sums of first two and first four ionization energies of nickel and platinum are given in Table 19.3.
Table 19.3. Ionization Energies of Nickel and Platinum
Since sum of the first two ionization energies is less for nickel, therefore, Ni(II) compounds are thermodynamically more stable than Pt(II) compounds. On the other hand, Pt(IV) compounds are more stable than Ni(IV) compounds because sum of first four ionization energies is less for platinum. K2PtC16 is well known compound of platinum with +4 oxidation state. The corresponding nickel compound does not exist In addition to ionization energy, the other factors that determine the stability of a particular state are the atomisation energy of the metal and the lattice energy or the solvation energy.
ATOMIC AND IONIC RADII
The atomic and ionic radii of transition elements are smaller than those of s-block elements and larger than those of p-block elements. Among the elements of the particular transition series. as the atomic number increases, the atomic radii first -decrease till the middle, become almost constant and then increase towards the end of the period. For example, the atomic radii of first transition series decrease from Sc to Cr. remain almost constant till Cu and then increase towards the end.
Table 19.4. Atomisation Energies, Ionization Energies and
Standard Electrode Potentials for Elements of First Transition Series
Table 19.5. Atomic and Ionic Radii of Elements of First Transition Series
Reason. The decrease in size in the beginning is attributed to the increase in nuclear charge. However, the increased nuclear charge is partly cancelled by the increased screening effect of electrons in the d-orbitals of penultimate shell. When the increased nuclear charge and increased screening effect balance each other, the atomic radii become almost constant Increase in atomic radii towards the end may be attributed to the electron-electron repulsions. In fact, the pairing of electrons in d-orbitals occurs after d5 configuration. The repulsive interactions between the paired electrons in d-orbitals become very dominant towards the end of the period and cause the expansion of electron cloud and thus, resulting in increased atomic size. The ionic radii also follow the similar trend.
All transition metals exhibit a great variety of oxidation states. The oxidation states of first row transition elements are listed in Table 19.6. The less common and unstable oxidation states are given in the parentheses. The stability of a particular oxidation state depends upon the nature of the element with which the transition metal forms the compound. The highest oxidation states are found in compounds of fluorine and oxygen. This is due to the high electronegativity values and small size of fluorine and oxygen.
The variable oxidation states of transition elements are due to the participation of ns and (n -1) d-electrons in bonding. The lower oxidation state is generally, exhibited when
ns-electrons participate in bonding and higher oxidation states are shown when ns as well as (n- 1) d-electrons take part in bonding. It may be noted the oxidation states of transition elements differ from each other by unity whereas oxidation states of non-transition elements generally differ by two.
Some noteworthy features of oxidation states of the transition elements are:
1. In each group, the highest oxidation state increases with increase in atomic number, reaches a maximum in the middle and then starts decreasing. For example, for the first transition series the maximum oxidation state is shown by manganese.
Table 19.6. Different Oxidation States of Transition Metals
Note. Less common and unstable oxidation states are given in parentheses.
2. The elements which exhibit the maximum number of oxidation states occur either in or near the middle of the series. For example, in the first transition series manganese exhibits maximum number of oxidation states ( + 2 to + 7).
3. The elements in the beginning of the series exhibit fewer oxidation states because they have small number of electrons which they can lose or contribute for sharing. The elements at the end of the series exhibit fewer oxidation states because they have too many d-electrons and hence have fewer vacant d-orbitals which can be involved in bonding.
4. For the elements of first transition series (except scandium) + 2 oxidation state is the most common oxidation state. This oxidation state arises due to the loss of 4s-electrons.
5. The transition elements in lower oxidation states ( + 2 and + 3) generally form ionic bonds. In higher oxidation states, the bonds formed are essentially covalent. For example, in tetraoxochromate(VI) ion (CrO42-). the bonds formed between chromium and oxygen are covalent.
6. Some transition metals also show oxidation state of zero in their compounds. [Ni(CO)4] and [Fe(CO)5] are common examples.
In contrast to the representative elements, transition elements form many coordination complexes. Their tendency to form complexes is attributed to the following reasons:
1. Small size and high charge density of the ions of transition metals.
2. Presence of vacant orbitals of appropriate energy which can accept lone pairs of electrons donated by other groups (ligands).
Some examples of coordination complexes are:
(i) [AgH3)2] Cl (ii) K4[Fe(CN)6]
Coordination complexes have been discussed in detail in Section 19.4.
The compounds of transition elements are usually coloured both in solid state and in aqueous solution. The colour of these complexes is due to absorption of some radiation from visible light, which is used in promoting an electron from one of the d-orbitals to another. This can be explained as under:
The d-orbitals in the transition elements do not have same energy in their complexes. Under the influence of the ligands attached, the d-orbitals split into two sets of orbitals having slightly different energies. In the transition elements, which have partly filled d-orbitals, the transition of electron can take place from one of the lower d-orbitals to some higher d-orbital within the same subshell. The energy required for this transition falls in the visible region. So when white light falls on these complexes they absorb a particular colour from the radiation for the promotion of electron and the remaining colours are emitted. The colour of the complex is due to this emitted radiation. For example, copper(IT) salts are bluish green due to absorption of red light. Ti3+ salts appear purple due to absorption of yellow light.
The energy difference between the two sets of d-orbitats in the central atom of the complex depends on the nature of ligands and the structure of the complex ion. As a result different complexes of the same metal ion, with different ligands, may have different colours. For example, [COC14f is blue in colour whereas [CO(H2O)6] 2+ is pink[Fe(H2O)6 ]2+ is green in colour whereas [Fe(CN)6]4- is yellow.
Zn2+ and Ti4+ salts are white because they do not absorb any radiation in the visible region. In these compounds, d-d transitions are not possible because in Zn2+ all the d-orbitals are fully filled whereas in Ti4+ all the d-orbitals are vacant. The colours of some transition metal ions in aqueous solutions are given in Table 19.7.
Table 19.7. The Colours of Some Transition Metal Ions in Aqueous Solution
The substances, which contain some species (atoms, ions or molecules) with unpaired electrons in their orbitals, behave as paramagnetic substances. Such substances are weakly attracted by magnetic field. On the other hand, the substances whose constituent particles do not contain any unpaired electrons are repelled by magnetic field and are called diamagne1ic.
The transition metal ions generally contain one or more unpaired electrons in them and hence their complexes are generally paramagnetic. The paramagnetic character increases with increase in number of unpaired electrons.
Many transition metals and their compounds are known to act as catalysts. For example, finely divided iron acts as catalyst in the manufacture of ammonia by Haber Process. vanadium pentoxide (V2O5) or platinum act as catalyst for the oxidation of SO2 to SO3 in Contact Process, ferrous sulphate and hydrogen peroxide (Fenton’s reagent) are used for the oxidation of alcohols to aldehydes.
The catalytic activity of transition metals is attributed to the following reasons:
l. Because of their variable oxidation states transition metals sometimes form unstable intermediau compounds and provide a new path with lower activation energy for the reaction.
For example, v p5 catalyses the oxidation of SO2 to SO3.
The catalytic action of V2O5 can be understood a5 follows:
During the conversion of SO2 to SO3, V2O5 adsorbs SO: molecule on its surface and gives oxygen to it to form SO, and V2O 4. V2O 4 then reacts with oxygen to form V2O5
Similarly, iron(III) catalyses the reaction between iodide and persulphate ions.
The catalytic action of iron(III) in this reaction is explained as follows
2Fe3+ + 21 à 2Fe2+ + I2
2Fe2+ + S2O82- à 2Fe3+ + 2SO4
2. In some cases transition metals provide a suitable surface of the reaction to take place. The reactant are adsorbed on the surface of the catalyst where reaction occurs.
Adsorption results in increased concentration of reactants at the surface and also weakens the bonds between atoms in the reactant molecules.
Catalytic Properties of Transition Elements and their Compounds
Some first row metals and their compounds used as catalysts are given below:
Catalyst Process Catalysed
TiC14 Used as the Ziegler-Natta catalyst in the
polymerization of ethene and propene
V2O 5 Used as catalyst during conversion of S02 to S03
in the Contact process for the manufacture of
MnO2 Used as catalyst to decompose KC103 to produce
2KC1O3 à 2KCI + 3O2
Fe Iron in the presence of a promotor act as catalyst in
Haber process for the manufacture of ammonia
FeCJ3 Used as catalyst in the production of CC14 from
cs2 and cl2
Co2(CO)8 Oxo process for conversion of alkenes to alkanals
Ni Hydrogenation of vegetable oils
CuCl2 Used as catalyst in the manufacture of chlorine from
HCI (Deacon process).
The catalytic activity of transition metal compounds can be demonstrated by the following activity.


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|National Football League|
|All Sports|||||Scoreboard|||||Stats|||||Standings|||||Teams|||||Players|||||Player News|||||Injuries|||||Transactions|
|Sep. 21 8:08 AM PT9:08 AM MT10:08 AM CT11:08 AM ET15:08 GMT11:08 PM 北京时间8:08 AM MST10:08 AM EST10:08 AM CT19:08 UAE11:08 ET14:08 - Pierce will miss today's game against the Browns with a thigh injury.
Analysis: Pierce had started Baltimore's past two games, filling in for Ray Rice, who was released by the team and suspended indefinitely by the NFL this month for domestic violence. He will be replaced by Justin Forsett, who has averaged 6.6 yards on 19 carries and scored a touchdown through two games.

domain: sports


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Under a new law in Saudi Arabia, women will be notified about divorces via text message. It’s meant to put a stop to rampant “secret divorces,” in which husbands leave their wives without the woman’s knowledge. It brought up the questions: is it ever okay to break up with someone over text message?
This is an archived article and the information in the article may be outdated. Please look at the time stamp on the story to see when it was last updated.


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The result of a three-year long process mapping the town’s official planning blueprint, last updated in 2002, was brought to fruition this week, but the fact the town’s proposed Official Plan still contained a controversial development in the North Gwillimbury Forest brought calls for its amendment with its tabling at council last night.
The town’s updated Official Plan (OP) is a comprehensive document that is the result of the town’s planning division, the consulting firm hired in 2013 to undertake an Official Plan review, council-appointed steering committee, technical advisory committee and analysis of input from a total of 48 written submissions from the public, agencies and private landowners/agents on its draft version released in April of last year.
It covers a multitude of areas, including outlining the municipality’s growth management, general land use and development, sustainable natural environment, settlement areas, servicing and infrastructure, housing and community design.
It also, however, is the latest battleground playing out at the council table in a war over development rights versus environmental protections concerning a 400-acre piece of property north of Deer Park Drive in the north end of Keswick.
For a number of years now, DG Group (the rebranded Metrus company that owns the property), planners and lawyers with the town and York Region, Georgina council members, as well as lawyers and planning consultants with the North Gwillimbury Forest Alliance have been wrangling over interpretations of various planning documents that will either put the brakes on or open the door to a subdivision of just less than 1,100 homes dubbed Maple Lake Estates (MLE).
At issue is whether or not a development on the planning books for more than 20 years should still be allowed to be built under subsequent planning policies that have designated portions of the property as significant wetlands.
Ward 3 Councillor Dave Neeson doesn’t think so and he tabled a motion seeking an amendment that would change the designation of the MLE lands to an environmental protection area in Georgina’s Official Plan.
“After decades of controversy, I believe that the time is here,” Neeson said.
"I simply cannot accept that there are no expiry dates on development approvals, which, in this case, occurred decades ago. Decades ago, as a society, we also saw fit to not wear seatbelts and to smoke in our cars with children present. I don't think anyone would see those things as acceptable in today's society and, similarly, I don't think anyone in Georgina or the broader Lake Simcoe watershed would think that development on a provincially significant wetland is acceptable in a municipal Official Plan".
According to the town’s planning department, however, changing the designation of MLE lands would conflict with a complex layer of upper-tier planing documents and policies under the Planning Act.
“You can’t just divorce yourself and ignore the particular facts of the matter,” the town’s director of development services, Harold Lenters, said, referencing MLE’s long history, including the OMB’s urban residential designation of the property, re-affirmed by an Order of Council by the provincial cabinet, a draft plan of subdivision registered on title and a registered development agreement between the town and the developer.
“A registered plan of subdivision is about as far as you can go in terms of the planning process. It’s got a lot of strength to it.”
Based on the strength of the planning approvals in place, significant investment was made by the developers of the property to bring about $3 million in total water and sewage servicing infrastructure to the site, including the water tower on the north side of Deer Park Drive that is owned and operated by the region, but was bought and paid for by the developers.
“It is an integral part of servicing the lakeshore community in the system we have today,” Lenters said.
Neeson’s decision to seek an amendment to the town’s proposed Official Plan this week comes on the heels of the North Gwillimbury Forest Alliance (NGFA) re-iterating its position the town is legally obligated to bring its official plan into conformity with the provincial policy statement and York Region’s official plan, adding the town’s official plan must be amended to prohibit development on MLE’s wetlands and woodlands.
But Lenters and Jim Dyment of consulting firm MHBC Planning, Urban Design and Landscape Architecture, said the MLE lands were basically exempted from all the wetland policies the PPS and every other policy and plan has, including the Greenbelt Plan, which designated the MLE land towns and villages, and, in so doing, exempted it from the natural heritage system that is the backbone of the plan, and its policies.
“So, here’s the province’s tool to create a protected greenland system and it recognizes this development. That was a clear message to us.”
Alliance chairperson Jack Gibbons argued otherwise.
“There is nothing in the Greenbelt Plan that exempts the town from its Planning Act obligations to protect the MLE’s provincially significant wetlands and woodlands,” Gibbons said, adding “towns and villages” are not subject to the province’s Greenbelt Plan legislation and “continue to be governed by municipal official plans”.
Gibbons believes that is an opening for the town to do what he is asking it to do, but Lenters and Dyment don’t agree.
In addition, according to the Planning Act, upper-tier plans take precedence regarding conflicting policies and, therefore, the Greenbelt Plan and York Region Official Pan would have to be amended first to prohibit the approved development in order for the town’s official plan to be amended, Dyment said, adding both recognize and permit the approved Maple Lake Estates development.
From a planning perspective, MLE doesn’t need any more planning approvals to go ahead and build what is stipulated in its registered plan of subdivision.
In the interest of moving forward, protecting the forest and best serving the public interest, Lenters said supporting council’s decision, raised over the province’s review of the Greenbelt Plan of pursuing a land swap, is the best option.
That would move the MLE development to the south side of Deer Park Drive to land also owned by DG Group.
“I honestly believe that’s the best and only chance to save the forest,” Lenters said.
“Our position is this Official Plan represents good planning. It has been the most complex in terms of trying to knit all the things together in a way that meets all the tests of the Planning Act and all the policy. It implements provincial policy and it implements the region’s plan. Having said that, council is the policy makers. Our job is to provide them the best recommendations we can.”


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Photo by SHVETS production from Pexels
By Maggie Bloom
If you’ve seen the hemp industry, there’s been an explosion of cannabinoids. Today, you can buy THC, CBD, and now CBG. CBG might not sound as familiar as the other two, but it’s still exciting. Cannabigerol has a different effect than them, making it useful for other conditions. Here’s what you ought to know about CBG.
What Is Cannabigerol?
Cannabigerol, or CBG, is a cannabinoid derived from the cannabis plant. In nature, it functions as the parent compound for most cannabinoids. There is a ton of cannabigerol acid in cannabis while it’s growing.
Usually, we can detect around 1% CBG in a modern cannabis plant. Compared to CBD, it’s found in way lower concentrations. So, this can make it difficult to find consumer CBG products at an affordable price. Check out CBGA for sale to see the best deals online if you’d like to save a little money.
How Is It Made?
When cannabis is young, it has a much higher concentration of CBG. That’s why growers harvest young plants when they’re focusing on cannabigerol. Also, certain strains have higher-than-average CBG concentrations.
Most facilities prefer using strains like White CBG, Super Glue CBG, and Jack Frost CBG. Using them, they can produce way larger yields once it’s harvest time.
As plants age, CBG converts into other cannabinoids. Consequently, you’ll find higher concentrations of THC and CBD in aging plants. Harvesting them while they’re still young preserves their CBG, increasing overall yields.
What Is Its Mechanism of Action?
Like other cannabinoids, CBG acts on the body’s endocannabinoid system. By imitating endogenous cannabinoids, it can stimulate our CB1 and CB2 receptors.
CBG has a slightly different binding profile than the other cannabinoids. Comparatively, it acts on a broader range of functional receptors. It can function as an agonist at both the CB1 and CB2 sites.
One of the CBG’s main appeals is its lack of psychoactivity. If you consume THC, it also activates the same receptors. But, it produces a state of intoxication that can make daily life difficult.
Using CBD doesn’t have the same type of mind-altering effects.
What Can You Treat With CBG?
Above all, CBG’s health benefits are what’s given it such a popularity boost. It can treat certain conditions without intoxicating you, similar to CBD.
So far, there’s not as much research concerning CBG’s effects on the human body. However, what little there is does seem to support its use.
There was a studying looking at its impact on patients with IBD. Inflammatory bowel disease is an autoimmune condition characterized by chronic inflammation. By administering CBG, patients experienced a lessening of symptom severity.
Animal models support the use of CBG in glaucoma cases. After giving some to rats, researchers noticed a reduction in intraocular pressure. They also noted an increase in aqueous humor outflow, vital for eye health.
CBG even seems to possess neuroprotective properties. When given to rats with Huntington’s, it stopped neurons from dying. The rats had improvements in their motor function due to CBG’s administration.
How to Dose CBG?
Most of the time, CBG comes as oil if bought online. Each oil varies in its concentration, making doses different. Check the label to see what they’ve set as a standard dose before taking any.
We’d recommend starting with around 10 mg and working your way up in dose. Typically, people find their sweet spot before going up 50 mg.
What’s the Difference Between CBG and CBD?
CBD is found in much higher quantities in mature cannabis plants. So, it usually doesn’t cost as much if you’d like to buy some. It has many of the same benefits, and it’s less expensive. CBD and CBG both interact with the endocannabinoid system. But, CBD has less of an influence on CB2 receptors.
CBG: A Unique Cannabinoid with Restorative Properties
Not everyone experiences the same benefits when trying cannabinoid compounds. Sometimes, CBD is the best one for somebody. Yet, it has nearly no effect on someone else. CBG is a novel compound that’s beginning to be more available. If you’ve had bad experiences with other cannabinoids, give it a try. It may have better effects.
Maggie graduated from Utah Valley University with a degree in communication and writing. In her spare time, she loves to dance, read, and bake. She also enjoys traveling and scouting out new brunch locations. If you want to know more about cbg and how to use it, consider talking to professionals about cbga for sale in your area.


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**** Opening Soon!!!***********
Freedom Behavioral Program will be a 12 bed inpatient senior adult unit. The unit will be a D.P.U. of Oakdale Community Hospital, with the program being an off site campus will be located inside Mercy Regional Medical Center, Ville Platte, La.
Coordinates safe transportation of hospitalized patients to and from their residences/appointments as well as meal pick up. Also provides assistance to mental health services staff for patient care activities. The responsibilities include, but are not limited to, the transporting of patients to and from the facility site, assistance in the overall day-to-day functioning of the program including aiding other staff in patient chart production, meal provision, answering telephones and supervision of patients during staff break periods. The Mental Health Worker/Driver is responsible for communicating to staff any problematic or clinical issues that occur during his/her supervision of or transportation of patients.
MUST HAVE A CLEAR DRIVING HISTORY
Education: High School Diploma
License: Current Motor Vehicle License with clean MVR
Experience: Prefer 1-2 Years transporting patients in a 10-12 passenger van

domain: medical


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Leftfield are an electronic band formed in 1989 in London, United Kingdom. From 1989 to 2002, Leftfield was a duo of artists and record producers that consisted of Neil Barnes and Paul Daley. In January 2010, Barnes resurrected the band name and Daley has declined to be involved. They are pioneers in the fields of idm and progressive house, being among the first to fuse house music with dub and reggae. ...show more
Leftfield are an electronic band formed in 1989 in London, United Kingdom. From 1989 to 2002, Leftfield was a duo of artists and record producers that consisted of Neil Barnes and Paul Daley. In January 2010, Barnes resurrected the band name and Daley has declined to be involved. They are pioneers in the fields of idm and progressive house, being among the first to fuse house music with dub and reggae.
As with many of their contemporaries such as The Chemical Brothers and Underworld, Leftfield pioneered the use of guest vocalists throughout their career. Among the more prominent were Toni Halliday (of Curve), who sang on "Original", Djum Djum on "Afro-Left" and Earl 16 and Cheshire Cat on "Release the Pressure". Neil Barnes' entry into the music world was as a DJ at The Wag Club while simultaneously playing percussion instruments. Around 1989, inspired by Afrika Bambaata, Barnes decided to try his hand at electronic music production.
In 1990, he released the single "Not Forgotten" on the Rhythm King label. It was followed by "More Than I Know" in 1991. For the remixes of these tracks, Barnes called upon Paul Daley, then a hairdresser, but also in A Man Called Adam and a formerly a session musician for the Brand New Heavies and Primal Scream, appearing on their Dixie Narco EP. Barnes and Daley had previously worked together as percussionists at The Sandals' first club, Violets. ...show less
Albums & Singles by Leftfield
Playlists Containing Tracks by Leftfield
90`s Dance antheems!!!!!!!!! - KD
Squat is the Answer
Early Morning Electronica
Beatport: Best of Deep House
Ultimate Trip Hop
DEEP HOUSE (UPDATED)
Ibiza (future) classic 2013
The Guinness Adverts
1001 Songs you must hear before you die
The Zen Hipster
Music For Fast Cars
MIXTAPE: Smokin Joints from the 90s vol. 1
Forever Cool - Modern Edition
Instant Party.... Just Add People
The best Deep House tracks of this moment (u…
Mercury Music Prize: 1992-2013
chillwave || downtempo || chill out
Techno Days of Old
1990s Brilliance! [Indie, Alternative, Rock, …
Best Office Lounge Music r
Fresh fm House Top 1000 ( lijst 2013)
Running as hard as fuck
Forgotten Classics - Vol 2: 1998-2001
Transgenerational Electronic Odyssey
Songs In My Head
Smoking / Chill
GREATEST DANCE TRACKS EVER
Playlists We Love
100 Greatest Christmas Songs Ever
An extensive 5 hour playlist of the 100 greatest Christmas songs ever!
UK TOP 40 CHART
Listen to the top-selling singles in the UK, updated regularly.
UK New Music Fridays
Each week we will update this playlist with the latest new releases from the UK
Hear tomorrow's hits first before anybody else!
The very latest floorfillers, perfect for the party and updated regularl
House Music 2016
The very latest house music updated each week
Topsify Biggest Songs Right Now
The biggest hits in the world right now
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This is the perfect playlist to unwind & relax to
The 100 Greatest Pop Songs Ever
The most perfect pop songs from around the world.
Feel Good Indie
A hand picked selection of new indie music chosen to put a lift in your step & a smile on your face.

domain: entertainment


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Bob Stoops and the Sooners host Florida State on September 11.
NCAA college football expansion has been the big buzzword this past offseason, but that expansion will eliminate one of the sport's best divisions. The Big XII Conference South Division boasts national powers Texas and Oklahoma, along with the solid programs of Oklahoma State, Texas Tech and Texas A&M.
When Nebraska bolts to the Big Ten Conference after this season, and with Colorado scheduled to join the Pac-10 in 2012, the Big XII will have 10 teams and no conference title game. The powerful South Division will now be joined by the weaker teams in the North Division. Without a conference championship game, Texas and Oklahoma might have a tougher time capturing a national title with a diminished Bowl Championship Series ranking.
There are plenty of interesting storylines heading into the final NCAAF college season of the Big XII South Division. This division hasn’t won a national championship since Vince Young led the Longhorns past Southern Cal back in 2005. The only other team in this division to win it all was the Oklahoma Sooners in 2000.
Both of those programs will be strong once again this season, entering the season as a 12/1 selection to win the national championship. Texas Tech and Texas A&M opened at 100/1, while Oklahoma State enters the fray at 150/1.
Perennial division doormat Baylor is listed as a 25/1 selection as a member of the ‘field.’
Texas went 8-0 in the conference last season, and won its first 13 games before falling to Alabama in the BCS National Championship Game in Pasadena. The Longhorns chances of victory took a major hit when quarterback Colt McCoy went down with an injury, but backup Garrett Gilbert earned some valuable experience during that game.
Texas will have to overcome the losses of McCoy and Jordan Shipley on offense, and talented Sergio Kindle, Roddrick Muckelroy and Lamarr Houston on defense. However the Longhorns continue to have one of the nation’s best recruiting classes every year, keeping this program as an annual BCS contender.
Texas has its sights set on recording its 10th straight season with at least 10 victories, currently the nation’s longest active streak. The biggest games on the regular-season schedule include the annual Red River Rivalry game with Oklahoma October 2 before a bye week and Oct. 16th tussle at Nebraska.
Oklahoma enters the 2010 college football campaign just one win shy of 800 victories in program history, joining just seven other schools on that distinguished list. The Sooners played for the national championship at the end of the 2008 season, but stumbled to an 8-5 record last season along with a 5-3 conference ledger. Oklahoma uncharacteristically finished tied for third in the Big XII South, but did conclude the season on a positive note with a Sun Bowl victory over Stanford.
There are a couple of potential potholes on the nonconference schedule, with the Sooners facing Florida State at home on Sept. 11 and at Cincinnati Sept. 25. That road matchup with the Bearcats occurs the week before the Red River Rivalry contest with Texas. Oklahoma wraps up the regular season with three road matchups the final four games, traveling to Texas A&M, Baylor and Oklahoma State along with a home game against Texas Tech.
Oklahoma State posted a 9-4 record last season that included a 6-2 conference ledger. The Cowboys finished second in the South Division, but culminated the season with a 21-7 setback to Ole Miss in the Cotton Bowl. Despite all the T. Boone Pickens money flowing in Stillwell, Oklahoma State figures to take a step back this season.
The Cowboys will have to deal with the loss of quarterback Zac Robinson and wideout Dez Bryant. Along with those two offensive stars, five other starters will have to be replaced. Oklahoma State will also have to find nine new defensive starters, meaning growing pains will be evident this fall.
An easy non-conference schedule against Washington State, Troy, and Louisiana-Lafayette should get this team some confidence before facing some of the Big XII heavyweights.
Texas A&M played 17 freshman last season in some capacity, leaving the team with a 6-7 record including 3-5 in conference. The Aggies advanced to the Independence Bowl, but they were hammered by Georgia, 44-20. Coach Mike Sherman’s team will be led by quarterback Jerrod Johnson, who had 22 touchdowns passing (seven rushing) with just five interceptions.
Texas A&M should get out of the gates quickly with home games against Stephen F. Ausin, Louisiana Tech and Florida International. There is a tough midseason stretch with games at Oklahoma State followed by a NCAAF college matchup with Arkansas in Dallas and home game with Missouri. A bowl game might be on the line leading up to late-season games against Nebraska and at Texas.
It has been an eventful offseason at Texas Tech, where the team will be hard pressed to repeat last year’s 9-4 ledger and 5-3 conference record. The Red Raiders toppled Michigan State in the Alamo Bowl, 41-31, but then the real fireworks began.
Head coach Mike Leach put this program on the map, and almost had the team playing for a national championship just two years ago. But the coach was suspended for the Alamo Bowl victory surrounding the alleged mistreatment of a player, and was eventually fired in late December.
Tommy Tuberville was brought in to clean up the mess after successful stints at Ole Miss and Auburn, but his offensive philosophy differs greatly from Leach’s air attack. There is a potential non-conference loss Sept. 11 at New Mexico, while back-to-back Big XII road trips against Colorado and Texas A&M could have this team rebuilding for the future.
Every conference or division has a doormat, a place that Baylor (4-8 overall, 1-7 in conference) knows all too well. The Bears secured just one victory last season after October 3 with a road upset November 7 against Missouri, 40-32. This year’s non-conference slate contains tough matchups versus Buffalo, along with road games against Texas Christian and Rice.
Quarterback Nick Florence had 1,786 yards passing and six touchdowns during his freshman campaign, while senior Jay Finley led the team last season by rushing for 370 yards. Despite some returning playmakers on both sides of the ball, expect another long football campaign in Waco this fall.


You may have seen the shocking YouTube video of a FedEx delivery man throwing a computer monitor over a customer’s gate, uploaded in December.
Within 24 hours, it had received 200,000 views. The story then featured in the Daily Mail and the number of views soared to 4.5 million. Today, the total stands at over 8 million and it has been ‘liked’ 17,000 times.
So how did FedEx deal with the situation?
In the first statement, FedEx condemned the employee’s actions, stating that executives were ‘shocked’. They said the handling of the package was ‘unacceptable’ and vowed to track down the employee responsible.
This is a good initial response. FedEx probably learnt about the incident at the same time as the press so they wouldn’t have had time to investigate. FedEx was also right not to protect the employee; instead they distanced the company’s brand from the individual’s actions.
FedEx’s next move was smart. They created a YouTube video in response – within 48 hours. The speed of their response was critical, helping curb speculation about the incident.
In the video Matthew Thornton, Senior VP at FedEx, said they had met with and apologized to the customer. The company deserves kudos for this; in difficult situations, companies typically communicate with customers via telephone or in writing. Meeting face-to-face is personal and proves FedEx cares about its customers.
Thornton also answered the question everyone asked: what happened to the employee? He explained ‘they’re working within their disciplinary procedures and the employee is not working with customers’. This is a mediocre response. Customers and journalists alike wanted reassurance that the guilty party had been fired. I suspect HR procedures prevented FedEx from providing a stronger response.
Thornton then reminded viewers that the company’s motto is to ‘make every FedEx experience outstanding’. This is good; he uses a difficult situation to reinforce the company’s key messages and its commitment to customers.
Despite this, the footage still damaged the company’s reputation – and consequently it was listed by Forbes as the ‘most brand-damaging viral video of 2011’.
FedEx’s YouTube video also received less than half a million views, a sixteenth of the original video. Clearly bad news travels faster than good.
This incident won’t go away for FedEx and any reoccurring issues will be closely watched by the public eye. However, FedEx can be commended for responding quickly, using YouTube as the channel to respond and meeting the customer face-to-face.
What are your thoughts on FedEx’s response?


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CCD Counseling PA Denton Recovery Options
CCD Counseling PA Denton Recovery Options is an alcohol and drug rehabilitation program located at 1512 Scripture Street in Denton, Texas. They can be contacted at 940-382-5328 x25.
The program uses major approaches to treatment of Cognitive/Behavioral Therapy, Relapse and Aftercare Planning, 12 Step Therapy Support. The program offers services in these settings: Outpatient Rehab.
CCD Counseling PA Denton Recovery Options also provides people with a number of special programs tailored to the specific needs of individuals, such as: Continuing Care and Relapse Prevention, Substance Abuse Testing, Mental Health Rehab, Substance Addiction Screening. CCD Counseling PA Denton Recovery Options accepts the following types of payment: Self-Payment or Cash, Medicaid Covered Treatment, Private Insurance Covered Treatment.
We can help you find the right treatment facility that best fits your overall needs and financial requirements.


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Tomato, Corn, and Rice Skillet Casserole
- Prep Time: 10 minutes (+ time to cook rice)
- Cook Time: 35 minutes
- Total Time: 45 minutes
- Yield: 6 servings
- 1 Tbsp extra virgin olive oil
- 1 red bell pepper, diced
- 1 white onion, chopped
- 1½ Tbsp garlic, minced
- 1 cup long-grain white rice, cooked
- 1 Tbsp chili powder
- 2 cups frozen yellow corn
- 15 oz can reduced-sodium black beans, rinsed + drained
- 14.5 oz can diced tomatoes with green chilies
- 14.5 oz can reduced-sodium vegetable broth
- 3 plum tomatoes, sliced
- ¾ cup reduced-fat, shredded Mexican cheese
- Preheat oven to 350 degrees. Over medium heat, heat oil in a very large iron skillet (or a 3-quart flameproof casserole dish with lid). Add bell pepper, onion, and garlic; cook for about 4 minutes or until onion is transparent; stir occasionally.
- Stir in rice and chili powder. Cook for one minute before adding corn, diced tomatoes, beans and broth to rice mixture. Bring to boil and simmer for about 3 minutes; stir occasionally.
- Carefully cover with foil (I used hot mitts to press down and around the sides). Transfer to oven and bake for about 20 minutes or until most of the liquid is absorbed.
- Take off foil and sprinkle with Mexican cheese. Bake, uncovered, until cheese is melted, about 5 more minutes. Top with tomatoes and let stand for 5 minutes before serving.
- Serving Size: Heaping 1 cup
- Calories: 316
- Sugar: 8g
- Sodium: 1309mg
- Fat: 6g
- Carbohydrates: 50g
- Fiber: 6g
- Protein: 10g

domain: food


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MIAMI – In celebration of Hanukkah, the 60-story Paramount Miami World Center announced that “The World’s Tallest Menorah” will be lighting up South Florida’s skyline on Sunday.
The 700-foot-tall Paramount Miami Worldcenter is Miami’s soaring signature skyscraper.
The superstructure is located at 851 NE 1st Ave.
According to a news release, “The World’s Tallest Menorah, Digital Dreidels and array of Six-Pointed Jewish Stars” will be on full display during the eight days of Hannukah.
Through the center column of the 60-story superstructure is the phrase “Happy Hanukkah”.
The Paramount Miami Worldcenter features the world’s most technologically advanced L.E.D. animation system.
According to event organizers, the Paramount tower will illuminate every morning before dawn and from sunset through midnight.


New Ford Bronco Vs Jeep Wrangler
With two modern engines and six new trims the 2021 bronco seems ready to dethrone the jeep wrangler.
New ford bronco vs jeep wrangler. Following the launch of the 2019 jeep wrangler the all new ford bronco will debut for the 2020 model year 24 years after the bronco went out of production. And though we haven t driven the new bronco yet it s clear that. Ford made a big deal about the bronco s capabilities with several one up claims. Let s dig into the numbers because it s game on.
Jeep and ford spent much of the late 20th century in a tug of war for off roading supremacy. Ford is putting the jeep wrangler on notice with its revived bronco. And like the jeep the bronco skyrockets in price with the uplevel trims and over 200 options on offer. Ford has been testing a raptor.
Here we ll see how the 2021 ford bronco and 2020 jeep wrangler compare on paper. The arrival of the 2021 ford bronco means that for the first time in decades the jeep wrangler has a true direct competitor. Only time will tell if like the jeep wrangler ford s newly designed bronco holds true to the vehicle s heritage as a purposeful utility vehicle with real off road capability or if like chevy. Ford asks 34 695 to get into the four door bronco 1405 more than the unlimited wrangler.
In an epic showdown of off road suvs only one can reign supreme. The bronco and defender rely exclusively on turbocharged engines while. The small body broncos 1966 1976 were ford s answer to the cj but it was the bigger bronco that helped spark the suv craze of the 1990s. The bronco s 94 75 1 maximum crawl ratio is better than the wrangler s best but the jeep s transfer case with a 4 0 1 low range is better than the ford s 3 06 1 low ratio.
2021 ford bronco vs. Comparing specs after 25 years ford is back with a hardcore suv to take on jeep s iconic wrangler.
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See all those languages up there? We translate Global Voices stories to make the world's citizen media available to everyone.
Once you have the right perspective, you can travel anywhere … some places you might have to wait longer to visit, but you will eventually get there.
Travel blogger Rishi Sankar offers advice on how to “structure your mind to enable a life of travel”.
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HOUSTON – A lot of us are preoccupied with when a vaccine to protect against coronavirus will be available, but there’s another treatment on the horizon that could help those who could face complications before a vaccine is ready.
Regeneron’s antibody treatment, referred to as a “COVID cocktail,” is showing promise in reducing the length and severity of the virus in people who have been exposed.
It’s an injection of antibodies that could be used to protect caregivers or those who have been exposed to the virus.
Researchers at UTHealth are investigating if the strategy, which is currently used for tetanus, rabies, hepatitis B, and some herpes exposures, could prevent COVID-19 in people who have had sustained exposure to someone with the virus.
They’re researching whether injections of REGN-COV2, a combination of antibodies originally isolated from patients who have recovered from COVID-19, could help stop the spread.
Doctor Jonatan Gioia, a research associate at McGovern Medical School at UTHealth, said they need a diverse population to take part in this trial. He said people in the trial can be compensated for participating.
“Those antibodies...are a rapid response to the people who get COVID and that may help them reduce their symptoms or prevent hospitalizations. Or in this case, rapidly prevent COVID in people who live with people who have been diagnosed with COVID,” Dr. Gioia said.
To find out if you qualify to join, call 409-234-1398.