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The Wind Panel was created to be the next generation of onshore wind turbine, going beyond current technologies available on the market for capturing wind energy.
The production of electricity in Poland based on the burning of coal grew in March 2020 to 50.21 percent from 46.79 in March 2019, according to data from state owned transmission system operator PSE.
The European Commission (EC) on Tuesday approved PLN 232 million (EUR 54 million) in EU funds to support the construction of a power transmission line between Gdansk and Slupsk, northern Poland. The total cost of the investment is PLN 1 billion (EUR 232.5 million).
The amount of wind-generated electricity is on the rise, and is expected to keep on growing.
Poland's Industrial Development Agency (ARP) has signed a letter of intent with US company General Electric in a bid to boost the country's competence in conventional and new renewable energy generation, ARP said in a news release on Friday.
RWE Renewables announced on Friday that it had purchased shares in four wind farm construction projects, with a total potential of 1.5 GW, in the Polish part of the Baltic Sea.
Polish billionaire and business mogul Michał Sołowow seeks to build or take over operating onshore wind farms as well as invest in offshore wind projects, the daily Puls Biznesu wrote on Thursday.
Addressing accusations that the government has frozen the development of wind farms in Poland, Prime Minister Mateusz Morawiecki told public radio on Wednesday that some "huge projects" are being developed on the Baltic Sea.
With the EU pushing renewable energy PGE has unveiled a programme to boost solar and wind capacity.
Lietuvos Energija and Eesti Energia, state-owned energy companies in Lithuania and Estonia, respectively, want to invest in Poland. They are researching Polish wind energy and photovoltaics assets, reports Thursday's issue of the "Puls Biznesu".


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domain: chemistry


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Beyonce’s Camp Responds To Second Pregnancy Rumors
Earlier this month, bionic boob bandit Beyonce was caught on camera at an odd angle while on stage during one of her “Mrs. Carter” tour concert stops looking like she might have another little bun in her oven.
Bey’s camp had initially been quiet about the possible pregnancy chit-chatter, but a recent concert date cancellation has fueled the knocked up rumors even more.
via Yahoo News
Beyonce is canceling her Tuesday concert in Belgium because of dehydration and exhaustion.
In an email to The Associated Press, the singer’s publicist says Beyonce has been advised by her doctors to rest. She was scheduled to perform at the Sportpaleis in Antwerp. The show will be rescheduled and tickets can be used at that show.
Her next tour date is Wednesday at the same arena. The statement says “she is awaiting word from her doctors before making a decision.”
The King Bey camp must have figured they better say something in response after word got out about this cancellation amidst the preggo whispers, because they finally broke their silence shortly after. Hit the flip to hear what they had to say….
Despite the pictures and even alleged “confirmation,” from music industry insiders, camp Beysus says there’s no sibling for Blue Ivy on the way just yet.
via US Weekly
Is Beyonce pregnant with her second child? Uh-oh, uh-oh — no. In Monday’s Page Six, the New York Post claimed that the “Grown Woman” singer, 32, is secretly expecting her second child, and took pains to keep her growing curves under wraps by donning a tight leather corset at last week’s Met Gala in NYC.
Multiple sources close to the superstar, however, tell Us Weekly the report is inaccurate. “This rumor again?” marvels one insider. “Don’t be silly.”
Chimes in another pal: “I know another kid is in the future, but it wouldn’t make sense for her right now while on tour.”
Indeed, Jay-Z’s wife is currently in the midst of her grueling Mrs. Carter Show World tour, with daughter Blue Ivy, 16 months, in tow. “I would like more children,” Beyonce said on Good Morning America last week. “I think my daughter needs company. I definitely love being a big sister.”
It’s no secret that Bey being knocked up doesn’t stop her from doing the most when it comes to her career, so we’re still thinking the Carters are expecting but keeping it on the low.
Who do you believe, Bossip fam?

domain: celebrity


Brook Harris is a 14 year old up and coming musician with a talent for musical interpretation and performance. Vocal studies in speech language singing began at age nine, followed by piano and guitar studies. The Abbotsford, B.C. vocalist and guitarist began writing her own songs in 2009, and recording early in 2010. Currently, she is putting the finishing touches on her debut CD. Brook tackles catchy songs with heart and soul, and focuses on music that has a powerful message. Brook’s music evokes strong emotions in her listeners, and her audience cannot help but be touched by her unique and impassioned sound. Her sound is described as indie pop, with faint undertones of jazz and country intertwined.
Many of Brooks’ songs speak to the adversity she has faced and overcome in her life. At the age of eight her mother passed away suddenly and her life was turned upside down. Brook’s endearing, likeable personality, combined with her unique vocal sound, make her a crowd favorite with the locals in her hometown. Brook holds a musical maturity that is uncommon for a young teen. Her amazing, natural vocal ability is surprisingly fresh and honest. Brook stands by the motto of a musical mentor when she says, “We were created to be creative.” Brook is currently in grade 8 and resides in Abbotsford, B.C. with her parents, two brothers and two sisters.


Metabase version v0.37.4
My DB stores ipv4 addresses an integer. INET_ATON
In Metabase how do I easily convert the integer to ipv4 dot-decimal notation when displayed in a question result?
Ideally, I would like to be able to click the column drop-down for the IP Address column > Formatting > INET_NTOA
If this is not the right way to use Metabase, I would appreciate some guidance on what I am doing wrong.


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Coffee County detectives are attempting to identify two men involved in an armed robbery at Evans Grocery on Ga. Hwy. 32 West around 2:30 p.m. Thursday, Jan. 24. The armed perpetrators entered the store demanding money and left with an undisclosed amount of cash.
Anyone with information on this incident is asked to contact the sheriff's office at (912) 384-4227 or the E-911 non-emergency line at (912) 384-7675. Information can also be shared through our Facebook page.

domain: news


Next come two options for the table saw’s trusty sidekick, the jointer, as well as for the thickness planer. Because it’s usual to work between all three tools when dressing lumber, the first option, shown in the illustration, locates the jointer nearest the saw to the right of its extension table with the planer nearby. As with the table saw, it always makes sense to align these tools with the shop’s long axis.
With an orbital sander and good sandpaper you can smooth wood evenly and easily with first-class results. When flush-sanding solid edge-banding, draw a squiggly line across the joint before sanding. The edge-banding will be slightly proud of the plywood veneer, so the pencil marks provide a visual aid to make sure that you’re sanding flat, and that you don’t sand through the plywood’s veneer. As you go, you can also test for a smooth, level transition by gently scraping your fingernails against the transition. If it’s smooth, your fingers will not catch on the seam between the two pieces
My hand tools are stored in a cabinet built into my bench but my shop supplies, air tools, and a plethora of “misc stuff” is in a cabinet on the other side of the shop, and my clamps are mounted on a wall adjacent to my bench, where conventional wisdom says tools should be. I just like it that way. I run my DC overhead and drop down… because my floor is on a slab. My bandsaw is mobile so I can pull it out of a semi-alcove for resawing, otherwise it stays in place for small operations (20″ bandsaws are cumbersome to move, even on leveling casters).
With the advances in modern technology and the demands of industry, woodwork as a field has changed. The development of Computer Numeric Controlled (CNC) Machines, for example, has made us able to mass-produce and reproduce products faster, with less waste, and often more complex in design than ever before. CNC Routers can carve complicated and highly detailed shapes into flat stock, to create signs or art. Rechargeable power tools speed up creation of many projects and require much less body strength than in the past, for example when boring multiple holes. Skilled fine woodworking, however, remains a craft pursued by many. There remains demand for hand crafted work such as furniture and arts, however with rate and cost of production, the cost for consumers is much higher.
Here’s an easier way to stain or seal chairs, lattice or anything with numerous tight recesses. Pour the stain into a clean, empty spray bottle ($3). Spray the stain onto the project and wipe up the excess with a brush or rag. The sprayer will squirt stain into all those tight, hard-to-reach cracks and joints. — Valrie Schuster. Learn more about staining wood.
Instead of permanently mounting my 6-in. vise to a work-bench, I attached it to scrap plywood so I can clamp it wherever I need it. Stack two pieces of 3/4-in. plywood and screw them together with 1-1/4 in. drywall screws. Mark the vise-mounting holes on the plywood and drill 3/4-in. guide holes through both pieces. Recess the nut by drilling through the bottom sheet with a 1-in. spade bit using the 3/4-in. hole as a guide. Fasten the vise to the plywood with bolts sized to match the vise-mounting holes. If the bolt shafts are too long, cut them off with a hacksaw. — LuAnn Aiu. Plus: Learn how to use vise grips to pull nails.
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The thickness planer can joint a board's face. On this simple jig, the stock is supported by twin rows of wood screws driven into a platform and adjusted to meet the varying clearances on the underside of the board. The stock rides the sled cup side up. Slide the board slightly sideways to adjust the screws, then seat it firmly on the screw heads for planing.
Not long ago, I needed to make some angled wood parts to build a new soffit on my garage. I didn’t have the customary tool for the job, but I had some steel joining plates. I screwed through one of the holes in the plate, set my angle, then added another screw to lock the angle. I could then use it as a template to mark all the pieces at the same angle and cut them with my circular saw. — Ryan Bartsch
If your table saw is near a wall and your shop is fairly narrow, positioning the jointer and planer against the opposite wall is reasonable, as shown in option 2 in the illustration. If the shop isn’t long enough to accommodate long workpieces, try to put these machines near an operable doorway, as shown in the illustration and in the photo of Doug Warren’s shop.


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This has been a somewhat odd week for Street Fighter V as the strategic reveal of new characters was upset by the accidental reveal of a new fighter, Laura, by Famitsu almost a week ago while sharing Zangief screenshots. She seemed to be a Brazilian fighter that utilized electricity and Brazilian jiu-jitsu, but that was all that could be ascertained from the screenshots.
Now Laura has been officially revealed with a gameplay trailer shown below. She is a brand new character and is confirmed to be a Matsuda Jiu-Jitsu master. She seems very similar to Blanka in many respects, which isn’t a bad thing.
As well, there are various screenshots from the Famitsu reveal that will be shared below.
Be sure to keep checking back for the latest Street Fighter V news.
Founder and Editor of PC Invasion. Veteran PC gamer of over 22 years.

domain: game


Ontario’s biggest Wizarding Festival Will Play Host To A Harry Potter Actress Join thousands of others at the biggest wizardry…
As Seen On
At Transfigured Town, our favourite stories have always involved ordinary people coming together to do extraordinary things for those that need their help.
We’ve been there as three wizards worked together to save the wizarding world. We’ve watched as companions stepped into a phone box and travelled through time and space to help people in danger. And we’ve jumped for joy when old foes have put aside their differences to see off the forces of evil.
And then we realised – why can’t we do that, too?
That’s why our events aren’t just a chance to geek out with like-minded fans, they’re a chance for ordinary people like us to come together and do extraordinary things for people that need help, just like our favourite characters have always done.
Helped out today at the Harry Potter Festival in Goderich. Was so great seeing all the adults and children come and have fun. Wizards were everywhere! Tired but a great day!
A big thanks to all of you witches and wizards, for such a truly magical event! Hope to see you all again next year in Diagon Alley....
It felt like I got a glimpse into the wizarding world of Harry Potter right here in southwestern Ontario. Everywhere you look there was a new surprise, a snitch hanging from the ceiling, the hilarious wizard lead tour of muggle artifacts, amazing cosplay costumes of the other festivals goers and tons more.
Let Your Geek Flag Fly
As a team of proud Potterheads, Whovians and Jedi, nothing makes us happier than bringing people together under the banner of geekiness.
That’s why we always try to create events that have you running to grab your cloaks, practising your swishing and flicking or straightening your bowties. (Because bowties are cool, you know.)


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Hi! I am traveling to many places to get away from my kids and I shall tell you about the water cycle.
Here, we see evaporation occurring since the water is being evaporated into the air.
And up here, we see transpiration since water from within the plants is evaporating
We are going to pretend that the arrow pointing right is showing runoff. Runoff is the excessive flow of rainwater.
Here, we see that water has ACCUMULATED into a lake.
I have never seen colorful precipitation! It's a strange world we live in...
I wish I knew where we were.At least we know the process of condensation occurred here since there are cloud formations.
(For legal purposes, this is a joke)
Ahhhh finally back home. I should get going, the children I kidnapped in my basement are starting to cry!

domain: geography


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This week we are going to talk about character. I know that I said we would talk about plot next, but I decided that we should talk about character first. This is because I believe plot should usually be built upon setting and character; together they are the building blocks of a well written story, and without them, plot means nothing. The greatest story in the world will fall flat on its face if nobody cares, and without a great character-or at least a decent one-nobody will care.
For many writers, character is the first thing to appear when they are working on a story. This does not make it the easiest; a character may say hello to a writer days before they give the writer a name, and months before they tell the writer their story. Characters are part of us, but they are also outside of us. I think our subconscious knows what’s going on, but our consciousness is making constant objections, thinking the character should do things differently. The purest writing is created when conscious and subconscious meet, but I’m not here to talk about the philosophy of writing.
It is not only the reluctance of some characters which makes this part hard; it is the fact that to create a beautiful story, a masterpiece, you must not only know your main character well, but also your secondary characters, and especially your villain. Today I’m going to talk about some basic exercises which will help you get to know your characters.
The first thing to do for each of your characters-including your villain-is to build them a basic profile. This profile will consist of name, age, height, weight, physical description, dominant personality traits, and a one-to-four paragraph bio. The bio isn’t supposed to contain all the details of their life, rather it is there to hold the most important facts about your character. We’ll talk a bit more about character references when we start talking about characterization in story.
The second thing to do is to talk to your characters. This can be an interview-check out these sample questions-but I suggest that perhaps it shouldn’t be. I find it’s much more productive just to have a simple conversation about life. The conversation might turn into a debate of some sort and it likely won’t stay simple, but it’s more likely to produce good results than an ordinary interview.
One of the best ways to get to know your characters-and the last I’m going to talk about today-is by writing short pieces from their PoV. Essentially akin to the prompts I do here every week, putting your character in a series of interesting situations is one way to get to know them-let them do whatever they want and you’ll soon learn what kind of person they are by how they deal with different situations. You can make these pieces before or after that character’s story, but you won’t want to make them during-then they don’t add all that much depth. Let them surprise you; you learn more that way.
Setting and plot can tell you a lot about character; a very religious world will tell you that your character is either religious as well or oftentimes shunned. A plot about a spunky princess tells you that your character must be female, a princess, and capable of learning how to kick some bad guy butt. But character can also tell you a lot about plot and setting. A character who has been cast out of her religious order for a sexual act shows us a land where sex is taboo and dark; a character who partakes in fertility rituals speaks of an entirely different kind of society. And the prince regaining his throne story might fall flat on his face if the prince would sooner die-though it’s more likely to fall flat on its face if he’s just a jerk.
As a final note, we should never stop learning about our characters. They always have more to tell us, more to say. And they almost always have something interesting up their sleeves, if only you are willing to listen to the surprise.
How do you develop your characters? Have any of them seriously shocked you?
Previous posts in this series:
Setting and its Purposes in Early Planning
5 Questions to Ask Yourself when Starting a New Project

domain: literature


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Daniel Cage’s debut solo album sounds calculated to appeal to those prematurely approaching middle age. Co-produced by Kevin Killen (with Cage and Phil Nicolo), who has worked with U2 and Peter Gabriel, it has some of the production sparkle of their better albums but none of the invention that Gabriel especially is capable of.
The music is a combination of horror movie keyboards and chord progressions you’ve already heard over and over again if you’ve been listening to pop music for even a few years. And you will hear them more than once on this album, along with impressively played but meaningless guitar effects going deedle-dee, and machinelike, but acoustic drumming.
Cage says he brought so many hands on board (the album was also mixed by Joseph Puig and the ubiquitous-in-’80s-rock Bob Clearmountain) because he wanted to insure the record wasn’t “myopic.” But what he has done is to allow others to paint over his glasses, going so far as to lose his vision, or at best subsume it to others’ instincts.
I would be curious to hear “stripped-down” version of some of the songs, though. The album makes them seem like potentially interesting house guests that have been dressed up and gone out of their way to make a good impression, and in so doing have masked everything that might make them interesting in the first place. Funnily enough, this Daniel is not in a lion’s den but in a cage of rock expectations. I believe he has some good things to say, but they won’t be heard until he can push them above the crowd.
And the shame of it is, buried under all of this is a talented lyricist. Musically, it’s been done, but Cage shows real skill with words. I mean he’s no Elvis Costello or anything (but who among us is?), but like flowers plucked, cut, and put in water where they’re presentable but will surely die, these songs are unlikely to live long once the CD has stopped, with only the rare exception (“You Set Me Free” being one).
If and when Napster takes over the world, albums like this will be exhibit A in the case for what the big record companies did to music.

domain: entertainment


Having issues with the image 1 section arrow on my theme. I tried all of the different options in the screen shot attached and it is not working. I actually tested the demo site as well and noticed the arrow isn’t working on that either. I’ve tested this on Chrome, Safari and Firefox. The arrow function only works on Firefox.
Chrome and safari are not fans of jumplinks. Here is thread about it. We are hoping that this is solved in the next round of browser updates.
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This is my third book by Robert McCammon and the second in the Matthew Corbett series. I liked Matthew in the first of the series and was very pleasantly surprised to find I like him even more in this book. The "good" characters are likeable and the "bad guys" are very bad, indeed, and the plot was engrossing. The history is interesting, there are gruesome crimes, sword fights, plenty of action, wonderful development of relationships with the other characters and thankfully, none of the "gross" language that is so common today. The ending insures I will be listening to the third in this series.
The narration is first class and only adds to the enjoyment.
I highly recommend this series.
I never expected to be so overwhelmed. I loved everything about this book. I will not be forgetting the title, the plot, or the characters anytime soon! If you like wilderness stories, do not miss this.
The characters are unique, interesting and likeable. The mystery is in the development of the story which I really appreciate. Have loved every single book!
Interesting storyline about teenagers coming to term with life and just how far parents should go to protect them. Really liked the main characters and the realistic emotions faced by them and their families.
Absolutely loved this story. The characters are fun, loyal, outrageous and endearing. I will definitely want more of this series.
The story is up to Nesbo's standards, but the narrator keeps getting in the way. I was hoping I could adjust, and I did, but definitely detracted from my enjoyment.
This should be the guide for great storytelling novels! Understandable that this was the basis for Tarzan and Indiana Jones. Absorbing from first sentence to last and action aplenty!
Maybe it's because the previous books were so outstanding, but for whatever the reason, I was really disappointed in Book 5 of the series. I was expecting the usual instant connection with storyline and characters only to wait, wait and wait, and it never happened.
Time and again I was tempted to just stop listening, but persisted thinking surely the magic would happen, but it did not. Hope the next book is back to the usual standards.
Huge thank you to Audible to for bringing this novel to my attention. Like many of my generation, I read On The Beach in high school in the early 60's and was very familiar with the name "Nevil Shute" but was unaware of the other novels he wrote. I check the Daily Deals everyday and what a prize I picked with this one. Based on enjoyment, it is the best value I have ever received from Audible. Robin Bailey's narration was perfect for me. From the first word, I was hooked. It was as if we were old friends, and he was telling this story just to me. Enjoyed every second and hated to see it end. One of the few books that I will definitely listen to again.
My second Q, and promptly downloaded 3rd in series.
Would have been a 5 star but narration was difficult at first. First class detective story!
Ethiopia is physical setting but draws characters from all over. With such a diverse history, the participants in this wonderful novel come together and weave a spellbinding story of family, dedication, faith, and history. Not to be missed, this is one of my favorites!
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domain: library


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Looking to join Bunkazilla as a fellow monster of culture? Well, this is where you can express your interest in getting involved with the radio station and website. You can currently get involved in the following areas:
We are very keen to start bringing in online DJs for daily live slots across our weekly programming, ideally weekday evenings plus weekend daytime and evenings. Whether its music-based or talk radio and fused to geek culture themes, we’d love to hear from you. Our online platform allows remote connection either using the provided software from the broadcasting platform or by alternative programs.
Bunkazilla Original Show Runner
Do you have an idea for a pre-recorded radio show that you think might be suited to Bunkazilla’s audiences like Passion Project, Boardgames with Bez or A Redhead’s Ramblings? We’d love to hear your ideas and suggestions. Fill out the form to tell us a little bit more about your idea and see if we can make it a reality.
Syndicated your existing Podcast or Radio Show
Do you have an established podcast or radio show you want to showcase and widen your audience? Then Bunkazilla may be the place for you to roar next. We currently are a broadcasting platform for shows such as Hustlers of Culture, Hardcore Genki Hour and Bela Lugosi’s Shed. We’re always on the lookout for additional shows to join the line-up. If you think your show will suit our audience, fill out the form and provide a few examples of the show below.
Write for the Blog
The Bunkazilla Blog is a place for all our monsters of culture to share their thoughts and views. Whether it’s reviewing the latest movie blockbusters, recommending a new anime for people to try, or even sharing their adventures at the various cons across the UK. We’re always on the lookout for more contributors to the blog who have distinct, unique, voices or views on the ever-expanding world of geek culture. We also try to attend as many events as possible.
We are actively recruiting for these roles on an on-going basis so if your eager to get involved, please fill out the form and we’ll be in touch as soon as possible to discuss how you can get involved. Please note that DJs, Show Runners and Blog Contributor roles are on an unpaid voluntary basis at this time – Bunkazilla is still in its infancy and we are currently looking at numerous ways to bring in revenue to help cover currently monthly operating costs. We hope to review this in the near future.

domain: hobby


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Helices in proteins play an important role in a variety of fields such as biology, medicinal chemistry, and organic chemistry. Therefore, stabilized helical peptides have been developed in recent years. As tools for peptide-helix stabilization, non-proteinogenic amino acids such as α,α-disubstituted α-amino acids, cyclic β-amino acids, and cross-linked side chains are often utilized. Herein we report secondary structural control of short peptides using L-amino acids, D-amino acids, α,α-disubstituted α-amino acids, and cross-linked side chains. Furthermore, we applied the stabilized short helical peptides to the catalytic enantioselective epoxidation of α,β-unsaturated ketones, to the inhibitors of vitamin D receptor(VDR)-coactivator interaction, and to the efficient cell-penetrating molecules.
Various types of functionalized fullerenes have been widely developed by considering unique reactivities of the spherical reaction sites; such as not only the enhanced reactivity due to the curved and thus strained C=C double bonds, but also the multiple addition and its electronic control for the selective monoaddition, the regioselectivity controls by spherical π-conjugation and by twisted C=C double bond, the unprecedented substitution mechanism, the highly symmetrical multiple addition via fullerene anion, and the drastic reactivity change by ion encapsulation. The derivatives also proved effective against many potential applications to CMP polishing slurry, antioxidant, anti-inflammatory agent, resist materials, n-type materials for organic photovoltaics, and more.
Four types of synthetic applications of indium(III) salts as characteristic Lewis acids have been discussed. (1) Reductive functionalizations of carbonyl compounds were assisted by a catalytic amount of indium(III) halides, which achieved reductive chlorination and reductive Friedel-Crafts alkylation of aldehydes or ketones, moreover presented reductive allylation and reductive aldol reaction of esters. (2) Direct substitution of hydroxy groups of alcohols and carboxylic acids were also achieved by characteristic interactions between indium trihalide catalyst and silicon moieties. (3) Indium halides catalyzed direct couplings of alcohols with carbon nucleophiles such as enol acetates or 1,3-dicarbonyls were achieved. (4) A novel type of carboindation of alkynes or alkenes was successful, in which direct anti addition of indium tribromide and carbon nucleophiles to alkynes or alkenes takes place.
Although quaternary onium salts-catalyzed phase-transfer reactions are generally believed to require base additives, we discovered even without any base additives conjugate additions of 3-substituted oxindoles to nitroolefins proceeded smoothly in the presence of lipophilic quaternary ammonium bromide under water-organic biphasic conditions. The mechanism of this novel base-free neutral phase-transfer reaction system was investigated, and the assumed catalytic cycle was presented together with interesting effects of water and lipophilicity of the phase-transfer catalyst. The base-free neutral phase-transfer reaction system could be applied to highly enantioselective conjugate addition and aldol reactions under the influence of chiral bifunctional ammonium bromides as key catalysts. The efficient approach for the design of chiral quaternary phosphonium bromides as chiral phase-transfer catalysts was also introduced. A catalyst library with various structures has readily been constructed by the use of commercially available chiral phosphines as catalyst precursors. The optimized catalyst has successfully been applied to highly enantioselective conjugate additions and sulfenylation under base-free neutral phase-transfer conditions with low catalyst loading.
DNA is an attractive chiral source because of its unique helical chirality. Recently, DNA-based hybrid catalysts, self-assembled from DNA and a metal complex with a specific ligand through supramolecular or covalent anchoring strategies, have been developed and applied successfully in a variety of carbon-carbon or carbon-heteroatom bond-forming reactions. Now these enticing biohybid catalysts are expanding their role in asymmetric synthesis. In this review, we summarize the advent and significant progress of DNA-based asymmetric catalysis and discuss remaining challenges for future applications of DNA-based hybrid catalysts.
Polycyclic aromatic compounds possessing heteroatoms are one of the most important materials for organic electronics. Because of the lack of a suitable synthetic methodology, only a few polycyclic aromatic compounds with ring junction heteroatoms, heteroatom-doped nanographenes, have been synthesized to date, even though theoretical investigations have suggested that those molecules are attractive not only as the electronic materials but also as substructures of heteroatom-doped nanocarbons. Herein, we describe development of novel tandem hetero-Friedel-Crafts reactions and their application for the synthesis of heteroatom-fused polycyclic aromatic compounds. These compounds showed strong luminescence or carrier transport ability, thus can be a promissing class of organic materials for optelectronic devices. We have demonstrated their potential utility by fablicating phosphorescent organic light-emitting diodes with a sufficiently high efficiency and a long device lifetime.
Organic macrocycles have been attracted much attention as functional host molecules that selectively recognize and encapsulate small molecules such as ions and organic molecules within its cavity. Usually, artificial organic macrocycles are synthesized by repetitive connection of monomer units and cyclization of linear oligomers formed thereby. In this context, there have been problems in the control of the number of units or in the selectivity of cyclic products over linear ones. This review focuses on recent breakthroughs that achieved the synthesis of novel functional macrocyclic molecules from fresh and original points of view to overcome the synthetic challenges.
An aziridine is a highly strained, triangular molecule that has been recognized as an invaluable synthetic intermediate as well as a structural motif of bioactive molecules. Numerous catalytic/stoichiometric, racemic/asymmetric methods for synthesis of N-protected aziridines have been demonstrated but a practical method for direct N-H aziridine synthesis has been missing for decades despite of its promising utility for drug design. The present review describes recent developments of intermolecular N-H aziridine synthesis as an emerging field of potential application to practical and stereoselective synthesis.
Development of direct catalytic anti-Markovnikov addition reactions of oxygen nucleophiles to simple alkenes is a difficult challenge due to the propensity to form Markovnikov adducts under ordinary reaction conditions. Herein selected recent examples that realize these reactions with high anti-Markovnikov selectivity are summarized.


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We are ready to see what comes next for Nathan and Nora. The bad news is Amazon isn’t. Upload Season 3 will not arrive this month.
All eyes are on when the next season of the Robbie Amell series, Upload, will arrive on Prime Video. It’s been more than a year now since the second season, and there are no signs of the third season arriving any time soon.
That’s right; it is not on the list of arrivals in April 2023. When you consider the final season of The Marvelous Mrs. Maisel is the big show of the month, that shouldn’t be too surprising. Even if the episodes of Upload Season 3 were ready, Amazon would need to be strategic with the release.
When will Upload Season 3 come to Prime Video?
Production came to an end in November 2022. I’ve seen a lot of publications sharing that the new season was expected at some point in the first quarter of this year, but that doesn’t make sense and there is no source for this. I can’t wrap my head around the claim, to be honest.
While I do think 2023 is likely, I think it’s going to be toward the end of 2023. This is simply based on how long post-production takes for this series.
Season 2 wrapped production in April 2021 and the season arrived on Prime Video in March 2022. That’s 11 months of post-production. If Season 3 wrapped production in November 2022, we’re looking at October 2023 as a release date for the season.
This is plausible and could work for the scheduling of other shows. The Wheel of Time is another big fantasy series that needs to drop a new season and is expected some time this year. We could see that show in the summer and then Upload in the fall to space out big content and keep subscribers on the platform.
Upload is available to stream on Prime Video.


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Royalty free front porch clip art, vector images, two house clipart clipart suggest. Railing clipart clipground. Porch clipart wooden pencil and in color porch clipart.
3 ways to decorate a porch wikihow, royalty free front porch clip art, vector images. Back porch clipart clipart suggest. Vector illustration stairs leading to the door the.Published on June 12, 2019
Tag: Porch Steps Clip Art

domain: artistic


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News release from the Alberta Law Enforcement Response Team (ALERT)
Cocaine seized after four Edmonton homes searched
More than two kilograms of cocaine, cash, and four vehicles have been seized following an ALERT Edmonton investigation into cocaine trafficking.
The investigation began in October 2022. Police were able to identify four homes and four vehicles linked to the drug trafficking operation.
“Through the course of this five-month investigation, officers were able to identify several suspects, and seized several pieces of equipment which were being used to produce large, commercial-sized quantities of product. This tells us that this was a much bigger, sophisticated operation,” said Sgt. Jeff Woodliffe, ALERT Edmonton.
On February 23, 2023, police searched four homes and seized the following items as evidence:
- 2.6 kgs of cocaine;
- 28 grams of methamphetamine;
- 10 kgs of a cocaine buffing agent; and
- $11,000 in cash.
The investigation remains ongoing as investigators prepare reports and disclosure for Crown Counsel.
The Edmonton Police Service assisted throughout the investigation.
Members of the public who suspect drug or gang activity in their community can call local police, or contact Crime Stoppers at 1-800-222-TIPS (8477). Crime Stoppers is always anonymous.
ALERT was established and is funded by the Alberta Government and is a compilation of the province’s most sophisticated law enforcement resources committed to tackling serious and organized crime.
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Tiger stripe is a feature of maple in which the growth of the wood fibers is distorted in an undulating clairvoyant pattern, producing wavy lines known as "flames." This effect is called "figure," as the distortion is perpendicular to the grain direction. Prized for its beautiful appearance, it is used frequently in the manufacturing of musical instruments, such as violins and bassoons, and fine furniture.
The brass head has a slight bell shape to optimize the striking action when impacting a chisel or gouge handle. They are made from the highest quality materials in a foundry in Vermont.