text: when condensed with primary amines are reported as not being as thermodynamically. Structurally amines resemble ammonia in that the nitrogen can bond up to three hydrogens, but amines also have additional properties based on their carbon connectivity. Thesis Presented for the Degree of Master of Science by Research By Brian O’ Sullivan B. Phenolpthalein changes colour at around pH 9 which is commonly the pH at which an amine. 12 aPHa max. , dopamine, epinephrine,. salicylates, amines, glutamate, monosodium glutamate (MSG)) or artificially added (e. Primary amines are organic compounds that include the functional group -NH2, that is a nitrogen atom attached to two hydrogen atoms by a single covalent bond to each. Choosing a name for your bunny is one of the fun things about getting a new rabbit. Determination of Aspirin using Back Titration This experiment is designed to illustrate techniques used in a typical indirect or back titration. The tighter, rounder the atom, the. It is one of the four isomeric amines of butane. Currently, there are 24 carcinogenic amines which are banned (as releasable amines from azo colourants under reductive condition) in textile and leather by global legislations. The program examines each residue and compares it to the other residues in the same column. "Total Chlorine" is measured when DPD#3 tablet is the added and the colour deepens after a few minutes. , Sz/zz/ki-cho 1-1, Kawasaki 210-8681, Japan. Secondary (2°) amines—Secondary amines have two organic substituents (alkyl, aryl or both) bound to the nitrogen together with one hydrogen. It may present as urine that is red to brown, or as frank blood. ORIGINAL_ARTICLE 131-144 en 2016 15 2 Reza Amiri Chayjan Behnam Alaei Ahmed, J. b) Colour Common coloured compounds include nitro and nitroso compounds (yellow), -diketones (yellow), quinones (yellow to red), azo compounds (yellow to red), and polyconjugated olefins and ketones (yellow to red). The nitrosation of primary aromatic amines with nitrous acid (generated in situ from sodium nitrite and a strong acid, such as hydrochloric acid, sulfuric acid, or HBF 4) leads to diazonium salts, which can be isolated if the counterion is non-nucleophilic. Spectral scans from 200 nm to 350 nm in 1 nm increments were performed on the amino acids, tryptophan, tyrosine and phenylalanine, as well as BSA protein in aqueous solution using a Synergy HT multi-detection microplate reader. Tertiary amines react with nitrous acid to form N‐nitrosoammonium compounds. The K vitamins are naphthoquinones, as are some chemical indicators of acidity or alkalinity and various dyes used to colour certain types of fabrics. In the IUPAC system of nomenclature, functional groups are normally designated in one of two ways. Chlorine is a chemical element with the symbol Cl and atomic number 17. Potentiometric titration » End point detection Many things that have been told about use of indicators in acid-base titration hold also for potentiometric titrations. After1minto 2min,add1mLofβ-naphthol solution R. Both caramelization and the maillard reaction only occur on the right producing the noticeable brown color. If given ammoniums, draw the related conjugate neutral amines, rank them as bases, and realize that the strongest amine base relates to the weakest ammonium acid. The color produced in the assay is stable and increases in proportion to a broad range of increasing protein concentrations. The dye helps during the spraying process by making it easy to indicate where you have sprayed to prevent overspraying and drift into unwanted area. If we replace one or more hydrogen atoms by substituent groups such as alkyl or aryl in Ammonia, we get a new class of organic compounds called Amines. While the conjugate acid of an amine has a pK a of about 9. Nucleophilic Reactions at the Alpha-Carbon Carboxylic acids containing a "good leaving" group at the carbon atom adjacent to the carbonyl (the α-carbon) may be substrates for nucleophilic displacement. Permissible limit for aromatic amines, PCP, TeCP and N-Nitrosamine is 30mg/kg, 0. When ammonia or primary and secondary amines are detected, a deep blue or purple color known as Ruhemann's purple is produced. CCC Sulphur Products is a 200 MT/day sulphur burning sulphuric acid and sodium bisulphite plant. com, a source of free OSCE exam notes for medical students’ finals OSCE revision Taking Gynaecological Swabs. Note that since ninhydrin is a strong oxidizing agent, proper caution should be exercised in handling this compound. Although it is possible that the aromatic amines are related to genotoxicity or even carcinogenicity, Brown HT exhibited negative in in vitro genotoxicity as well as in long-term carcinogenicity studies. A few amino acids produce a different color, however; proline, for example, produces a pale yellow color with ninhydrin. However, not many know that this peachy plum also contains over 18 essential amino acids!. But most of the time I found the color of the Schiff base is Yellow/pale yellow, so 2nd Feb, 2015. All structured data from the file and property namespaces is available under the Creative Commons CC0 License; all unstructured text is available under the Creative Commons Attribution-ShareAlike License; additional terms may apply. Peter Zhang. Typical uses include:. Jmol Color Schemes: AMINO, CHAIN, CPK, FIXEDTEMPERATURE, FORMALCHARGE, GROUP, MONOMER, PARTIALCHARGE, RELATIVETEMPERATURE, SHAPELY, and STRUCTURE. GOAL(s): Write ionization constant expressions for acids and bases; Compare strengths of acids and bases using ionization constant values; Calculate the ionization constant of an acid or base from the pH of an aqueous solution of known concentration. Abstract—Meats cooked at high temperatures sometimes contain heterocyclic amines (HCAs) that are known mutagens and animal carcinogens, but their carcinogenic potential in humans has not been established. Amino acids are the building blocks of both peptides and proteins, and each has a specific role in skin care. Get advice on hair, clothing and folds, faces, female figures and some coloring tutorials for paint Shop Pro and Photoshop. Associated With. Compared to amines, amides are very weak bases. Primary and secondary aryl aminesproduce immediate yellow or orange color, while alkyl and alicyclic amine require hot solution for color development. Tests for the Functional Groups Present in Organic Compounds Molecules of organic compounds except that of hydrocarbons can be divided into two parts, a reactive part which is referred to as functional group and a skeleton of carbon atoms called alkyl group. Dimethylamine | (CH3)2NH or C2H7N | CID 674 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities. Chemical Reactions of Amines. Many ninhydrin analogues, with the same active cyclic vicinal triketone part, have been developed since the 1980s to enhance the colour and fluorescence of the original Ruhemann's purple. Dark blue color is attributed to completely buried amino-acids, whereas red color is attributed to amino-acids with at least 75% of their relative surface accessibility accessible. Properties and Uses of Amines Amines are organic compounds and functional groups which contain a basic nitrogen atom with a lone pair of electrons. Among, aryl amines, lower members are liquids but higher members are solids. The quantitative determination of primary un- sulphonated aromatic amines in this extract may be undertaken either according to this method or to specific methods (8-11). Amines are effective surfactants that can act as biocides due to their ability to kill microorganisms. Citation data is made available by participants in Crossref's Cited-by Linking service. The most important reactions are fair as amino acid chemistry is concerned are the reactions that are utilised in the formation of peptides and proteins. Color Align Conservation: Color Align Conservation accepts a group of aligned sequences (in FASTA or GDE format) and colors the alignment. ESTERS Esters of Organic Acids The esters of glycerol are the commonest and most diverse group of glycerol derivatives. , Sz/zz/ki-cho 1-1, Kawasaki 210-8681, Japan. Amino acids differ from each other with respect to their side chains, which are referred to as R groups. - N=N group is called an azo group - HNNH is called diimide • Aryl azo compounds have vivid colors, especially reds, oranges, and yellows SYNTHESIS OF DYE Yellow azo dye 32. The experimental amine-blocked DDBSA gave the least color development of the catalysts tested without an epoxide additive. Arpadis is one of the largest chemical distributor in Europe. 12 aPHa max. behind pictures) or if the dry paint is exposed to fumes from ammonia or the amines in epoxy paints. The "lighter" polyamide or amine hardener separates from the epoxy and floats to the surface where it oxidizes and turns yellow or brownish in color. The instrument used in MS is called mass spectrometer. The identity of the coloring matter was proved by the three tests mentioned in the previous paper. Amide N-H Stretch: 3700 - 3500 (m). Amines are introduced into the pool mainly by urine and perspiration. A list of aromatic amines that may cause cancer shall not be disintegrated from the dyes under reducing conditions. Search the world's most comprehensive index of full-text books. Harish & Purvi Kakrani 28 COLCHICUM. Get CIEAT 2019 syllabus at Shiksha. Therefore all of these procedures need to be carried out "blind", and the results will be seen when a revealing agent (ninhydrin) is sprayed on the resulting chromatogram. In primary amines, only one of the hydrogen atoms in the ammonia molecule has been replaced. What are synonyms for Primary amines?. Procedure (for water-soluble phenols) The iron (III) chloride test for phenols is not completely reliable for acidic phenols, but can be administered by dissolving 15 mg of the unknown compound in 0. The increased pH of the medium is detected by color change of the pH indicators bromcresol purple and cresol red present which results in a color change from orange to purple. Glycerol heated to 135" to 140" C with an excess of hydriodic acid is reduced to isopropyl iodide. Each color pair is followed by a comma, except for the last pair. Stable, concentrated dispersions with small particles and narrow particle size distribution. The contents of biogenic amines histamine, putrescine, and cadaverine in fish sauce were determined and the bacte-ria isolated from the samples were evaluated for their amines degradation activity. Industrial epoxy coating catalysts usually fall into one of these four categories, aliphatic and cycloalishatic amines and polyamine, amides and polyamides, cycloaliphatic, and amine adducts. 12 aPHa max. acetamide 206. O-Phenylenediamine is used in t he synthesis of fungicides, corrosion inhibitors, pigments and pharmaceuticals, sulfur dispersant. This lab contains material copywritten by. Colors were always observed visually. 'Azo dye' is the collective term used to. Proline and hydroxyproline produce a yellow rather than a purple colour with ninhydrin. The completion of a titration is the end point, detected by some type of physical change produced by the solution, such as a color change. (ix) Miscellaneous Chloranil test, in which primary and secondary. Organic Letters 2012, 14 (21) , 5606-5609. The use of added base to drive the equilibrium in the formation of amides from amines and acid chlorides. • High-quality defoamer system, non-harmful to hoses, plastics or gaskets. The reaction among amino acids, except proline, hydroxyproline, and ninhydrin, produced purple violet color [3-5]. Holophane's Lighting Guides will help you get started in finding the right solutions for a variety of market and/or industry applications. False positive result: For certain dyed Fabrics a listed amine is detected under the conditions of the analytical test even though no banned azo dye is present in the garments. HAPPINESS WAS ‘74 HOURGLASS 999 SILVER ART BAR 1 Troy Oz COLLECTABLE USSC-158 17 / 18 - NIKE ; CHELSEA AWAY SHIRT SS + PATCHES / DRINKWATER 6 = KIDS. Introduction: The purpose of this experiment is to isolate a protein (casein) from a natural source (milk) and to demonstrate that the product obtained is indeed a protein by performing a number of tests on your product. Chemistry of Amines 1. Important representatives include dimethylamine, while an example of an aromatic amine would be diphenylamine. Fatty Amine Ethoxylates based on coco-amine, lauryl, oleyl amines etc. The present invention relates to a continuous process for the quaternization of tertiary amines with an alkyl halide. If we replace one or more hydrogen atoms by substituent groups such as alkyl or aryl in Ammonia, we get a new class of organic compounds called Amines. Amidoamines are reaction products of a polyamine and a fatty acid. The starting materials are phenylamine (aniline) and methanal (formaldehyde) which react together to form a mixture of amines, known as MDA (methylenedianiline). They are basically the derivatives of ammonia. This book provides an authoritative account of the properties and applications of amines with respect to the characteristics of bonded substituents and the nature of their surrounding chemical and physical environments. Aromatic amines are generally toxic. What are synonyms for Primary amines?. The two exceptions mentioned probably give a posi- 8 Ruhemann, J. Both caramelization and the maillard reaction only occur on the right producing the noticeable brown color. Amine Oxides. In ninhydrin test , if reacts with these free amines, a deep blue or purple. Amino acids are the building blocks of both peptides and proteins, and each has a specific role in skin care. The pyrroles yield colored complexes on coupling with p-dimethylaminobenzaldehyde. The mechanism of Schiff base formation is another variation on the theme of neucleophilic addition to the carbonyl group. Take 1 ml test solution in dry test tube and 1 ml distilled water in another tube as a control. In the IUPAC system of nomenclature, functional groups are normally designated in one of two ways. Amines can act as both bases and nucleophiles due to the unshared electron pair. I transferred it into a thoroughly cleaned and rinsed glass bottle with a cap having a teflon liner. This product is derived from non-aromatic amines which are not included in the list of carcinogen amines. He worked with Canadian producer Kaytranada on a few songs from his Calling Brio mixtape. The RasMol 'colour' command allows different objects (such as atoms, bonds and ribbon segments) to be given a specified colour. Construction of Propylene oxide (PO) and tertiary butyl alcohol (TBA) plant at Houston-area complex in Channelview, Tex. Lawrence Index Index. O-Phenylenediamine is used in t he synthesis of fungicides, corrosion inhibitors, pigments and pharmaceuticals, sulfur dispersant. Surgical instrument spotting, staining, and corrosion are serious problems in many healthcare facilities. This should be Amphetamine (speed)tested with marquis, it also smells like speed. The resultant solutions warmed with phenol and concentrated H 2 SO 4, a brown or red colour is formed at first soon it changes to blue and then to green. by reacting a tertiary amine and an alkyl halide in a tubular reactor at a pressure sufficient to keep the alkyl halide dissolved in the reaction mixture. (iii)Due to the−R effect of the benzene ring, the electrons on the N-atom are less available in case of aromatic amines. BASF will build a new speciality amines plant at its existing wholly owned site in Nanjing Chemical Industry Park in China. com, a source of free OSCE exam notes for medical students’ finals OSCE revision Taking Gynaecological Swabs. Edlon offers coatings in PVDF, ETFE, and FEP up to 40 mils thick, and in ECTFE and PFA up to 80 mils thick. behind pictures) or if the dry paint is exposed to fumes from ammonia or the amines in epoxy paints. The present invention relates to reaction products H of at least one cyclic urea U, at least one multifunctional aldehyde A and at least one polyol P, process for preparing thereof and compositions comprising thereof. It's not a stretch to say that amino acids are indispensable, for our skin and. In the IUPAC system of nomenclature, functional groups are normally designated in one of two ways. Because amines are bases, they can react with acids to form amine salts. The small primary amines behave in exactly the same way as ammonia. Furthermore, by adapting the substituent groups (eg aromatic rings), we can change the wavelength of absorption and tune the colour. Dealkalizing the make-up water will reduce solids that are one of the major sources of carbon dioxide. The K vitamins are naphthoquinones, as are some chemical indicators of acidity or alkalinity and various dyes used to colour certain types of fabrics. In this experiment, we will first be looking at how diffusion occurs in hot and cold homogenous mixtures. Chlorine is a chemical element with the symbol Cl and atomic number 17. 95 458 60 32 400 NA NA Provides low color with longer pot life than other cyclo-aliphatic amines, with comparable mechanical properties to aromatic amines. Gives low blush and exudation, and good flexibility. 95 315 86 46 120 12 ambient temp Longer pot life, low viscosity and good color stability. In many states the highway patrol carries two gallons of Coke in the truck to remove blood from the highway after a car accident. Colour Schemes. Primary amines are organic compounds that include the functional group -NH2, that is a nitrogen atom attached to two hydrogen atoms by a single covalent bond to each. Amide can also refer to azanide (the anion H 2 N −, conjugate base of ammonia) or to an organic amine (an anion R 2 N −). Combes Synthesis 98, 325. Colchicine is a toxic, yellowish-white amorphour or crystalline substance that darkens on exposure to light. Arylating reagents such as NBD halides react with thiols or amines by a similar substitution of the aromatic halide by the nucleophile. Our chemicals are suitable for land, marine and heritage steam boilers. Experiment #3 Hydrocarbons Page 3 φ φ φ φ v v m m m n = s s = sin sin vacuum l material i g h t b e a m lig h t b e a m Figure 2 - Index of Refraction In some molecules, even though the net charge is 0, the distribution of positive. Carbothane® 130 Clear Coat provides a smooth, high gloss durable finish that provides superior resistance to colour fade of base-coats. Two years have passed since the CCG's raid on Anteiku. Ninhydrin is not actually used in the separation process itself (is not part of the actual. As noted earlier, 1º and 2º-amines are much weaker acids than alcohols, so it is not surprising that it is difficult to force the nitrogen function to assume the role of a nucleophilic leaving group. Yellow on purple. Structurally amines resemble ammonia in that the nitrogen can bond up to three hydrogens, but amines also have additional properties based on their carbon connectivity. pdf), Text File (. for alkenes and alkynes upon. Reductive cleavage or degradation into component aromatic amines is one of the mechanisms leading to the genotoxicity of azo dyes. It is a slightly weaker base than E because of its size. Their properties generally fall between those of amines and polyamides. The female is rather less conspicuous, lacking the orange tips. Rosaleen Devery and Dr. Read your favorite manga online! Hundreds of high-quality free manga for you, with a list being updated daily. Contamination of the amine stream can. Hydrophobicity increases as the number of carbon atoms on the hydrocarbon chain increases. The purpose of coloring is to identify amino acids in an unusual or surprising environment. They are consumed in butter, shortening, margarine, salad oils, and cooking oils, as well as in animal feeds, fatty acids, soaps, personal care products, biodiesel, paints (made from alkyd resins), lubricants, and greases. Colour, sound and objects can get distorted and you can experience double vision. The color gold is cousin to the color yellow and the color brown, and is also associated with illumination, love, compassion, courage, passion, magic, and wisdom. In primary amines, only one of the hydrogen atoms in the ammonia molecule has been replaced. The "lighter" polyamide or amine hardener separates from the epoxy and floats to the surface where it oxidizes and turns yellow or brownish in color. ’ ‘Chemically, aluminum will react with the alkalis in concrete and produce hydrogen bubbles. Finding the allergen. Here is one study of the mechanism [from first page of Google search for amines air-oxidation]. b) Colour Common coloured compounds include nitro and nitroso compounds (yellow), -diketones (yellow), quinones (yellow to red), azo compounds (yellow to red), and polyconjugated olefins and ketones (yellow to red). Some sorption products of 1d with amines became amorphous, but the crystalline framework could be recovered on desorption of the amines. The oxidation of a tertiary amine leads to the formation of an amine oxide. Most aliphatic amino acids are found within protein molecules. This mixture reacts with carbonyl chloride (phosgene) to produce MDI in a similar way to the manufacture of TDI. Colour code: brown Hg Protects against mercury. The ban covers commodity goods that contain azo dyes which can form one of the following amines due to the reduction of one or more azo groups. Methods for the detection of amines and the colorimetric determination of aromatic secondary amines are described. However, all such data, statements and recommendations are given gratis and Alkyl Amines Chemicals Ltd. com offers 155 ethoxylated amines products. Shapely can be selected from the RasMol Colours menu. they can cause cancer and hence there is a ban on usage of dyes and pigments that can release such amines. Colorants are also now being used in novel applications and are termed functional (high technology) as they are not just included in the product for aesthetic reasons but for specific purposes, for example in surgery. the presence of biogenic amines. thermal motion. 34: Aspartame: Nutrasweet, a synthetic, non-nutrative sweetener: C 14 H 22 N 2 O: 234. Primary aromatic amine reacts with nitrous acid to form a diazonium salt which is stable but low temperatures. You should also exaggerate the pupils and include large white circles inside them so it looks like light is reflecting off of the eyes. 9 reviews of Amines Coiffures "This place is so amazing in every single way! From being greeted with amazing service from the owner (Kevin), to having a manicure done by the sweetest woman (which I can't remember her name)to having my hair cut &…. Red coloured, based on ethylene glycol, free from silicates, borates, amines, nitrites and phosphates, it ensures optimum protection against freezing/boiling and avoids the phenomenon of corrosion for longer periods when compared to conventional coolants. + + ANCAMINE® 2074 Modified. (HUSKY COLORS). PubChem is the world's largest collection of freely accessible chemical information. That means that the formula of the primary amine will be RNH 2 where "R" is an alkyl group. Summary notes, past exam questions by topic, flashcards and videos for OCR (A) Chemistry A-Level Module 5 - Physical Chemistry and Transition Elements. Amide N-H Stretch: 3700 - 3500 (m). The plates were then heated at 110˚C for 10 min in an oven and the colors were recorded again. February, 2000. Amines are named in several ways. Enterprises, Mumbai, Maharashtra. (Jung R, 1992). Here's what you need to know. This type of mutation causes a change in the primary structure of the protein (the linear sequence of amino acids), which can result in a change in the three-dimensional conformation of the protein. Stable, concentrated dispersions with small particles and narrow particle size distribution. Here is one study of the mechanism [from first page of Google search for amines air-oxidation]. This book provides an authoritative account of the properties and applications of amines with respect to the characteristics of bonded substituents and the nature of their surrounding chemical and physical environments. Amines can be described by classification, shape, properties, and uses. If given ammoniums, draw the related conjugate neutral amines, rank them as bases, and realize that the strongest amine base relates to the weakest ammonium acid. 3, depending on protein structural context). what is the colour of aniline?? Share with your friends. Histamine Intolerance. HAPPINESS WAS ‘74 HOURGLASS 999 SILVER ART BAR 1 Troy Oz COLLECTABLE USSC-158 17 / 18 - NIKE ; CHELSEA AWAY SHIRT SS + PATCHES / DRINKWATER 6 = KIDS. 1 Protocols for reducing fixative-induced fluorescence 3. Chlorine is a chemical element with the symbol Cl and atomic number 17. Amide > Acid > Alcohol > Ketone ~ Aldehyde > Amine > Ester > Ether > Alkane Amide is the most polar while alkane is the least. Amino acids are the building blocks of both peptides and proteins, and each has a specific role in skin care. Zhong Zhang,'it Donald L. That means that the formula of the primary amine will be RNH 2 where "R" is an alkyl group. In primary amines, only one of the hydrogen atoms in the ammonia molecule has been replaced. 4 3 / 17 In case of skin contact : Remove contaminated clothing. • Low viscosity, colour and vapor pressure • Completely miscible with a wide variety of solvents, including water • Provides tough, clear, impact resistant coatings, castings, and adhesives • Coatings are free of surface blush prevalent with many amine curing agents. 5 mL of water or water-alcohol mixture and add 1 to 2 drops of 1% aqueous iron (III) chloride solution. Tertiary (3°) amines—In tertiary. Although convenient to evaluate DDGS quality based on color, nutritionists and producers need to rec-. Wastewater Odor Control: An Evaluation of Technologies Odor control on the backburner In the modern world of wastewater treatment , control of odors has moved from an afterthought to a primary design consideration for most collection and treatment facilities. Amino Acids are fundamental ingredients in the process of Protein Synthesis. Reaction as a proton base (Section 19-5 and 19-6) RN H H N H R H H X H-X(protnacid) amine NaO base. 8 could not be undergone by a tertiary amine such as trimethylamine? Briefly explain your answer. Aliphatic amines give a brisk effervescence due (to the evolution of N 2 gas) under similar conditions. They are basically the derivatives of ammonia. However, if the cause is unknown, diagnostic tests may be needed, such as: keeping a food and symptoms diary to check for patterns. 3, depending on protein structural context). Thesis Presented for the Degree of Master of Science by Research By Brian O’ Sullivan B. Useful for students and teachers. Colour code: grey E Protects against acid gas and smoke, such as sulphur dioxide, hydrogen chloride, etc. Two years have passed since the CCG's raid on Anteiku. A color stabilized aliphatic amine composition wherein said amine has the formula: ##STR1## wherein R 1 is a primary alkyl group containing about 6-30 carbon atoms, said composition containing a color suppressing amount of an additive selected from the group consisting of nitrilotris methylenephosphonic acid, salts of nitrilotris methylenephosphonic acid and mixtures thereof. As little as 1 mL of blood can impart colour to 1 litre of urine. 2], and then followed by a cascade of reactions in foods leading to formation of different intermediates including aroma components and high molecular weight brown polymers (Nursten, 2005). The instrument used in MS is called mass spectrometer. The quantification method for all amino acids and amines was fully validated. AMINES, PRIMARY AROMATIC Acidify the prescribed solution withdilute hydrochloric acid R and add 0. 5 a Which of the reactions of amine described in Section 13. Although it is possible that the aromatic amines are related to genotoxicity or even carcinogenicity, Brown HT exhibited negative in in vitro genotoxicity as well as in long-term carcinogenicity studies. But I snorted 100mg and I barely feel anything, and when I look at things they are moving a little. The present invention concerns a process for providing tertiary amine products which are color-stable, and have a greatly reduced tendency to take on color during their storage. Amines are included in some school chemistry courses, such as UK A-Level organic chemistry for students aged 17-18, and international equivalents. Some antioxidants in coffee have been associated with fighting disease or enhancing health. Finally, it does not react with tertiary or aromatic amines. You are provided with a number of solutions of amino acids, and solution X (a mixture of 2 amino acids). Colour may vary depending on the substitution on the ring. Methionine is a good lipotropic as it helps in breaking down fat and prevents fat accumulation in arteries and specific body areas. colors were noted. Produced uniquely during the best years, when the Chardonnay (around 40%) and Pinot noir (around 60%) grapes have attained perfect maturity, Cristal is aged for 6 years in Louis Roederer’s cellars and left for a further 8 months after dégorgement. The name of the complex was hydrindatin and the color was purple. The resultant solutions warmed with phenol and concentrated H 2 SO 4, a brown or red colour is formed at first soon it changes to blue and then to green. Colour change : Corrections for temperature & humidity : Relative standard deviation : Shelf life : Performance （0. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. AZO Testing AZO dyes are the name of the group of synthetic dyestuffs based on nitrogen that are often used in textile industry. Published November 2018. Her color has faded a bit, but does not look washed out or ugly faded. Nitro compounds and nitriles are reduced to amines. Purple color develops upon reaction of amino acid with ninhydrin. The color reaction of amines with quinonedichlorodiimide (QDCI) can be used for their qualitative test. amines, is discussed in relation to both the minimisation of corrosion rates and deposit formation. Yellowing is accelerated in the absence of light (e. The Company is in the business of manufacturing and marketing various aliphatic amines, amine derivatives and other speciality chemicals for the last 30 years. Each amino acid is described by two colors separated by a blank space. Early hair dye formulations contained chemicals, including aromatic amines that were found to cause cancer in animals. (iii)Due to the−R effect of the benzene ring, the electrons on the N-atom are less available in case of aromatic amines. Each amino acid and nucleic acid residue is given a unique color. When someone refers to a polyamine epoxy he is referring to the curing agent. False positive result: For certain dyed Fabrics a listed amine is detected under the conditions of the analytical test even though no banned azo dye is present in the garments. Alkyl Amines Private Ltd in India became my primary source of acquiring the waste by-product soot. Structurally amines resemble ammonia in that the nitrogen can bond up to three hydrogens, but amines also have additional properties based on their carbon connectivity. In many states the highway patrol carries two gallons of Coke in the truck to remove blood from the highway after a car accident. The present invention concerns a process for providing tertiary amine products which are color-stable, and have a greatly reduced tendency to take on color during their storage. Generally speaking, colourants are usually either dyes or pigments. Under anhydrous conditions, ninhydrin in glacial acetic acid reacts with a number of amino acids, as well as amines and imino acids, to produce discernible colors. Some amines are carcinogenic in nature i. they are hard, good conductors of heat and electricity, and melt and evaporate at high temperatures. Manufacturer of Primary Food Colours - Brown HT Food Colors, Tartrazine Supra Food Colors, Green S Food Colors and Liquid Food Colors offered by Arun Colour Chem Private Limited, Bahadurgarh, Haryana. Aromatic amines like was detected in 32 of the 54 hair dye in concentrations up to be 88. It is also colored magenta. When reacting with these free amines, a deep blue or purple color known as Ruhemann's purple is produced. “There’s so much pollution in the air now that if it weren’t for our lungs, there’d be no place to put it all. find major application as dye levelling, wetting agents in textile formulations & detergents. Dispersant Intermediates. It can be used qualitatively (e. As noted earlier, 1º and 2º-amines are much weaker acids than alcohols, so it is not surprising that it is difficult to force the nitrogen function to assume the role of a nucleophilic leaving group. Amines are included in some school chemistry courses, such as UK A-Level organic chemistry for students aged 17-18, and international equivalents. On the other hand, Maillard reactions may reduce the nutritional value of a product, as amino acids and carbohydrates may be lost. HPLC for Food Analysis The fundamentals of an alternative approach to solving tomorrow’s measurement challenges Angelika Gratzfeld-Hüsgen and Rainer Schuster. Standard Phenol. This is only an approxiamtive scale, but perfectly sufficient to differentiate core amino-acids from surface ones. Amines are organic compounds which contain and are often actually based on one or more atoms of nitrogen. If on skin, rinse well with water. Furthermore, the color intensity developed is dependent on the type of amino acid. Test Significance 1) Ninhydrin reaction All Alpha amino acids 2) Xanthoproteic test Aromatic amino acids 3) Millon's test Confirmatory test of Tyrosine 4) Biuret test Not given by free amino acids, and dipeptides 5) Sakaguchi test Arginine 6) Hopkins Cole. Start studying Color reactions of proteins and amino acids. The magenta color represents the negatively charged amino acids. The six tests are: (1) Ninhydrin Test (2) Biuret Test (3) Xanthoproteic Test (4) Millon's Test (5) Hopkins-Cole Test and (6) Nitroprusside Test. Edlon offers coatings in PVDF, ETFE, and FEP up to 40 mils thick, and in ECTFE and PFA up to 80 mils thick. Composition** Ingredients Gms / Litre Peptic digest of animal tissue 10. In 'O' Biology practical examination, you are required to know Iodine test, Benedict test, Biuret test, Alcohol test and Sulphur test. At Azelis we encourage entrepreneurial thinking in every area of our business. All categories. The identity of the coloring matter was proved by the three tests mentioned in the previous paper. Amino acids of the general formula RCH(NH 2)COOH are amphoteric, behaving as amines in some reactions and as carboxylic acids in others. what is the colour of aniline?? Share with your friends. These salts often much more soluble then the original amine. With the exception of proline and hydroxy-proline, all the alpha-amino acids found in proteins react with ninhydrin to give the same intensely colored purple anion (570 nm). For example, heating an amine with HBr or HI does not normally convert it to the corresponding alkyl halide, as in the case of alcohols and ethers. WWW description What your thyroid pill does. Among these amines, para-phenylenediamine (PPD) is a small molecule form of aniline commonly used in beauty products despite being a known allergen to humans. Detection, quantification and identification of amino acids in any sample constitute important steps in the study of proteins. Search the world's most comprehensive index of full-text books. Besides, the modification also optimises the hardness, reactivity and handling time of the system and improves carbonation resistance. With the exception of the two tertiary amino-acids examined by Ruhemann, bases of this type do not give any reaction with ninhydrin.

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Composition: 100% Polyester interlock ripstop.
The Bullpadel Chumber Junior shirt fits perfectly to your body allowing a great mobility during the game, it is a very comfortable and light thanks to its 100% polyester fabric.
It brings a feeling of freshness and dryness since its fabric with Quicker-Dry technology that helps eliminate the humidity allowing a correct ventilation.
2 other products in the same category:


|560 N. Maybelle St|
|Tulsa Parks - The City of Tulsa Online|
Owen Park is Tulsa's first park. It offers a great playground, water playground (a splash pad with more equipment), Owen Park Pond, and Tulsa's Oldest House. The closed community center there is scheduled to become the new home of the Tulsa Children's Museum.
According to the Tulsa Parks History site, Owen Park Lake (later shrunk to Owen Park Pond) was built on a crater from an accidental nitroglycerine explosion on January 23rd, 1904. The city purchased the land from Chauncey Owen and Mary Owen in 1909 for $13,500.


Fiat has taken the wraps off the Fastback concept at the Sao Paulo Motor Show 2018. The new model features a coupe-crossover design with a steeply raked roofline, which gives it a silhouette similar to that of the Renault Arkana. The show car previews the much awaited Fiat Toro-based SUV.
Speaking at the Sao Paulo Motor Show, Antonio Filosa, President, FCA Latin America, revealed the company's plan to invest 8 billion Brazilian Real (INR 1,58,78,50,00,000) into local operations by 2023 for new models, powertrains, and infotainment systems. The company plans as many as 15 vehicle introductions in Brazil in the next five years. The production version of the Fastback concept will be one of the future models and is expected in or before 2020.
While the Fastback concept's front-end features styling cues similar to that of the Toro pick-up, the rest has a distinct styling. The interior is said to feature a futuristic look with three transparent digital screens - one displaying various vehicle-related information, one for the infotainment unit, and another to control the aircon. The steering has a flat top and bottom while the seats are upholstered in leather. The conventional outside rearview mirrors have made way for cameras, while the concept features a handle-less doors.
The company has not revealed specifications of the new model. That said, powertrain options for the production-spec version should include 2.0-litre Tigershark Flex and 2.0-litre Multijet II diesel motors. The gasoline motor will use a 6-speed automatic transmission while the oil-burner will be paired with a 9-speed automatic unit. Rumours are abound that Fiat could also offer a 1.8-litre E.torQ motor.
Also See: Fiat 1.3L Multijet engine to be phased out in India in 2020 - Report
The flex-fuel motor outputs 159 hp along with a peak torque of 195 Nm firing petrol, and 163.66 hp and 201 Nm firing ethanol. The oil-burner outputs 170 hp and 350 Nm whereas the E.torQ motor develops 135 hp and 182 Nm of peak torque.
Image source - facebook.com


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Our intimate club is inspired by New York’s jazz scene. The club has its own entrance and is located in the basement of Amerikalinjen. With a stage, state-of-the-art lighting and sound systems, a kitchen and dining facilities, Gustav can accommodate many types of events and arrangements.
The club is named after Gustav Henriksen, the founder of Amerikalinjen. In the years prior to the opening of the Norwegian American Line he was met with huge resistance, but Gustav knew that people wanted to explore, and in 1913 the first ship left the dock. His work was the start of a 60-year long adventure – for all the thousands of people who emigrated, for Amerikalinjen and for Norway. Let yourself be inspired! The club reflects Gustav’s playful, New York and jazzy side.
Come join us for Friday & Saturday Jazz sessions and experience smoky tunes and an electric atmosphere: you will always feel welcome!
Jazz Nights winter season 2023 tickets
Felix Peikli & Friends ft. Knut Kippersund
Season Premiere: The Music of Cole Porter Cole Porter was one of the major composers for Broadway in the 1920’s and 30’s - having composed more than 1000 songs and many hit musicals, he remains one of the most revered composers in jazz tradition. His numerous hit-songs include "Night and Day", "Begin the Beguine", "I Get a Kick Out of You", "Well, Did You Evah!", and "I've Got You Under My Skin" to mention just a few! Kicking off the 2023 season: Join us as Club Gustav-favorite Knut Kippersund teams up with Felix Peikli & Friends, and delve into the musical vault of the great Cole Porter!
Norsk Jazzorkester ft. Felix Peikli
Valentines Special: Jazz for Lovers Jazz has always been a key ingredient in bringing people together - jazz classics from the grand romantics such as Cole Porter and Irving Berlin have melted their way into the classic jazz repertoire for all the right reasons. This Valentines Weekend, artistic director Felix Peikli will appear with his stellar Norsk Jazzorkester and added strings to sweeten the evening just a bit more. Join us in what is sure to be a romantic evening for you and your better half as Norsk Jazzorkester ft. Felix Peikli presents their carefully selected repertoire in Jazz for Lovers!
Felix Peikli & Friends ft. Frikk Heide-Steen
The Crooner Songbook Crooner is a term used to describe primarily male singers who performed using a smooth style made possible by better microphones which picked up quieter sounds and a wider range of frequencies, allowing the singer to access a more dynamic range and perform in a more intimate manner. The crooning style developed out of singers who performed with big bands, and reached its height in the 1940s to late 60s. Crooning is epitomized by jazz vocalists like Bing Crosby, Frank Sinatra, Dean Martin, and Sammy Davis Jr. who leaves behind a vast legacy of wonder-hits and evergreens from the golden era. We look forward to the return of the multifaceted vocalist Frikk Heide-Steen, who’ll join Felix Peikli & Friends to pay homage to the biggest entertainers in history, presenting The Crooner Songbook!
Felix Peikli & Friends ft. Tricia Boutté (USA)
Celebrating Mardi Gras! The holiday of Mardi Gras is celebrated in all of Louisiana, including the city of New Orleans. Huge parades and masquerade balls accompanied by authentic New Orleans and southern jazz music are coupled with colorful and extravagant fashion to celebrate Easter and Shrove Tuesday. Homegrown, New Orleans-native, vocalist-extraordinaire Tricia Boutté will once again join Felix Peikli and Friends as they celebrate Mardis Gras and bring you back on a journey to New Orleans!
Felix Peikli & Friends ft. Venke Knutson
International Women's Day: Women in Jazz Women have been an undeniable force throughout the many eras of jazz history, as performers, composers, songwriters and bandleaders. Already in the 1920’s «Ina Hutton & Her Melodears», an all female orchestra, blazed trails through the American music industry at the same rate as their male counterparts like the Duke Ellington Orchestra, Benny Goodman Orchestra to name a few. Billie Holiday, Sarah Vaughan, Eartha Kitt, Nina Simone - the list of women who dedicated their lives and careers to the contribution of jazz is long. Join us in welcoming the Club Gustav favorite - Venke Knutson, as she joins Felix Peikli & Friends in paying homage to the heroines in jazz!
Felix Peikli & Friends ft. Christian Lundqvist
Buddy DeFranco Centennial Many couplings in jazz have made their mark in history - Benny Goodman and Lionel Hampton, Charlie Parker and Dizzie Gillespie, Miles Davis and John Coltrane. One of those was clarinetist Buddy DeFranco and vibraphonist Terry Gibbs. 2023 marks the 100th year anniversary of the legendary clarinetist Buddy DeFranco. Buddy DeFranco pioneered as one of the only be-bop clarinetists, leading the Glenn Miller Orchestra in the 1960’s and appeared in concert and on recording with legends such as Oscar Peterson, Count Basie, Art Blakey and more. Felix Peikli & Friends are joined by vibraphone-virtuoso Christian Lundqvist from the Norwegian Radio Orchestra. Join us as we celebrate the legendary Buddy DeFranco Centennial!
Felix Peikli & Friends ft. Hetty Kate (U.K.)
Celebrating George Gershwin Gershwin is one of the most prominent American composers of all times, where his body of works including legendary songs such as“Summertime”, “An American in Paris” and “Rhapsody in Blue” is forever etched into the fabric of jazz history. 2023 marks the 125th anniversary of The incomparable George Gershwin and to celebrate the occasion Felix Peikli & Friends are proud to invite vocalist extraordinaire - the Australian born, U.K. raised, singer Hetty Kate - joining us exclusively from France. Felix Peikli & Hetty Kate performed for the first time at the prestigious New York Winter Jazz Fest and will together bring Gershwin’s musical legacy to life at Club Gustav!
Felix Peikli & Friends ft. Sisi Sumbundu
The Music of Nina Simone Nina Simone was an American singer, songwriter, pianist, and civil rights activist. Her music spanned styles including classical, folk, gospel, blues, jazz, R&B, and pop, having released more than 40 albums to her name during the span of her career. Her musical reach has no boundaries leaving a legacy of repertoire such as “ I Put A Spell On You”, “I Loves You, Porgy”, “I Wish I Knew How It Would Feel To Be Free”, and “Feeling Good” to mention a few. Join us in welcoming vocalist-extraordinaire Sisi Sumbundu (fresh from “Sister Act”) as she returns to Club Gustav together with Felix Peikli & Friends, to present The Music of Nina Simone!
Felix Peikli & Friends ft. Benny Benack III (USA)
Season Finale: Birthday Blowout Spectacular! Our music curator and host Felix Peikli resided many years as a performing artist in New York, during which time he had the opportunity of befriending and performing with some of the world's leading artists. One of them being trumpet virtuoso, vocalist extraordinaire, and all around entertainer Benny Benack III. Mr. Benack III is third in a generational line of Pittsburgh jazz notables, having appeared with the likes of Josh Groban, Ben Folds, the 8-bit Big Band and the youtube sensation Postmodern Jukebox to name a few. Mr. Benack III is an emerging force of music on the global stage and will join us at Club Gustav for this season's grand finale. Join us this weekend in celebrating Felix’ 30th+3rd anniversary, the reunion with Benny Benack III and the Winter Season Finale at Club Gustav!

domain: artistic


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Large windows are a good way to connect with nature and add more sunshine into your house. But they can also be hard to cover as a result of their width.
Drapes can be hard to open, capture dust easily and are nearly impossible to wash. And other types, especially ready-made window treatments, may bow or sag over time.
When you work with a window treatment professional like Louver Shop of Charleston, you can easily design the right product for your home. And pick the ideal operating system for your blinds or shades, such as PowerView®, which enables you to move and set schedules for your window treatments with your web-enabled device.
You’ll also get many free advantages, like a consultation, professional measurements and a Louver Shop Complete Comfort™ price quote. All with no pressure or obligation.
As you start finding ideas, here are seven of our favorite best window treatments for large windows in Charleston.
1. Plantation Shutters
Although plantation shutters have been around for years, they are still a a favorite for homeowners. They’re quick to dust, are virtually maintenance-free and may even decrease your energy costs.
Selecting the proper material for your plantation shutters is crucial to prevent them from sagging on tall windows. We suggest wood, solid polymer or a combination of the two to keep your shutters looking good for years to come.
Available in a variety of stain and paint options, wood is the lightest and strongest material. Polymer shutters, commonly customized in white, offer mighty insulating effectiveness you’ll likely notice on your monthly utility bill.
Receive the top features of both materials with our best-selling Classic shutters. These shutters feature extra-strong hardwood frames and energy-efficient solid polymer louvers to keep your heating and cooling within your home.
If you want wood shutters that make a statement, reach out to your Louver Shop of Charleston professional about our Heritage shutters. These shutters are crafted from the finest American hardwoods and include broad panels for a premium look.
To enjoy more of your surroundings, design your shutters with a bypass or bifold track frame so you can effortlessly shift them out of the way. And, inquire about our PerfectView™ tilt rod, which is obscured on the reverse of the shutter panel, for an even less obstructed view.
2. Panel Track Blinds
For a contemporary appearance for floor-to-ceiling windows, there’s Skyline®.
Flaunt your personality when the gliding panels are drawn with over 600 fabrics, textures and colors. When the panels are open, they fit together tidily out of the way for a wider view.
3. Sheer Vertical Blinds
Sheer vertical blinds aren’t unfashionable. Luminette® combines everything you enjoy about sheer shades and blinds in one modern window treatment.
The sheers turn bright light into a warm glow, while the floating blinds offer added privacy. You can also upgrade your shades with an added room-darkening panel.
With Luminette fabrics sold by the yard, you can coordinate your new window treatments with matching accessories like pillows and duvet covers.
4. Horizontal Sheer Shades
If you want a horizontal shade that’s identical to Luminette, there’s Silhouette®.
With S-shaped vanes nestled between two sheers, this shade offers the feel of drapes with the versatility of blinds. The sheers transform glaring light into a light glow, while the vanes provide precise control over privacy.
You can also enhance Silhouette by incorporating ClearView® Shadings, which provide an open view of the outdoors, and Duolite®, which involves a room-darkening shade.
5. Honeycomb Shades
Use less energy in style with Sonnette™ cellular roller shades. These contemporary shades use the most wanted features of classic roller shades and energy-saving honeycomb shades.
These shades transform glaring sunlight into a light glow. And their curved pattern holds on to air to keep inside temperatures balanced and utility costs inexpensive.
6. Roman Shades
Enjoy the look of fabric shades but are seeking a window treatment that looks distinctive when shut?
Complement your interior design with Vignette® modern Roman shades, which show off flat or contoured folds when closed. These folds turn into neat pleats once you move the shade.
When creating these shades, you can pick from high-quality fabrics in sheer to room-darkening opacities. A Duolite® roller shade is available for even more light control.
7. Roller Shades
For a sleek feel for bright rooms, there’s Designer Screen Shades. With hundreds of fabric styles and multiple opacities, you’re certain to discover a color and pattern that matches your space.
These screen shades provide UV protection for areas in your home that get the greatest amount of natural light, like sunrooms or patios. By diverting up to 96% of harmful rays, these window treatments help stop your furniture and flooring from losing color.
Find the Right Window Treatment with Louver Shop of Charleston
At Louver Shop of Charleston, your local specialist is here to help make creating your new window treatments easy. We’ll help you choose the right kind for your residence’s expansive windows and offer expert installation. Since we live in Charleston, we’re only a phone call or text away. To get started, call us at 888-428-1415 or contact us online to schedule your free consultation now.

domain: design


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Today Electronic Arts announced that Battlefield 2142 has kindly transported back in time to give gamers a taste of what war will be like 136 years from now. Developed by Sweden-based Digital Illusions (them Swedes make a good war game), Battlefield 2142 is now available for an MSRP of $49.99.
In this, the latest in the long-running Battlefield franchise, players are called to fight for the European Union or the Pan Asian Coalition in an epic battle for survival. Armed with an arsenal of high-tech assault rifles, cloaking devices, and sentry guns, players will wage war using massive Battle Walkers on the ground, while futuristic aircraft rule the skies.
Battlefield 2142 supports online multiplayer for up to 64 players in the classic Conquest mode. Up to 48 players can go at it in the new Titan mode, which challenges gamers to use teamwork to destroy their opponent's Titan, a massive flying battleship, while defending their own. The game also features a deep new persistence system, with more than 40 ranks, from Recruit to Supreme Commander. Players can also customize their soldier with more than 40 unlockable weapons and gadgets for upwards of 1,000 possible combinations.
"Battlefield 2142 is a bold leap into the future for the franchise and represents nearly 18 months of development by the team at DICE," said Marcus Nilsson, senior producer at Digital Illusions. "Battlefield 2142 reinvents the classic Battlefield sandbox with all-new toys, deep persistence, and the massive new Titan mode -- the first all-new mode since we introduced Conquest mode in Battlefield 1942."

domain: news


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The technology uses AI to provide real-time analysis and interpretation of video surveillance footage, enabling patients and healthcare providers to know the status of urgent healthcare services. It streamlines emergency healthcare, leading to faster care delivery, higher quality care, and lower costs for insurance providers.
I-Corps Team Members:
- Elizabeth Chen, Philosophy, Politics and Economics undergraduate student
- Renee Kim, Cognitive Science undergraduate student

domain: medical


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Bonnie Stern, NATIONAL POST
Turkish olive salad. Youve probably been using Turkish olive oil, which is some of the worlds best, for years without knowing it.
Throughout Turkeys tumultuous past, the olive tree has remained constant. Turkey has become the fourth largest olive oil producer in the world and has approximately 160 million olive trees. In order to advance in the worlds rankings and make Turkish olive oil more well-known internationally, the National Olive and Olive Oil Council invited a group of journalists, from Canada, the U.S., China, Japan and Brazil to tour Turkeys largest and finest olive growing region. I was fortunate enough to be invited on this trip.
We drove through beautiful olive groves from Izmir to Ayvalik and Bursa, where three-quarters of Turkeys olive trees are located. We went to huge plants such as Taris and Kristal, and smaller, artisanal producers such as Kursat and Laleli. We ate at restaurants where they cooked exclusively with olive oil, we toured olive oil museums, we learned how to pick olives, we tasted superb extra virgin olive oils and sampled hundreds of delicious table olives. We loved Turkish food, which celebrates seasonal vegetables and fruits, local flavours and traditional cooking.
Agim Pristine of Torontos Cheese Boutique says: Canadians have been consuming Turkish olive oil for years without even knowing it at restaurants and under other labels. Now, Turkey is branding their own products and going international.
TURKISH OLIVE SALAD
Turkey is the second largest table olive producer in the world. This salad is similar to one we had as part of the meze at Begendik Abi, a restaurant in Izmir that follows slow-food principles and cooks traditional dishes. I used large, pitted green olives and smaller natural, dry, wrinkled black olives (like Gemlik), which I halved and pitted. Be sure to warn guests if the olives are not pitted!
- 1 cup black olives, pitted
- 1 cup green olives, pitted and sliced
- 2 tbsp coarsely chopped fresh parsley
- 2 green onions, thinly sliced
- 2 tbsp coarsely chopped fresh dill
- 1/4 cup sliced sun-dried tomatoes
- 1/4 lemon, thinly sliced
- 1 tbsp lemon juice (or more to taste)
- 1/8 tsp freshly ground black pepper or Aleppo pepper
- 3 tbsp extra virgin olive oil
Read the rest and more recipes at

domain: agronomy


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Find the top rated cross country skiing trails in Tallahassee, whether you're looking for an easy short cross country skiing trail or a long cross country skiing trail, you'll find what you're looking for. Click on a cross country skiing trail below to find trail descriptions, trail maps, photos, and reviews.
Great for marathon roller blading. I would like to see the State of Florida add mile markers.
The trail is easy and fun for a family day out. However, the path may not be ideal for roller blades. Parts of the path might be wet or have sand/dirt across it. Having said all of that I would still go back, 1.3 mile trail is a great distance for rollerblades (we did a down and back twice)!
Overall surface in great shape. Saw only a few riding all day. If your looking for speed you can ramp it up pretty good on this straight shot to St. Marks. Just pay attention at 4-5 roads crossing the path along the way.
Rode this trail today. We parked off Suwannee St in Cascade Park., it was Friday but we found plenty of parking even though we were by the Water Park which was busy. First rode trail on side of Franklin St. and was thinking this is just a wide sidewalk. Quickly we were enjoying the ride though the neighborhood the gardens and landscape was beautiful and well groomed. We rode to Tennessee across from Leon High then turned back, there was a few road crossings but there were crosswalk lights. We passed back through the park and kept going to a nice trail bridge over Monroe and then followed FAMU Way on the trail. It did not end at Pinellas Circle so we kept going. Great views of the Capital, we passed some Canadian Geese who moved slowly from the trail. We kept going until we knew we were going south and went under Orange Ave. Then we realized we were on the Tall- St. Marks Trail. So the two trail do connect. We returned to our Van at the park and explored more and found the old Utilities Building is a beautiful restaurant Called The Edison. A great ride and a showcase trail for what a local city can do with its spaces and resources.
We biked the entire trail and back, from Sopchoppy to Mashes Sands Beach. Total distance was 24 miles round-trip and took us a leisurely 3 hours. Beautiful scenery along Surf Road and especially close to the marsh and beaches at the end of the trail. Stopped at Mashes Sands beach for a light lunch. Due to off-peak tourist season, the vehicle traffic wasn't a factor, especially when trying to cross Hwy 98. A must-ride for anyone staying in this beautiful area of the "Forgotten Coast" of north Florida.
We parked at the Capital Circle Trailhead, where there are bathrooms, a water fountain, a pavilion, and a nice bench area.
Heading south, the trail is wide and smooth, with trees on either side, providing shade but not much "tree debris". The section along the Woodville Highway has a lot of road noise, but further down the trail, it runs along a less busy road and the noise drops off. The trail runs past older residences, and a few businesses. We turned around after 7 miles, but will definitely come back to explore the rest of the southern section another day.
Heading north from the Capital Circle Trailhead, the trail is obviously older, with a yellow center line. This section has few trees, and runs by businesses such as used car lots, and is not very scenic. The trail ends at a street, across from a working train yard.
This trail is a treasure to the region, and we look forward to returning again.
I rode this trail on Tuesday Oct 25, 2016. If there is parking in Sopchoppy, I couldn't find it. Just park at the boat ramp at the Mashes Sands end. There is a bathroom there, but that's it until you reach Sopchoppy. Leaving Mashes Sands, there are a few STOP signs on the trail, but not much traffic. You have to cross 98 after about a mile, but visibility was good at a well marked crossing. Then you will pedal your way out into the St. Marks Refuge which is very nice. Prescribed burning has kept the forest open and airy with mostly palmetto and pine. This is a woodsy trail, not a beachy trail! Traffic is very light on Surf road, and you will be there before you know it. I encountered no other pedestrians, and very few cars. There is one spot where you have to cross a short bridge while joining traffic, and you have to cross Surf Rd. twice (I think). I highly recommend this trail and will ride it again. Watch for bears!
We loved this trail. We rode it mid-day in July and were able to keep a decent pace because of the abundance of shade. Bring your drinks and snacks because there aren't stores on the first 10 miles. We will be back to ride the whole trail when time permits.
This trail has jumped to the top of my list of favorite bike trails!
Perhaps it was the peaceful rolling thru the wildlife refuge or crossing the many boardwalk bridges. Once I was lulled into the gentle woodland sounds I was then awakened by the delightful squeals of gulls and water fowl over the bay that has suddenly come into view.
Kept on rolling and came upon quiet sugar sand beaches.
There are wonderful Sea Food restaurants within a stones throw from this path.
I have already made plans to go back next year!
all cleared w/i 48 hours of major storm debris. we see the same folks often. 32 miles from Woodville head to St Marks r/t.
Thick forest shades virtually all 20 miles, making a cool green tunnel from Gamble & Stearns Streets in Tallahassee to a waterfront park in St. Marks. The trail is wide and smooth, with occasional restrooms and benches along the rural stretches. No parking lot at Gamble & Stearns, but plenty of room for unloading beside the adjacent street. The trail follows a former rail line that carried cotton bales to the docks at St. Marks for export. Near the southern terminus, ruins of Spanish masonry lie beside traces of Confederate earthworks at the San Marcos de Apalache historic park.
If you find yourself on bike-laned Crawfordville Road, you probably missed the sharp jog to the northeast on the south side of Ridge Road. Here the trail follows Ridge Road/Gaile Avenue for a block before continuing south-southeast along Woodville Highway. There's no signage to mark the jog, at least when going south.
I started the trail from the St. Marks end, because there doesn't seem to be very good parking at the Tallahassee end. St Marks is a bit of a resort town, and there are lots of bars and restaurants to cool off at after the trip.
There are covered rest benches every few miles, and quite a few bathroom and water stops as well. If you want to skate, you're probably most interested in the surface. It was very smooth and well maintained. Additionally, where the trail crosses a dirt road, the dirt road is paved back several feet on either side to keep vehicles from tracking dirt and gravel onto the trail.
All the crossings are well marked, and most of them are back roads, or private roads. There are a couple of big streets to cross, but the traffic is not bad, and crossing is easy.
Some highlights here:
TrailLink is a free service provided by Rails-to-Trails Conservancy (a non-profit) and we need your support!

domain: geography


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GRAMMY®-nominated multiplatinum powerhouse trio Jonas Brothers released their highly anticipated fifth full-length album Happiness Begins on June 7 after a six-year hiatus. The album features the band’s history-making comeback single “Sucker.”
DJ Snake, J Balvin & Tyga
DJ Snake, J Balvin, and Tyga have shared an irresistible new summer anthem called “Loco Contigo.” With its otherworldly beats and undeniable melodies, “Loco Contigo” finds DJ Snake and his collaborators redefining Latin music for today’s pop landscape.
As an aspiring songwriter, Dean Lewis released his last album A Place We Knew in March. For a self-styled perfectionist, who in addition to writing every song on the album also played piano and acoustic/electric guitar, perhaps one of the most remarkable things about the album is that Lewis is at peace with his creation.

domain: entertainment


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City council candidates discuss important issues ahead of election
As it did for so many governing body across the country, the COVID-19 pandemic changed almost everything for the Grand Marais City Council in 2020. Priorities were shifted, plans were modified and even the frequency and format of when the city council met and made decisions changed this year.
Many critical issues remain inside the city limits of Grand Marais, including a lack of affordable housing, a general shortage in the housing stock, employee shortages for local businesses and other timely and important issues.
At the end of the election filing period for Grand Marais on Tuesday, August 11, there were four candidates vying for two seats on the city council. They are incumbent Craig Schulte, Michael Garry, Diane Greeley and Mike Smieja. The top two vote getters take the council seats.
During a candidate forum that aired live Oct. 13, WTIP’s Joe Friedrichs spoke with all four of the candidates to hear their stance and thoughts on important issues facing the community. The audio below is the complete program as it originally aired on WTIP.
Topics discussed include the role political parties play in local government, how to make Grand Marais a more affordable place to live, a workforce shortage for local businesses and how to diversify the local economy.

domain: economics


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Due to the massive changes in the Tax Cuts and Jobs Act (TCJA), the 2019 filing season resulted in surprises. Some filers who have gotten a refund in past years wound up owing money. The IRS reports that the number of refunds paid this year is down from last year — and the average refund is lower. Read More
In most cases, refunds are routinely sent to taxpayers within a few weeks. However, there may be delays, or, in worst-case scenarios, refunds may be applied to debts owed to the federal or state governments. Read More
Will you be age 50 or older on December 31? Are you still working? Are you already contributing to your 401(k) plan or Savings Incentive Match Plan for Employees (SIMPLE) up to the regular annual limit? Then you may want to make “catch-up” contributions by the end of the year. Increasing your retirement plan contributions can be particularly advantageous if your itemized deductions for 2018 will be smaller than in the past because of changes under the Tax Cuts and Jobs Act (TCJA).
If you’re an executive or other key employee, your employer may offer you a nonqualified deferred compensation (NQDC) plan, which pays you in the future for services currently performed and allows deferral of income tax. But NQDC plans must meet many requirements. One is that, if you wish to defer part of your 2019 compensation, you generally must make the election by the end of 2018. Questions? Contact us. We can answer them and help you determine what, if any, steps you need to take before year end to defer taxes and avoid interest and penalties... Read More
For investors, fall is a good time to review year-to-date gains and losses. Not only can it help you assess your financial health, but it also can help you determine whether to buy or sell investments before year end to save taxes. This year, you also need to keep in mind the impact of the Tax Cuts and Jobs Act (TCJA). While the TCJA didn’t change long-term capital gains rates, it did change the tax brackets for long-term capital gains and qualified dividends... Read More

domain: finance


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One of the oldest board games and the popular online free multiplayer game backgammon is now available with unique features and endless fun.
Download Next Backgammon now, and play backgammon with your friends or with any online player around the world.
The best backgammon game on your computer.
NextBackgammon offers you the best backgammon gaming experience with unique features:
- PLAY AGAINST YOUR FRIENDS
Your Facebook friends waiting for you to play backgammon. Also you can always play with any backgammon player at your level from all around the world.
- ONE TAP PLAY
Tap one button and voila! Start to play backgammon in easiest and most quickest way.
- DON’T NEED TO STOP YOUR MUSIC
Enjoy your own music while playing Next Backgammon. You don’t need to stop it or listen game musics.
- DON’T LOSE GAMES BECAUSE OF BAD CONNECTION
If you get disconnected, just reconnect and continue to play your backgammon match from where you left.
- NICE DESIGN
Next Backgammon has a very nice designed interface to make your game more enjoyable.
- BACKGAMMON GURU :
Increase your experience level, challenge your friend to climb the leaderboards! Show your skills and become a backgammon guru.
- ENJOY ROLLING DICES
Enjoy dice rolling experience just as real life.
- DAILY BONUS
Roll the dice, collect free bonuses every day.
Tavla, tavle, tawla, tavli, tapa, tawula, gammon, shesh besh, mahsuba, narde, tapa, acey deucy, gul bara, portes, plakoto, fevga, tavëll, trik-trak, gioul, moultezim whatever you call it, just download NEXT BACKGAMMON and enjoy the game.
Please contact us via our facebook page:
important : Facebook account is required to play.

domain: game


That said, we're not dealing with green "boots"...these are now hardened combat vets who have seen active conflict for over a year (since late 1998). They understand their supply problem, and they are not going to be operating under the impression that unlimited ammunition is available. Trigger discipline will be higher...
...except that the system doesn't allow for it.
Using one ammo die is
trigger discipline. Soldiers are not trained to take a single shot and then wait. They are trained to shoot at the target until it goes down: double-tap - pause - double tap - pause - etc. If you have a ten-second combat round you will
be firing more than one shot.
Now might be a good time to point out that a player using one ammo die is actually using less
ammo than a player firing one "shot" per round in 1E. Firing one shot per combat round in 1E expends 3 rounds of ammunition for each 5-second combat round. A player using one ammo die in this system expends a maximum of 6 rounds of ammunition in one ten-second combat round. So most of the time, you are actually using less
ammunition per unit time in this system.
What people are complaining about, profligate ammo use and a lack of trigger discipline, is actually a complaint about the loss of control over exactly how much ammunition is expended. You are rolling not only to hit but also for how much ammo was consumed achieving that hit. This offends people because standard RPG mechanics have a certain roll to hit, which is a function of character skill, and therefore the amount of ammo consumed per hit is also a function of skill. When you achieve a hit, your character magically knows this to be so and stops firing, so you have efficient use of ammo.
But in the real world, you may hit without knowing you have hit, and fire again. You may mentally commit to a shot that's unnecessary and take the shot even as the target is falling. You may fire at a falling person thinking he is diving for cover. You don't have efficient use of ammunition. You don't commit to firing exactly three shots; you commit to a rate of fire. So in a sense, the ammo dice concept in some ways may more accurately model ammo expenditure.
The idea of firing exactly three shots is game thinking, not real-world thinking: an attempt to balance resource expenditure with goals within a system of precisely delineated probabilities. The complaint about ammo dice, stripped to its core, is a complaint that the system has randomized that expenditure and robbed the player of that control and precision.
This system has a lot going for it. Suppression works very well. It models suppressive fire in a way that supports fire and movement, which other games do not. It is quick and simple. Certainly, it has flaws: mishaps are too common and serious, to choose the most obvious example. But the rate of ammo expenditure really is not one of those flaws.


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Chennai, earlier known as Madras, is the capital of the South Indian State, ‘Tamilnadu’. The house of temples, churches and museums is the biggest southern Indian city. This coastal city has rich heritage, culture, and tradition to make the place in your heart. Chennai represents itself as the safest and healthiest city in India. The cuisine culture of Chennai ranges more from just Soft Idli to mouth-watering Uttapam.
Chennai has an exotic taste and variety in it. Whenever people go to Chennai or cross the Chennai Central Railway Station, they love to eat the yum of the city. People can even get these delicious meals on wheels. If you are on a trip and travelling by train and your tummy is asking to fill it with some local dishes, order the South Indian food on the train using the RailRestro food delivery app.
Yummy Food to Order at Chennai Central Railway Station
Chennai food is best described as mild-spicy, lightweight, and varieties of vegetarian and non-vegetarian but best in taste. South Indian Culinary is famous for its aromatic flavour and lip-smacking food.
Here are some popular South Indian foods you should try at the Chennai Railway Station.
1. Dosa; Traditional and Full of Varieties
Dosa is a popular and traditional dish made using a fermented batter of rice and urad dal. This dish comes in varieties like Plain Dosa, Masala Dosa, Rava Dosa, Mysore Masala Dosa, Set Dosa, Benny Dosa, etc. At Chennai Central Station, you can taste the amazing & crispy dosa with sambar and coconut chutney. Today, you can even enjoy non-veg dosas such as egg dosa and chicken dosa. You can order these delicious dosa meals on wheels during your travel journey.
2. Chicken Chettinad; Loaded with Local Spices
Most foods of Tamil Nadu follow vegetarianism, but the yummiest Chicken Chettinad is an exception. Some of the Chettinad are Mushroom Chettinad, Masala Chettinad, Fish Chettinad, etc. It uses loads of local spices such as stone flowers and Maratty Muku, cumin, bay leaf, turmeric, clove, tamarind, and fenugreek. But the secret of its spiciness is not chilli or chilli powder; it is because of the use of pepper. It will double your train journey excitement.
3. Idiyappam; South Indian Noodles
We all love noodles; their shape, texture and aroma excite us but have you ever tried this South Indian noodle called Idiyappam? Idiyappam is made with rice flour and prepared with the same process as noodles. Although, it’s served differently. You can order this Idiyappam for your breakfast or dinner and get it served with some coconut chutney and vegetable curry. You can also order Idiyappam with fish curry or egg curry. The exotic taste of this noodle is addictive. Try it once, and you will crave another treat on the wheels.
4. Kothu Parotta ; Similar to Lachha Paratha
Lachha Paratha is one of the top main course menus of north Indian restaurants. You must have tried this once. But have you ever imagined having something similar to this in south India? Kothu Parotta looks like Lachha Paratha and tastes amazing. It is another non-veg food you can enjoy at Chennai station. Parotta is made using flour, vegetables, eggs, or meat. It is a popular street food of Tamilnadu which you can enjoy on the train.
5. Mysore Pak; Popular Dessert of South India
We Indians love sweets at the end of our meal. Then why compromise this on the wheels? After having South Indian food on train, satiate your taste buds with a juicy Mysore Pak. This dessert originated in Mysore, Karnataka, but you can get it at Chennai Railway Station Junction. This traditional Indian sweet is made using only three ingredients; Sugar, Bengal gram, and Desi ghee. The soft and super delicious dessert will melt in your mouth and sweeten your train journey.
It is not the end of the list of tasty foods at Chennai Railway Station. The city plates various food items in front of foodies like Thukpa, Atho, Athouk, Puttu, Sundal, Murukku sandwiches, etc. You can explore the amazing taste of these dishes and give yourself a wonderful travel experience.
What is the famous food of Chennai?
The famous food of Chennai is Dosa. It is the typical South Indian food and is eaten worldwide. The dish is stuffed with Potato Masala and served with Sambar, chutney, and varieties of curry. At Chennai Junction, you can order Dosa from RailRestro e-catering.
How to make Tamil Nadu Tour a Delicious Affair?
Foods will make your trip to Tamil Nadu a delicious affair. You can explore awesome places of this Southern Indian State with regional delicacies on the go. Whether it is a traditional Uttapam, Coconut chutney, Idli and Sambar, or Murukku, you will love to mesmerise their delicious taste. These recipes have cultural, traditional, and community influences, and people travel far and wide to captivate their tastes.
Do I need to take a break to enjoy food at Chennai Railway Station?
Of Course Not! You need not to worry about meals on wheels in this technological era. You can order food on train just using your mobile phone. Download the RailRestro food delivery app or visit its website. Enter your 10 digit PNR number and browse your preferred food from the menu list of restaurants in Chennai. Place the order and choose a payment method from cash on delivery or online payment. Relax and wait patiently till your train reaches Chennai station and get your food delivered to your seat. Enjoy your train journey with the lovable South Indian cuisine on the train.
Regional dishes boast unique ingredients, textures and tastes. Staple foods are the most preferred: whether it is a light breakfast, full lunch, or a lavish dinner. Exploring India through Indian Railways offers splendid glimpses of the country’s culture and food. Why not find some great food on train and create a memorable story of your journey, which you can share.
E-catering services of Indian Railways offer you the opportunity to delight your taste buds with authentic local foods.
RailRestro e-catering is an online food delivery app on trains. It provides varieties of cuisines on the train, including south Indian food, North Indian food, Jain food, Punjabi food, and regional food. You can order your favourite restaurant-style hygienic and delicious meals on wheels during your train journey across India.
Food does not only fill our tummy, but it is also a way to explore the rich culture and heritage of the state and city. Eateries of any place state the story of the tradition and culture of that particular place. If you are travelling by train, why leave this beautiful opportunity to taste the city’s charm.
These are the five best foods that you can order at Chennai Station. With the Railrestro app, order delicious meals on wheels and make your happy journey the happiest!

domain: food


- Lotus and Britishvolt sign MoU to collaborate on advanced EV technology
- Partnership to co-develop innovative EV package to power new generation EV sports car
- Design sketch provides first clues to new Lotus EV sports car
Hethel, UK – 28 January 2022
Lotus and battery cell expert Britishvolt have signed an MoU to collaborate on the research and development of advanced new EV technology.
The partnership will focus on the co-development of an innovative new battery cell package to power the next generation of electric sports cars from Lotus. The package is set to feature in a new sports car, powered by Britishvolt cells and utilising advanced electric propulsion technologies developed by Lotus. An official design sketch provides the first clues to a new Lotus EV sports car.
Britishvolt is the UK’s foremost investor in battery cell technologies and associated R&D to create homegrown intellectual property. Key focuses of the partnership will be fast-charging, optimising energy density and weight reduction.
Development work on the project will benefit from the close proximity of Lotus and Britishvolt’s R&D centres of excellence in the West Midlands, the UK’s ‘golden triangle’ of battery excellence. The Lotus Advanced Technology Centre (LATC) opened in Wellesbourne in 2020 as the global headquarters of Lotus Engineering, the consultancy division of the business.
The collaboration with Britishvolt is another significant development in the ongoing transformation of Lotus, from a UK sports car company to a global and all-electric performance car business and brand. It follows a £100m investment by Lotus in its UK facilities, which includes manufacturing centres at Hethel for the Evija pure electric hypercar and Emira sports car – future-proofing the world-renowned and innovative UK high-performance auto sector and the thousands of jobs that it supports.
Matt Windle, Managing Director, Lotus Cars, commented: “Lotus is delighted to be collaborating with Britishvolt to develop new battery cell technology to showcase the thrilling performance that a Lotus EV sports car can deliver. These are the first exciting steps on the journey towards an all-new electric sports car from Lotus, and yet another step towards the transformation towards sustainable, renewable electricity stored in batteries.”
He added: “Last year we committed Lotus to a pure electric future, and in the first month of this year we announce another significant step on that journey. In the coming months we will be unveiling the Type 132, an all-new and all-electric Lotus SUV and we’ve confirmed three more EVs are on the way.”
All future Lotus cars will be pure electric and inspired by the Evija, deliveries of which commence this year as the world’s first British electric hypercar.
Britishvolt is on target to responsibly manufacture some of the world’s most sustainable, low carbon battery cells on the site of the former Blyth Power Station coal stocking yard located in Cambois, Northumberland.
The development is a major boost for Northumberland, and indeed the country, and will bring around 3,000 direct highly-skilled jobs and another 5,000+ in the associated supply chains.
Advanced works started on the site on September 6, 2021, following a unanimous planning decision approval earlier in the year. The project will be built in phases, to keep up with technology advancements, and will have a total capacity of over 30GWh by the end of the decade onwards.
Notes to Editors
For more information, please contact the Lotus Communications team:
|James Andrew | Executive Director, PR and Communications
+44 (0) 7384 830903
|Rob Borrett | Manager, PR Content and Launch Programmes
+44 (0) 7718 560789
|Alastair Florance | Group PR Manager
+44 (0) 7802 918662
|Richard Yarrow | PR Manager, News and Technology
+44 (0) 7471 994525
|Samantha Thomas | PR Officer, Product Press and Digital Media
+44 (0) 7909 813785
The Lotus Media Site – contains news, images, specifications and full details of current models, as well as heritage cars and engineering technology.
For the latest news and information from the Lotus PR Team please follow:
Lotus PR Team | Twitter
Lotus PR Team | Instagram
|For Lotus Cars social media please follow:
Lotus Cars is based in Hethel, Norfolk, UK, and is the global HQ for sports car and hypercar manufacturing operations, the Lotus Advanced Performance Centre and the iconic 2.2-mile test track. Lotus Cars builds world-class high-performance cars, born out of legendary success on the racetrack including 13 FIA Formula 1 world titles and many other championship honours. In July 2021 Lotus unveiled the all-new Lotus Emira, its last petrol-powered sports car and best-of-breed, and in July 2019 it launched the Evija, the world’s first all-electric British hypercar. Customer deliveries of both cars will begin during 2022.
Britishvolt is Britain’s foremost investor in battery cell technologies and research and development. It is dedicated to developing the future of electrified transportation and sustainable energy storage, producing best-in-class, low-carbon, sustainable, responsibly manufactured lithium-ion battery technologies.
Britishvolt’s aim is to establish the UK as the leading force in battery technology, and associated ecosystem infrastructure. It is working with leading strategic partners/suppliers to achieve this, as it is of paramount importance to the future of the UK automotive industry and the overall economic and industrial health of the country. The company is built on a foundation of ESG Principles and Commitments.
Britishvolt believes that the UK is the right place for its initial investments because of the strength of its automotive and renewable energy industry alongside its expertise and history in industrial and academic battery R&D. As well as the UK Government’s foresight in creating a world-class battery ecosystem.
Quarter four 2023/early 2024 has been targeted as the start of production of Phase One of Britain’s first full-scale Gigaplant situated on the old coal stocking yard of the former Blyth Power Station in Cambois, Northumberland.


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Follow its promise “Passion for Better”, SCG has always contributed to the development of community where it operates. In recent months, the Covid-19 pandemic has impacted seriously both local economy and the lives of people across the country. Therefore, SCG and its subsidiaries have taken initiatives to support various communities during the difficult time, such as donating cash; medical equipment including medical masks, face shields, hand sanitizers, disinfectant spray; and food for medical staffs with values up to seven billion dong. … [Read more...] about SCG Three decades for quality of life in Vietnam
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"Over the past twelve years, the Asia Young Designer Awards stayed true to our commitment to innovation and sustainability. By instilling a deep sense of responsibility and accountability in these young budding designers, we believe that in time, they will contribute to social and environmental advancements in society through their professional achievements. We are proud of the network that we've built, connecting industry professionals and talented designers from across the region," said Wee Siew Kim, Group CEO of NIPSEA Management Company Pte. Ltd. (Subsidiary of Nippon Paint Holdings Co.). … [Read more...] about Nippon Paint Reveals the Winners of the Asia Young Designer Awards 2019/20
In 1999, I was one of the dozen scholars of American studies chosen to meet with a dozen Viet Nam scholars of American studies in a conference in Ha Noi. One of the sponsors of the conference was Ambassador Pete Peterson, the first US ambassador to Viet Nam. Peterson, himself a former POW, declared the whole POW/MIA issue was a “hoax". At the conference, an elderly Vietnamese professor asked us Americans if we knew who was the first Vietnamese scholar of American studies. Several of us immediately shouted out “Ho Chi Minh.". This led to a discussion of great relevance today, as we celebrate the 25th anniversary of diplomatic relations between our two nations. … [Read more...] about What does the future hold for relations between Vietnam and US?
Fourth place jointly went to Italy, Finland, Spain, and Luxembourg, followed by Denmark and Austria with 187 points. Furthermore, Sweden, France, Ireland, the Netherlands, and Portugal finished with 186 points, whilst the US, the UK, Belgium, Norway, and Switzerland recorded 185 points. In addition, the Czech Republic, Greece, Malta, and New Zealand had 184 points, Canada and Australia with 183, and Hungary with 182. … [Read more...] about Vietnam ranks 89th on most powerful passport list during COVID-19
A doctor diagnosed that she had placenta previa which occurs when a baby's placenta partially or totally covers the mother's cervix, the opening for the uterus. Doctors put her on a drip and tested her blood while they sent a Red Alert to ask for help from doctors at Hùng Vương Hospital. … [Read more...] about Doctors save pregnant woman, baby after emergency surgery


- Adds 5 rounds to the factory 19 round magazine
- Uses factory 19 round spring
- Machined from Delrin
- Easy assembly
- Overlaps the parent magazine and will not come off
The TACCOM +5 magazine extension, was design specifically to add 5 rounds to the factory RIA/Armscor 19 round magazine while still using the factory magazine spring! If you haven’t noticed by now, that spring is really tight! Installation is a breeze; you just remove the factory floor plate, and lock plate; loosen up the screws on the TACCOM extension enough to slip over the retaining lips on the parent magazine and retighten the screws and you are done! If you barney load one shell in the chamber you can start out with an entire box of ammo on your stage! The extension itself is super light, and super strong. It’s not going to come off unless you want to take it off. Your magazine and our extension will be the first magazine in your shotgun most every time!!