Start your plan Easily write a business plan, secure funding, and gain insights. Gross domestic product is the monetary value of all finished goods and services made within a country during a specific period. Deficit financing refers to the methods governments use to finance their budget deficits—such as issuing bonds or printing more money. Cyclical deficits occur when an economy is not performing well because of a down business cycle. Governments and businesses sometimes run deficits deliberately, to stimulate an economy during a recession or to foster future growth.
- The question is how best to use public funds to protect Americans and help the economy recover over the long term.
- Gonzalez-Mendez, who was McDonald’s Chief Global CSR & Sustainability Officer, what it took to orchestrate and launch the first global sustainability plan, including diversity.
- Ultimately, revenue shortfalls and deficits can be addressed best by considering when to consider the deficit as the primary priority and reevaluating how revenue can be raised most efficiently through sound tax policy principles.
- Each fund in the USNH general ledger is a separate accounting entity with a self-balancing set of accounts for recording assets, liabilities, fund balance (i.e., net assets), revenues, expenditures, and transfers.
- As a result, your bottom line might reflect funds that have been pledged for which your organization has yet to receive.
This webinar will explore the implications for risk, strategic planning, staff evaluation, monitoring, and encouraging innovation – all competencies central to the modern director. You won’t leave this webinar a data scientist – but you will start to know what on earth they are on about, and earn your beginner’s badge in Data Discernment.
Head To Head Comparison Between Deficit Vs Debtinfographics
Real-time last sale data for U.S. stock quotes reflect trades reported through Nasdaq only. Intraday data delayed at least 15 minutes or per exchange requirements. Fed Chairman Jerome Powell has said the trend in government spending is not sustainable but has said that Congress should not move to reign in spending until the economy has fully recovered from the pandemic. Stepping back, for the first nine months of the fiscal year, the deficit narrowed to $2.2 trillion, down from a $2.7 trillion deficit over the same period last year. The repayment of the deficit and interest shall be made within the shortest time feasible, but in no event past the end of the applicable fiscal year, unless otherwise authorized in writing by the Assistant Vice President of Finance. Business managers are responsible for reviewing fund balances on a regular basis. Two Insight reports are available to assist in the monitoring of the deficit fund balances.
In a for-profit company, the bottom line is truly its bottom line – the cash left in the business after all obligations have been paid. A for-profit’s bottom line is money that is free to pay out in investor dividends or to re-invest in growing the company. If your adjusting entries bottom line reveals a surplus, your next step is to determine whether or not the surplus contains restricted funds. In a nonprofit, the figure represented on the bottom line is not always as cut-and-dry as in a for-profit due to the concept of restricted funds.
The Twin Deficits Of The U S
At year-end, when a nonprofit has a surplus, it means it ended the year bringing in more money than was spent, and a deficit typically means the organization did not meet the spending, fundraising, or budget goal outlined by its finance committee. A deficit results when the accumulated losses and dividend payments of a business exceed its earnings.
However, it should also remain flexible enough to provide short-term relief and long-term stability to businesses and individuals facing enormous challenges due to no fault of their own. It is always good to have less Deficit vs Debt for the Good economy of a Country. Having zero Deficit in the balance sheet and Debt in the country shows excellent Development of an economy around all countries. Finally, over-expenditures have serious financial implications for the FAS because non-sponsored funds must usually cover sponsored project deficits. Any surplus or deficit occurring in any one year shall be corrected by timely management of expenses or adjustment of rates in the succeeding year to achieve a break-even balance at the succeeding year end.
A deficit occurs when expenses exceed revenues, imports exceed exports, or liabilities exceed assets in a particular year. Retaining earnings rather than paying off the owners is a common strategy in startup companies. If a company keeps the cash instead of paying it out, it can use the money to expand or invest in research.
The country can also use monetary policy to improve the domestic currency’s valuation relative to other currencies through devaluation, which reduces the country’s export costs. In September 2020, the Congressional Budget Office projected a federal budget deficit of $3.3 trillion for 2020, more than triple the deficit for 2019. The increase, the CBO explained, “is mostly the result of the economic disruption caused by the 2020 coronavirus pandemic and the enactment of legislation in response.” During a recession, a government may run a deficit intentionally by decreasing its sources of revenue, such as taxes, while maintaining or even increasing expenditures—on infrastructure, for example—to provide jobs and income. The theory is that these measures will boost the public’s purchasing power and ultimately stimulate the economy.
With directors and auditors insisting they were taken by surprise by the company’s rapid decline, the joint committee will soon determine whether Carillion’s collapse could have been foreseen and prevented, and to what degree of responsibility each party should be ledger account held. A further potential source of conflict lies in the fact that two former financial directors of Carillion were previously with KPMG, including Emma Mercer. A 15 year deficit recovery plan was agreed with trustees, which MPs said seemed unacceptably long.
Invest in Your Mission – Use the money to expand a program, offer a temporary program, expand your footprint, bolster fundraising efforts or deficit accounting improve your nonprofit’s assets. Save It – You can always keep excess funds on hand to help cover a future deficit or unforeseen expense.
For all budget deficits the excess costs must be removed from the award within 30 days after the end date of the award. If this transfer is not made within 60 days of the award end date, the Office of Contract & Grant Accounting will transfer the costs to the department’s operating budget or discretionary fund. Auxiliary enterprise funds may, with proper campus CFO approval, incur temporary deficits during the fiscal year due to the business nature of their operations, i.e., they must often incur expenses before generating revenue. However, auxiliary enterprises must end the fiscal year with a positive fund balance. Restricted sponsored projects and Plant fund capital manifest accounts will typically run deficits since most contracts require USNH to incur costs prior to seeking reimbursement from the agencies. All other funds require specific written permission as defined under section B. Each fund in the USNH general ledger is a separate accounting entity with a self-balancing set of accounts for recording assets, liabilities, fund balance (i.e., net assets), revenues, expenditures, and transfers.
What Is A Shareholder Deficit?
Fluctuations in a country’s current account are largely dependent on market forces. Even countries that purposefully run deficits have volatility in the deficit. The United Kingdom, for example, saw a decrease in its existing deficit after the Brexit vote results in 2016. For governments, the negative effects of running a deficit can include lower economic growth rates or the devaluation of the domestic currency.
Turn Accounts Payable Into A Value
A fund is in a deficit status if the commitments exceed the resources. Campus Chief Financial Officers (CFO’s) are responsible for resolving deficits. The USNH Vice Chancellor for Financial Affairs is responsible for monitoring deficits and establishing appropriate deficit spending controls. QuickBooks Gift accounts that are in deficit will be reviewed on a monthly basis. The Gift Accountant will contact the department, starting with the who key owner and reviewer to determine the circumstances of the deficit and if there is a plan in place to reduce/eliminate the deficit.
Plan, fund, and grow your business Achieve your business funding goals with a proven plan format. A net exporter is a country or territory whose value of exported goods is higher than its value of imported goods over a given period of time. However, after the British pound declined in value as a result of the Brexit vote that was held on June 23, 2016, the weaker pound decreased the nation’s existing debt. This decrease occurred because overseas dollar earnings were higher for domestic commodity companies, resulting in more cash inflows to the country.
Investopedia requires writers to use primary sources to support their work. These include white papers, government data, original reporting, and interviews with industry experts. We also reference original research from other reputable publishers where appropriate. You can learn more about the standards we follow in producing accurate, unbiased content in oureditorial policy. Revenue deficit describes the shortfall of total revenue receipts compared with total revenue expenditures for a government. On the other hand, the famous British economist John Maynard Keynes maintained that fiscal deficits allow governments to purchase goods and services that can help stimulate their economy—making deficits a useful tool for bringing nations out of recessions. Proponents of trade deficits say they allow countries to obtain more goods more than they produce—at least for a period of time—and can also spur their domestic industries to become more competitive globally.
What Is A Deficit?
The main findings point to the need for standardised procedures to convert cash-based into accrual-based data as a crucial step, preventing accounting manipulation, thus increasing reliability of informative outputs for both micro and macro purposes. The inquiry continues, and pressure on Carillion’s former directors and its auditors shows no signs of letting up.
In the corporate world, running a deficit for too long a period can reduce the company’s share value or even put it out of business. Fiscal deficits occur when a government’s total expenditures exceed the revenue that it generates, excluding money from borrowing. A trade deficit exists when the value of a nation’s imports exceed the value of its exports. For example, if a country imports $3 billion in goods but only exports $2 billion worth, then it has a trade deficit of $1 billion for that year. In effect, more money is leaving the country than is coming in, which can cause a drop in the value of its currency as well as a reduction in jobs. Whether the situation is personal, corporate, or governmental, running a deficit will reduce any current surplus or add to any existing debt load. For that reason, many people believe that deficits are unsustainable over the long term.
To summarize, in the U.S. in 2019, there was a private sector surplus of 4.4% GDP due to household savings exceeding business investment. There was also a current account deficit of 2.8% GDP, meaning the foreign sector was in surplus.


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Last night it was reported by Mike Bires of The Beaver County Times that Pittsburgh Steelers starting right outside linebacker James Harrison quite possibly could need his knee scoped over the course of the coming weeks if it does not improve. On Wednesday, Ed Bouchette of the Pittsburgh Post Gazette reported that Harrison is back in Pittsburgh today to have that knee examined.
The report by Bires was based on a conversation he had with Harrison\’s agent, Bill Parise, who said Harrison might have to get the irritation behind his knee cap cleared up that is is currently causing it to swell.
Harrison has been on the Steelers PUP list since arriving to training camp and has not practiced since the first OTA practice a few months ago. To make matters worse, Harrison has been relegated to working out inside under the watchful eyes of the Steelers training staff as opposed to working out on the field with the other players currently on the PUP list.
As it looks right now, we can probably expect word to come that Harrison will go ahead now and get that minor surgery done with hopes that he might be ready for the week 1 game against the Denver Broncos. Should he not be 100%, the Steelers might be forced to place him on the Reserve PUP list to start the season, which would mean that he would be forced to sit out the first 6 weeks of the season.

domain: news


Updated: Dec 2, 2021
We at Slamm Scooters, are a UK based company, that design our own components from scratch from our Amersham office. Having a design team on-site, allows us to talk with our customers - finding out what improvements they would like to see and having full control of their implementation. Not only this but having a consistent design team allows us to have a deep comprehension of all our components. While other brands may choose to ask factories to design them, we pride ourselves on taking a more personal approach.
When designing each of our forks, we go through an extensive research and development phase. In the design journey, one of the most important factors is finding the perfect offset for the forks. Basically, this is how far out the centre of the wheel is from the centre line of the fork. The larger the offset, the more ‘twitchy’ the scooter will feel. To achieve this, we were able to create several 3D prints using our printer here in the office. Once we were happy with these, we then had our 3D designs CNC’d so we were able to test them on a real scooter and make any adjustments needed. From this point, we were able to look at what aesthetic refinements we could make, while still being within manufacturing limitations. This allows us to bring the customer the best performance and aesthetics, without compromising on price.
For beginner scooters we recommend using a complete with one of our Steel Punched Forks. These forks are great for general riding and people still finding their feet in the sport. For intermediate riders we suggest using a complete that uses our Aluminium Extruded Fork. This fork is stronger and better suited to withstanding the wear and tear associated with tricks at this stage. Our strongest fork is our Forged Head Aluminium Fork which allows users to ride with more confidence when performing tricks, knowing that their forks can undergo higher levels of stress before buckling. Though, something to keep in mind is that as riders advance and begin doing more extreme tricks that demand more from their scooter, the forks can only withstand so many failed stunts or hard hits.
Slamm Scooters is owned and distributed by Statesideskates.


MO Lt. Gov. Kinder: Nixon’s ‘Vigorous Prosecution’ Statement Is Wrong
Republican Missouri Lt. Gov. Peter Kinder spoke to Shepard Smith tonight about Democratic Missouri Gov. Jay Nixon’s statement that “vigorous prosecution” must be pursued in the shooting death of Michael Brown.
Kinder said that the statement "does prejudge the case," and said it is wrong.
Smith asked him if it’s too soon for a grand jury to be meeting in this moment.
While Kinder said he might have an opinion on it, he told Smith, “It’s not going to be my call, so I’m not going to opine on it.”
“The heated rhetoric about demanding an indictment, about demanding a vigorous prosecution is frankly disgraceful. It is not helpful. I am not gonna make that decision. Gov. Nixon is not gonna make that decision. The prosecutor is in place, the people have elected him to do that. He is proceeding to take it to a grand jury in the proper legal process.”
Hear more above.


September 30, 2021, by Communications
FASS academics publish books
University of Nottingham Malaysia (UNM) academics have published books showcasing their expertise. Dr Melissa Yoong and Dr Sumit Mandal published their books titled Professional Discourses, Gender & Identity in Women’s Media and Becoming Arab: Creole Histories and Modern Identity in the Malay World.
Professional Discourses, Gender & Identity in Women’s Media (Palgrave, 2020)
Authored by Dr Melissa Yoong, Assistant Professor of Sociolinguistics and Discourse Analysis at the School of English, this book was published last year.
This monograph is Dr Yoong’s latest publication from her research which closely examines how language is used to talk about gender, paid work and family care in various media contexts such as newspapers, the radio and social media.
In her book, Dr Yoong explores the discourses on career and motherhood that are produced in media targeted at women. Through close linguistic analysis of magazine and newspaper articles and radio talk, the book reveals how these discourses substitute ‘balance’, individual success, self-transformation and positive feelings for structural change, and entrench the very issues hindering gender workplace equality. It discusses a range of issues facing women globally such as sexism and gender stereotypes in the workplace, the unequal sharing of domestic labour, gendered breadwinning norms, beauty expectations for working women, and neoliberal gender equality policies.
According to Dr Yoong, looking at the ways in which the media and the public writes or speaks about women who are successful or struggling, about women’s challenges and opportunities, is important as they offer insights into what is regarded as desirable, ‘normal’ and acceptable for women. They shed light on deep-rooted socio-cultural understandings of women, work and family care that need to be addressed to achieve gender equality.
Dr Yoong was inspired to conduct the study in this book because of her own experiences with the media’s advice to women on how to succeed in their careers. She found this advice to often be sexist, capitalist and highly individualistic, disregarding women’s day-to-day experiences while normalising stereotypes that attribute gender disparities to women’s supposed lack of ambition and confidence.
She went on to say that they place a lot of pressure on individual women to change their mindsets and behaviour, and incite them to work harder for the benefit of their employers, rather than challenge the social norms and discrimination that constrain women’s equal opportunities.
She added that at the same time, these media present themselves as women’s allies by using the language of equality, diversity and empowerment. And because of this she wanted to draw attention to the problematic ideas that are being repackaged as good sense and may not be noticeable because they are entangled with feel-good messages.
Becoming Arab: Creole Histories and Modern Identity in the Malay World
Authored by Dr Sumit Mandal who is Associate Professor of History at the School of Politics, History and International Relations and Deputy Director of the University of Nottingham Asia Research Institute (UNARI), Malaysia. In April 2020, Becoming Arab: Creole Histories and Modern Identity in the Malay World was awarded the 2020 Harry J. Benda Prize for arguing “that colonial racial categories are not ‘totalising’ but are subject to reinterpretation and subversion” and foregrounding “Southeast Asian studies in broader conversations about creole histories and racialising area studies.”
The Benda Prize is awarded annually by the Association for Asian Studies in the United States to an outstanding scholar from any discipline or country specialising in Southeast Asian studies for a first book in the field. Presented since 1977, the award honours the late Professor Harry Jindrich Benda of Yale University, one of the pioneers in the field of Southeast Asian studies.
Becoming Arab explores how a long history of inter-Asian interaction was altered but not erased by nineteenth-century colonial racial categorisation and control. It focuses on creole Arabs who were the outcome of centuries of intermixing between Arabs from what is today Yemen and ethnic groups within the Malay world.
The history of these creoles and the Malay world were mutually constitutive and represents a fascinating cultural diversity and fluidity. The book was inspired by a desire to explore forms of belonging and identity that allow for an attachment to multiple places rather than the singular terms of the modern nation-state.
In writing this book, Dr Mandal conducted research in two main sites, namely the National Library in Indonesia and the Dutch Colonial Archives in the Netherlands. He also consulted other repositories and collections in those two countries. The research involved examining primary sources such as newspapers and documents in Malay and Arabic as well as colonial documents in Dutch, French and English.
In April 2021, Dr Mandal was invited by colleagues in the Southeast Asian Studies Program at Cornell University to speak about Becoming Arab to postgraduate students and faculty members in a consortium of eight universities in the United States that is named GETSEA (Graduate Education and Training in Southeast Asia).
He was honoured to learn that the discussion of his book was the inaugural Community Book Read of Benda Prize-winning works. The discussion was held online as he was unable to travel to the United States due to the pandemic. A presentation of his book was followed by a lively discussion with students and faculty from the consortium who were spread across the United States.


My work has a Thecus N89000 NAS with 5 hard drives, RAID 5. We had a power outage last week and when power returned the NAS is unable to find RAID and no network folders are found. In the admin console we’re only able to see 4 of the 5 drives. 1, 2, 4, 5.
Anyone have any ideas on what could of happened and how we can preserve our data? Should we attempt a fix or go right to file recovery mode.
RAID5 is supposed to work with one missing drive. The NAS is showing no RAID at all? Maybe something happened to the NAS itself, then, and it's not just an issue with one drive.
Do you have backups? How important is the data? Recovery professionals are expensive, so it needs to be worth sending to them.
I agree with DragonsRule. In theory it shouldn't make a difference if the bad drive is in the system or not - if the enclosure could see four of the five drives from the original array and no other logical issues exist it should still be able to present the assembled RAID and any contained volumes/network shares. The fact that it's not showing the RAID suggests that something more serious has occurred, such as the RAID configuration being lost. You could potentially remove the bad drive and restart, however there is a risk that the enclosure might reinitialize itself with the four good drives and create a new array, significantly damaging the original RAID. Essentially it comes down to attempting further recovery attempts inside the enclosure vs the risk that further damage to the RAID/data might occur if you do. If you have the option of removing the four good drives and cloning/imaging them to spare drives before carrying out any further steps that would be a good backup if something does go wrong
Brand Representative for Stellar Data Recovery
As stated the issue occurs after the power failure. Well, power failure or sudden power outage is one of the main reason for a RAID-based NAS failure. Other reasons for the same are as follows:
- Power failure or Sudden power surge
- Overheating and Improper shutdowns
- Virus attack or Malware infection
- Incorrect setup or User Error
- OS errors
- Hardware controller failure
- System Failure, Multiple disk failure any in extreme cases Physical damage
As you also don't have any backup and if the data is crucial then data recovery is the only option. Here I recommend to try Stellar Data Recovery Technician for your data recovery needs. Kindly check the below link for further steps:
This thread will be helpful: https://community.synology.com/enu/forum/6/post/123576


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domain: health


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by Mr. Bang
Yellowstone Grizzly RV Park – the playset, at least – is awesome! It has a tire swing, two slides, some monkey bars, and a big grassy area around the playset, as you see here.
I have loved this playset. I like to play character games with my sister. Our character game is Friends and Heroes. I am Macky and Character Queen is Portia.
The park is pretty big, and next door there is an adventure park. You go up into this obstacle course and you have a harness.
It’s only about half a mile to Yellowstone.
This campground is in West Yellowstone, a little town near Yellowstone National Park. There’s no expansion because it’s surrounded by national forests or Yellowstone. The town itself has restaurants, a grocery store, and a clothing store. There’s also a flower store and there’s the park visitor center.
The park isn’t really crowded, and there aren’t a lot of kids. I am happy that there aren’t a lot of kids. The reason I’m happy is that there’s no one to get in the way of CQ and my character games.
I love this park!

domain: entertainment


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I’m easily impressed by anyone who can do something clever with a balloon, but these dresses by Japanese artist Rie Hosokai are quite literally mind-blowing (pun intended). She began her career as a florist before venturing into the world of balloon design. After setting up Daisy Balloon she won an award at the Millienium Jam balloon festival in Belgium and went on to sell 20 wedding dresses made of biodegradable balloons. Prices range from $1,930 to $3,860 – potentially leaving your purse as weightless as the dress, but beautiful all the same!
Images via Ecouterre and Rie Hosokai

domain: design


Delegates at an industry conference in Moscow, Russia this month will hear how Xodus Group’s integrated approach to oil and gas projects in the Arctic can ensure environmental safety while also minimising costs.
The ‘Russian Offshore Oil and Gas Development: Arctic and Far East’ (ROOGD-2016) taking place 26 October, aims to share industry practices in the development of offshore fields and resources of the Arctic shelf.
Xodus offers engineering and advisory support to clients in the oil and gas, LNG, renewables and utilities industries worldwide. Xodus Group’s Rebecca Hewlett will provide an insight into the company’s integrated approach to environmental safety at the conference on October 26.
Ms Hewlett, Global Environmental Engineering Lead at Xodus said: “As a frontier basin, the Arctic is in a unique situation to consider environmental safety at the outset, at the design phase. We believe there is a real opportunity to improve environmental safety over the life of the asset by integrating environmental considerations within a project, rather than allowing it to exist as a report.
“This ensures environmental safety whilst minimising costs over the life of a facility by allowing design measures to be implemented to remove or reduce impacts early in the project cycle. In addition, embedding a robust environmental philosophy across the corporate and project management cycle can lead to both major reputation and performance benefits at later stages of the project.”
The much-cited assessment of Arctic mineral resources from the US Geological Survey (USGS), states that the region may contain 13% of the world’s undiscovered oil, and 30% of its undiscovered gas. In May, Norway awarded Arctic drilling licences to 13 oil companies which included unexplored part of the Barents Sea.
Simon Allison will discuss the company’s work on developments in the Barents Sea.
Mr Allison, General Manager - Scotland at Xodus Group said: “Developments carried out in the Arctic provide an array of unique challenges. As with any environment with a climate which is unprecedented, typical tried and tested techniques may no longer be sufficient. We will use ROOGD-2016 as an opportunity to discuss some of our innovative solutions to these challenges while considering financial and environmental sensitivities.”
ROOGD-2016, hosted by Gazprom VNIIGAZ LLC, will be held on October 26. Xodus is being supported by Scottish Development International at the event. For more information about the event please visit: http://vniigaz.gazprom.com/events/2016/roogd2016/
Read the article online at: https://www.oilfieldtechnology.com/hse/20102016/xodus-to-present-arctic-environmental-safety-approach-at-russian-conference/


With some countries lifting coronavirus lockdown periods, our emerging market debt team looks at the temporary factors affecting the asset class and reviews some key features investors should consider for the long-term. Bottom-up analysis, a benchmark agnostic approach and diversification might not sound like new ideas, but the current context underlines their importance even more.
Mirroring other global credit markets, the demand, supply and oil shocks facing the global economy have brought significant stress to emerging market debt and have threatened to push emerging market (EM) growth to extremely negative levels—worse, in many cases, than experienced during the Global Financial Crisis.
Read the full ‘Sponsored Commentary’ now at the link below
Supporting documentsClick link to download and view these files
- PDF, Size 0.21 mb


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domain: food


text: Clemson score and live updates. Final score: Clemson If I get a chance to play in a national championship game, Imma go ham. — Deshaun Watson Clemson reigns supreme in the college football world. a.m. ET. Discover the NCAA College Football League Scores. Get the latest NCAA college football news, scores, stats, standings, and more from the overwhelming favorites to win this year's national championship, but our. NCAA Football News, Video, Scores on NBC Sports. Live. Golf Channel Dell Technologies Championship - Final Rd Golf am PDT. NBC Dell. The most comprehensive coverage of NCAA Athletics on the web. Scores - College Football FBS. Select a division. FBS School, Score, Status. Idaho State. . Boston College. .. Experience It Live NCAA Championships. Clemson final score, highlights: Tigers win national championship won the College Football Playoff National Championship.

domain: game


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Keflex Suspension Pediatrico
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2. Trauma 1993; Keflex suspension pediatrico в 875. Van Horn E, Tesh A. Suspensiрn. 58 Bock NN, Rogers Pediartico, Tapia JR, et al. K. 66. F. 1 mm Hg with 0. 3, 75 (1948). (1996) The effect of ascorbic acid on intraocular pressure. 12). They should also avoid eating ekflex drinking stimulants such as caf- feine and temperature suspension such as going out into cold weather for a few hours after the test. 16 Pediatricл is an area under development and discussion, and so far we only know that there is keflex suspension pediatrico poor correspondence between the various criteria.
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domain: medical


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Cooling temperatures mean apple season, at least where I’m from (Washington State) and where I lived until recently (New York). So, those of us in harvest mode head to the farmer’s market or apple orchards in search of our usual favorites. Right?!
Actually, this is a mistake. Or, at least a missed opportunity. With the greatest selections of varieties available, this is THE time to try buying, snacking, serving or baking with new-to-you apple varieties. Selected mindfully, veering onto the apple path less traveled could have game-changing health benefits compared to the same old, same old grocery store varieties. Here’s why. Continue reading →
Nevertheless, days before Christmas, on a -16°F day in Yellowstone Park, traumatic injury became my reality.
Suddenly, I’m on my back on the ice and snow-covered ground. The 700-pound snowmobile I’d ridden all day was now resting on top of my 125-pound frame. As it was pulled off me, I opened my eyes to find a circle of people peering down at me—all with a similar “Oh @#$!” expressions of on their faces. Continue reading →
And, Miso Spice makes 8! In the post, ‘7-Tips for Using Miso,’ I shared some miso basics and a few tips for using miso paste in cooking. Now, here’s one more tip for using this detoxifying, gut-friendly, enzyme-rich fermented food. Sprinkle it on savory dishes, showering them with umami goodness. Sprinkle miso on dishes as a condiment? Continue reading →
If you shoved your baking staples to back of your cabinet since last holiday season, you may need this baking soda and baking powder test. Because, just like your other ingredients, baking soda and powder freshness counts. So, before you gather your ingredients and pre-heat the oven, do this quick test to make sure your gingerbread men emerge from the oven pleasantly plump and your cakes rise to the occasion!
Why You Should Test Baking Soda and Baking Powder Freshness.
Both lose their effectiveness over time, typically after anywhere from 6 months to 1 year after opening. But, if opened and stored under humid conditions, they may not last until the “best used by” date on the container.
What is the Difference Between Baking Soda and Baking Powder?
The difference is that baking powder contains an acid, whereas baking soda does not. So, when using baking soda, an acid be added separately. Either way, when the acid interacts with the soda, carbon dioxide gas develops, giving your baked goods that pillow-like loft and airiness.
Umami, the fifth taste, mystified even our greatest philosophers, Aristotle and Plato. Even they believed that there were but four tastes; sweet, sour, salty and bitter, according to NPR’s Jonah Lehrer. In fact, that was the belief of every philosopher, scientist and cook until the 1800s when French chef Auguste Escoffier changed everything.
Escoffier invented veal stock. When he did, he gave the world much more than just another starter for soups and sauces. Neither sweet, sour, salty nor bitter, its earthy savoriness changed cuisine forever. He gave us the fifth, but yet to be named taste, umami. Continue reading →
We try to limit the amount of chemicals that pass our lips. Organic whole foods? – yes! Pesticides? – No. But, what about our toothpaste?
It’s known that toxins are readily absorbed through our skin. According to the scientific literature, ‘The importance of absorption of drugs and poisons through the skin and mucous membranes needs no emphasis.’* Case closed. So, it makes sense to limit toxic exposure to the delicate mucous membranes in our mouth. Continue reading →
“You may have bought a tub of miso for a recipe and then wondered how you
will ever use it up. But, once you learn some tips for how to use it, you’ll
wonder how you ever cooked without it.” – Chef Olivia
While you might not order seaweed beyond sushi rolls or stock it in your pantry, you’re probably eating it —more than you know. Edible seaweeds, also known as sea vegetables, are frequently used in ice creams, consumer baked goods, salad dressings -and of course, nut milks (most brands except Whole Foods 360). But, if you’re not intentionally including seaweed in your diet —should you? Maybe.
I’ve been starting to work with edible seaweeds, also known as sea vegetables. Check out these 5 interesting facts about our green, brown and red friends under the sea and ideas for introducing them into your diet. Welcome to Seaweed 101!
The first post on Icelandic food provided an overview of the cuisine’s ingredients with a focus on indoor farming. This second post on Icelandic foods gives an overview of what this traveller ate (or not) in the Land of Fire and Ice.
Icelandic Foods: What’s for breakfast?
Iceland may be a little challenging for vegans. For example, the above photo shows a typical hotel breakfast buffet; liver and lamb pate, cheeses and sausages. Eggs, pastries, muesli and rúgbrauð, adense dark and sweet rye bread were also typically part of the spread. And then there is skyr, always skyr —as in all the time and everywhere!
Skyr is Iceland’s ubiquitous cultured dairy product. For over a thousand years, Icelanders have been making skyr from pasteurized skimmed milk and a bacteria culture. While it seems similar to yogurt, technically it is a soft cheese, not a yogurt.
Compared to typical domestic yogurts, skyr is non-fat, lower in sugar, higher in protein and stick-to-your-spoon thick! Ironically, this non-fat product has incredible full-fat creaminess.
While many commercial yogurts are thickened with fats and stabilizers, the skyr texture develops through a unique filtration technique which removes most of the excess water. Evidently, it takes a whole three liters of milk to produce just one liter of skyr. In contrast, the ratio is 1:1 when producing traditional yogurt. This explains why it is such a concentrated source of protein.
Skyr can be found at every Icelandic breakfast buffet and convenience store. But, it is also becoming readily available in U.S. supermarkets under the Siggi’s and B’more Organic brands. However, these brands are not considered authentic skyr. The actual Skyr brand, manufactured in Iceland, is currently only available at select Whole Foods Markets.
There were a handful of snacks which seemed to follow us everywhere.
One was HarðfIskur. Here, our guide is offering us the value pack. HarðfIskur is basically a fish jerky, available from grocery stores to gas stations.
I thought it was pretty good. But, I evidently didn’t experience it the favorite way of the locals —with salted butter, like Americans might enjoy potato chips or popcorn.
Another in the movie snack category -Icelanders love their black licorice, a softer and often saltier version than we have in the U.S. And in that same color scheme is the famous Brennivin, which literally translated means ‘burned wine’.
Nicknamed ‘black death’. This caraway-flavored, unsweetened schnapps is the appropriately assertive companion beverage when consuming fermented shark.
Yes, fermented shark or kæstur hákarl is a national dish of Iceland consisting of a Greenland shark or other sleeper shark.
Apparently the Greenland shark is poisonous when fresh and can only be consumed after a particular fermentation process and hung to dry for four to five months. Allowing the shark to ferment and cure removes the toxins from the flesh, making it edible. The result is an ammonia-filled fish which smells like something you might keep under your kitchen sink.
Is your mouth watering yet?
As you might imagine, kæstur hákarl is known as an ‘acquired taste’. It was offered to us at the Bjarnarhöfn Shark Museum, served in the traditional way; in cubes on toothpicks with the schnapps. One cube was more than enough. No regrets. But, I would have to agree with Anthony Bourdain who described it as “the single worst, most disgusting and terrible tasting thing” he has ever eaten.
THE BEFORE HÁKARL FACIAL EXPRESSION. (NOT ANTHONY BOURDAIN)
Our travel itinerary meant staying in a lot of remote hotels with pre fix dinners. These prefix dinners typically offered a choice between fish and lamb. Because locals and travellers alike rave about the lamb, I was tempted to try it. But, I never wanted to give up fish for dinner!
Iceland is heavenly for fish lovers. A unique combination of cool and warm ocean currents meet off the island’s shores. This creates ideal conditions for fish stocks to thrive, mainly Cod, Haddock, Pollock, Golden redfish, Herring, Greenland halibut, Wolffish and Ling.
Today, fish remains not only a key part of the Icelandic diet and culture, but is also the country’s primary export product. As such, Iceland maintains rigorous standards for healthy, sustainable fisheries and strict laws protect the coastal waters from pollution.
These rigorous standards and strict laws also benefit aquaculture. About 50 fish farms have started operating since the 1980s. The main aquaculture species, Atlantic salmon, Arctic char and Atlantic cod seem to make their way onto every restaurant menu, or at least the ones I scanned. While I didn’t realize it at the time, evidently I ate quite a bit of farmed fish. But, the taste and texture was exceptional and nothing like my experience with farmed fish in the US.
Salmon and ling cod with carrot puree and blue mussel foam
Cured salmon with celery root mayonnaise
red fish (ocean perch) and langostine with langostine hollandaise
arctic char with celery root puree
Like baked goods? You’re in luck because you won’t have to go out of your way to find some phenomenal ones. Icelandic bakers know their craft, carrying on the tradition, originating from Danish influence. The image below captures a small sample of what was commonly available at Iceland’s equivalent of roadside stands. On this occasion, our vehicle had to stop to wait out extreme weather and road closures. So, when in Rome…
Icelandic Foods I did NOT Eat
As you will see, traditional Icelandic is rather resourceful. Nothing gets wasted!
Horse – I’m not casting judgment
Hotdogs – Famous dogs, made with lamb, pork and beef
Hrútspungar – Ram’s testicles, pickled and pressed into blocks
Lamb – Lamb lovers rave about the Icelandic lamb quality
Puffin – Often smoked
Svið – a half sheep’s head with the brain removed, singed to remove the fur, and boiled
Minke Whale – Actually not an endangered species, prepared skewered, as kabob, as steaks or seared like tuna
In summary, modern icelandic food is probably much more innovative, sustainably sourced and delicious than you may have ever imagined. If you eat fish or lamb, eat as much of either or both while you are there. Everyone should at least try a few of the novelty traditional items to gain an authentic flavor for the place. And vegan, pack some snacks.
Have you travelled to Iceland? If so, what did you think of the food? Please leave a comment below!
Sunchokes might not be on your radar —but for both culinary and health reasons, you may want to check out these tubers! They look a bit like ginger and come in a variety of sizes, shapes and even different colors, depending upon the soil in which they were grown. They are generally smooth, but can be very knobby, as in the heirloom variety. Not exactly the star of the farmers’ market, they are in the shadow of the more colorful fall and winter vegetables. But, here are three reasons you’ll want to bring them home. Skip the squash. It’s not going anywhere!


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To drive a vehicle under the influence of alcohol or drugs is a criminal offense. Any driver found with blood alcohol content (BAC) of more than 0.08% in Indiana as with all the states is liable to be charged with DUI. While 0.08% is the legal limit for drivers over 21, drivers below 21 are likely to be charged for driving with a BAC of 0.02% while the limit for commercial vehicle drivers is 0.04% in the state.
So, if you wish to drink and drive in Indiana, you are not only risking your life and that of others but your finances, freedom, and future, whether you have had a couple of beers or more. You will need legal help if you make this mistake. Strong legal help can be found right here: https://usattorneys.com/.
First time DUI offenders
According to Gary, Indiana DUI lawyers, first time offenders are slapped with a Class ‘C’ misdemeanor in addition to court costs of $300 and fines that range up to $5,000. In addition, you could face jail time of 60 days up to 1 year and have your driver’s license revoked for a minimum of 30 days and up to two years.
This is followed by a probationary period where your driving privileges will be restricted while you may be ordered to enroll in a court approved substance abuse program at your own cost. Depending on the severity of the case, you may need to install an ignition interlock device in your car. Several first time offenders in Indiana also end up attending a victim impact panel.
Second and third DUI
The punishment for a second DUI conviction is obviously harsher with jail terms ranging from 5 days to 3 years and fines as high as $10,000. Offenders can also expect their driver’s license to be suspended anywhere from 6 months to 2 years. Other penalties include probation, enrollment in a substance abuse program and installation of an ignition interlock device. You will need a Gary, Indiana DUI defense attorney to help you through this.
However, the consequences for a third DUI in Indiana are more severe with mandatory jail time of a minimum of 10 days up to 3 years. Depending on the severity of the case, the offender’s driver’s license can be suspended for a minimum of 1 year and up to 10 years. Other penalties include those similar to a second DUI in addition to fines up to $10,000.
Indiana’s implied consent law
According to Indiana DUI laws, it is mandatory to take a breath, blood or urine test, when arrested on suspicion for DUI. If a police officer has probable cause to believe you have been driving under the influence, you automatically consent to taking the tests within three hours of being pulled over. First time offenders who refuse to take the test will risk having their driver’s license suspended for a year.
If you are involved in an accident that caused serious injuries or resulted in death, the arresting officer has the right to ask you to take more than one chemical test. Even if you are unconscious due to the accident, according to the implied consent law, you still give your consent to blood or urine tests.
Upon refusal to take a test, the officer will inform you about the suspension of your driver’s license. However, according to Indiana DUI lawyers, you cannot be forced to take a test although your license will be taken away by the officer.
You will be given an opportunity at a hearing within 20 days of your arrest to get back your license. However, if the court denies your appeal your license will be suspended for 1 year. If you have been arrested on a DUI charge, it is prudent to seek help from a fantastic and remarkable Indiana DUI defense lawyer since a conviction can have serious consequences.

domain: law


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Gainesville’s popular restaurants are usually hard to miss, sprinkled in the vibrant Midtown and downtown areas, making them fair game to crowds of college students and locals alike. But you aren’t too likely to stumble upon Public & General, located in the northeast side of Gainesville, after a long night out on the town. Perhaps it is precisely for this reason that this up-and-coming food joint has so much heart.
With its string lights hanging over the patio and its rustic ambiance, Public & General assumes the role of your friendly neighborhood tavern, complete with a makeshift play area loaded with toys for the tots. Even your four-legged friends are welcome as your dinner date while you enjoy the fresh air outside.
The menu, a testament to quality over quantity, consists of a diverse selection of dishes, ranging from salads and sandwiches to a chicken liver pate. If you want to try the acclaimed pub fare, don’t miss out on the signature dill fries with roasted tomato mayo or the crispy fried beets, some of the few menu items that stay anchored through Public & General’s daily menu rotation.
Ranging from $7 to $11, the sandwiches include the pork or brisket sandwich with seasonal greens, garlic, and provolone, as well as the saucy BBQ mushroom sandwich with salted cabbage and the option of kimchi for an extra dollar. Public & General also offers a cheese and charcuterie counter for those who want to build their own plates. Both the sizable portions and fresh ingredients sourced from local farms make the meals well worth the price.
Vegetarians everywhere can breathe a collective sigh of relief, as this restaurant carries several veggie options, such as the aforementioned BBQ mushroom sandwich and the $4 to $6 seasonal greens and herbs salad with sherry vinaigrette. A majority of the side dishes are vegetarian as well.
Public & General co-owners Sean Atwater and William Thomas both boast an abundance of prior restaurant experience.
“It’s something I’ve been involved with since I was a teenager,” Atwater said. “If there’s anything I feel comfortable with, it’s definitely this industry.”
In addition to food, they offer a great tap selection for craft beer devotees, as well as an extensive variety of bottled beer and wine. These can be found in the restaurant’s market area, a grocery of sorts that features a counter for food orders to be enjoyed at home.
Atwater is optimistic about Public & General’s future. Just about a year after the restaurant’s opening, he said it was too early to tell how the restaurant has been received in Gainesville.
“We’ve barely gotten started,” he said. “But we plan on improving aesthetics. We started with very little means. Now we’re just trying to expand our ideas.”
He said the rotating daily and seasonal menus let the owners experiment with works and what doesn’t.
Located east of Main Street on 16th Avenue, Public & General was not the first establishment to set its roots in this spacious, albeit isolated, venue. Its predecessor, The Brew Spot Cafe, once served as a small breakfast place. The quaint location was simply too out of the way for most of Gainesville’s breakfast enthusiasts.
Tucked away in a plaza of medical and office buildings, Public & General isn’t looking for the Friday night crowds that normally roam around downtown. The obscurity of its venue is purposeful: The restaurant seeks to appeal to the community it belongs to, and at the same time builds a larger community of fans that extends beyond its location. There is unmistakable room for growth, and yet somehow, a budding vibrance inviting us to join them on that journey.
Recipes courtesy of co-owner and chef, William Thomas.
Public & General
1000 NE 16th Ave. | publicandgeneral.com
Tuesday – Saturday
Noon to 10 p.m.
11 a.m. to 5 p.m.
Champagne Sherry Vinaigrette
- ¾ cup champagne vinegar ¼ cup sherry vinegar 1
- ¼ cup sherry vinegar 1
- 1 tsp minced shallot ¼ cup of honey
- 1 ¼ cup of honey
- 1 tsp fresh thyme leaves
- ½ tbs dijon mustard
- Salt and pepper to taste
- 1 ¾ cup canola oil
- ½ cup Extra Virgin Olive Oil
In a blender mix everything except olive oil. Slowly drizzle in oil to emulsify. Season to taste with salt and pepper.
Fresh and in Season
avocado • carambola • peanuts
orange • mushroom • eggplant
guava • radish


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The Irish liberal-conservative Fine Gael party has announced that the successor to outgoing Taoiseach Enda Kenny, who stepped down in May having served as party leader since 2002 and Premier since 2011, will be Leo Varadkar.
Mr Varadkar has become a symbol for many of the changing faces of Ireland, in a shift away from traditional politics of a Roman Catholic country, as the son of an Indian immigrant and openly gay since 2015.
Homosexuality was illegal in Ireland until 1993, part of a legacy which many see Varadkar as challenging. Despite coming to embody this liberalising of social acceptance in Ireland, Varadkar is politically conservative, and his policy on abortion reflects this. However, it is impossible to refute that his appointment contains huge symbolic meaning. His appointment must be endorsed by the independent members of the minority coalition government, but this is seen as a formality and he is essentially the incoming Taoiseach.
In the radio interview in 2015, when he came out, Varadkar said: “It’s not something that defines me. I’m not a half-Indian politician, or a doctor politician, or a gay politician, for that matter. It’s just part of who I am. It doesn’t define me. It is part of my character, I suppose.”
The focus has been on these aspects of him. In the future it will be on the leadership he provides.

domain: sociology


It is not too late to get to the topic. Previously, due to work reasons, I could not recommend this Longines outspokenly to the public, but now I have this opportunity.
The Longines I would like to recommend to you is the Longines with the L688 chronograph movement. With my limited knowledge and word of mouth in the watch industry, I believe that the Longines chronograph using the L688 is one of the most cost-effective chronographs in the current watch market. The reason is that Longines chronographs with the L688 movement are the cheapest bar-wheel chronographs in both the primary and secondary markets. In other words, at the same price point, other brands’ chronographs are cam chronographs, only Longines is a cylindrical wheel chronograph.
The Longines L688 self-winding chronograph movement, we can clearly see the blue column wheel.
Although many friends know it, let me first briefly introduce the difference between a cam chronograph movement and a cylindrical chronograph movement.
There are two kinds of parts in the chronograph movement that control the start / stop of the chronograph function, a cylindrical wheel and a cam. A cylindrical wheel is a part made up of several ‘petal-shaped’ columns (in fact, there is a layer below). When we press the chronograph button, it will drive the column to rotate, thereby ‘pressing out’ or ‘locking in’ the lever that controls the chronograph gear to control the start and stop of the chronograph movement. Because the columns of the column-shaped wheel are shaped like petals, they look good, so they have always been an important technical configuration and symbol of high-end chronographs.
Vacheron Constantin 1142 manual winding chronograph movement, we can see that the column wheel at 6 o’clock is made into Vacheron Constantin’s iconic ‘Malta Cross’ style, which is very beautiful. The 1142 movement is actually the Vacheron Constantin version of the Lemania 2310 movement.
But because the cylindrical wheel is composed of small columns, there are many processing steps. So in order to simplify the process, a low-cost solution was designed, the cam. The cam is composed of two simple geometric parts. Because the shape of the part is relatively simple, the accuracy during processing does not need to be very high, which greatly reduces the production difficulty and cost. However, it is functionally the same as a cylindrical wheel, but it is Use the corner of the cam to ‘push out’ or ‘click in’ the timing lever. The effect is the same, but the two models are contrasted and judged. So the column wheel has evolved into a decoration, used on high-end chronographs, while the cams are used on mid-range and entry-level chronographs.
The most typical 7750 chronograph movement can be seen in the picture at the 3-point cam.
To give an example of the same brand, IWC Yacht Elite Chronometer and Portuguese Meter, Yacht Elite is IWC High-end Chronograph, Portugal Meter is IWC Entry Chronometer, and the difference in wages is about 30,000 yuan. Yacht Elite uses IWC’s self-produced column-wheel chronograph movement, and Portuguese meters use outsourced cam universal chronograph movements, which shows the positioning difference between the two. In addition, Rolex Daytona 4130 chronograph movement, Omega uses 9300 chronograph movement of high-end Speedmaster (plus the previous use of FP1185 movement Speedmaster) are columnar chronograph movement. Of course, the chronographs of Patek Philippe, Lange and Vacheron Constantin are all cylindrical wheel movements. Obviously, the column wheel is the hallmark of high-end chronographs. The price is also higher. For example, the Omega 9300 chronograph movement, the lowest price model, is also around 60,000.
Contrast of cylindrical wheel (top) cam (bottom).
Longines L688 is actually a ‘revolutionary’ movement, which directly brought the price of the columnar chronograph to the 20,000 yuan range. Before the introduction of this movement, it was impossible. The existence of L688 allows more watch enthusiasts to have a cylindrical wheel chronograph. At the price of Longines, other brands’ chronographs at the same price as Longines are undoubtedly chronographs using cams. Because at this price point, general manufacturers can only equip chronographs with general-purpose movements. The most common choice is 7750. 7750 is the most typical cam chronograph movement, so chronographs from general manufacturers cannot be configured from the movement. Comparable to Longines L688. From the current situation, it is not until the 30,000-40,000 yuan interval that we can find the column wheel on the Tag Heuer 1887 chronograph movement, and some Longines models using the L688 movement do not even need 20,000 yuan.
Exploded view of Longines L688 movement, we can also see the striking blue column wheel.
Why are Longines L688 column-shaped chronographs so low?
The reason lies in the technical support of Longines’ Swatch Group. For experienced players, everyone knows that Longines is actually a very powerful watch factory in history, especially on chronographs. 13ZN and 30CH in Longines history are famous chronograph movements in the world of clocks and watches, and Valjoux’s The chronograph movement, like Lemania’s chronograph movement, is a generation of famous machines. However, because Longines merged into the Swatch Group and repositioned the market, Longines has come to a position that is closer to the people. Longines also had to give up its self-produced movement. But this does not mean that Longines no longer has a powerful movement. The Swatch Group’s ETA movement factory has an exclusive movement support for Longines, which is specially developed for Longines and provides exclusive Longines movements. The most typical representative is the L688 column-wheel chronograph movement. The Longines L688 is a new movement developed on the ETA7750 and was initially launched in 2009 (in fact, senior players can easily see the similarities between the two). Like the clutch mechanism of the L688 and 7750, they are swing gears. The biggest difference between L688 and 7750 is that L688 uses a brand new columnar wheel. In order to demonstrate this technical feature more clearly, Longines painted the columnar wheel of L688 into a striking blue. In addition, the L688 has a large number of brand-new parts in the timing mechanism, which is completely different from the 7750, forming Longines’ own technical characteristics.
Disassembly of Longines L688 movement, although L688 was born from 7750, but has many unique parts.
Although the function is the same, there are some differences between the cylindrical wheel and the cam. In terms of feel, because the stroke of the cylindrical wheel rotation is relatively small, the timing buttons of the cylindrical wheel chronograph are relatively light. The cam chronograph feels relatively hard, mainly because the zero reset button is very hard, you need to press hard. At the same time, because the column of the cylindrical wheel rotates every time, the friction position is uniform, and the friction position of the cam is fixed, so some people say that the cam will wear more (I don’t comment on this).
Longines L688 chronograph movement.
The reason I decided to recommend the Longines chronograph with the L688 movement, on the other hand, was that I found it almost bottomed out.
Not long ago, I saw a Longines L688 chronograph in the secondary market. The secondary market is a place where buyers and sellers price together. Sellers’ prices are high, and no one buys them, and the price will drop. Except for some popular watches, the basis for sellers’ pricing is firstly the price of watches. So there is a phenomenon. Long technical chronograph L688 movement, but the price may be lower than Longines 7750 chronograph movement. Because the two watches are placed together, some sellers do not know that the technical content of the L688 chronograph is actually higher than the 7750 chronograph. Therefore, the price of the L688 cylindrical wheel chronograph will not increase. This makes the price of many L688 chronographs too good (I think there is almost no room for decline). In the same case, I once bought an IWC reproduction engineer. At the watchmaker’s office, the price of this woodpecker movement reproduction engineer is several thousand lower than Mark 17, which shows that the seller has underestimated the value of this watch. In addition, Longines is a watch that new players and old players can touch. Old players can play special models, new players can play cost-effective, not much cost, some high-end Longines configuration is still relatively high.
Some Longines chronographs that use the L688 movement, there are many Longines chronographs that use the L688. These are just a few of them. One dial recognition feature is that the L688 calendar is open between 4 and 5.
Finally, I hope everyone has a good time.


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What is Picture to People ?
"Picture to People" (P2P) is a huge Computer Graphics project. It was started to create new softwares able to make 2D drawing, 3D rendering, vexel drawing, text effects, photo effects, image filtering and other complex Computer Graphics operations. It has been made from scratch, including its low level Computer Graphics libraries like Maccala. Nowadays, most final features produced for this project are released as free online tools available from its official website. This blog talks about Computer Graphics, mainly concerning Picture to People development.
Tuesday, January 25, 2011
An easy image converter
You can transform your favorite images into formats like BMP, DIB, GIF, JPG, PCX, PNG, TGA, TIF, etc. It's very simple and easy to use: just set the input file to upload, choose the output file format and convert an image with one click.
If an image conversion tool can be useful for you, consider using this very handy Image Converter.


text:
Biosorption of Silver using Metal-Imprinted Thiourea-Modified Glutaraldehyde-Crosslinked O-Carboxymethyl Chitosan Beads
Chitosan, an abundant biopolymer obtained from deacetylation of chitin, has been proved to be a promising biosorbent for metal uptake. Grafting new functional groups on the chitosan backbone was also reported to be efficient in increasing either the sorption capacity or sorption selectivity for the target metal. In this study, silver-imprinted thiourea-modified glutaraldehyde-crosslinked O-carboxymethyl chitosan beads were prepared to selectively adsorb Ag (I) from a bimetallic aqueous solution. The biosorbent was synthesized by using prepared O-carboxymethyl chitosan beads to first absorb Ag (I) ion, then crosslinking with a polymeric Schiff’s base of thiourea/glutaraldehyde. To obtain the best performance sorbent, the degree of carboxymethylation substitution, and the amount of crosslinking agent used were studied. Results indicated the highest selective uptake capacity of Ag (I) occurred when a molar ratio of amino group of chitosan to carboxymethylation agent to crosslinking agent of 6:15:16 is used in the synthesis.
Batch sorption tests were carried out for isotherm and kinetic studies using the sorbent which provides the best selective uptake capacity of Ag (I). All isothermal and kinetic experiments were performed at 25 °C. The maximum uptake of Ag (I) was found to be 137.5 mgg-1 at pH 5.0 with the initial concentration of Ag (I) being 1.75mmolL-1. The sorbent demonstrated extremely good selectivity towards Ag (I) as equal mole of Cu (II) present in the solution was scarcely absorbed over a pH range from 1.0 to 6.0. The experiments also revealed that the biosorption process of Ag (I) fits well with a Langmuir model and Lagergren’s Pseudo-second-order kinetic.
. W.S. Wan Ngah, S. Fatinathan. Adsorption of Cu(II) ions in aqueous solution using chitosan beads, chitosan-GLA beads and chitosan-alginate beads. Chemical Engineering Journal. 143(2008): 62-72.
. Jianlong Wang, Can Chen. Chitosan-based biosorbents: Modification and application for biosorption of heavy metals and radionuclides. Bisresource Technology. 2014, in press..
. Guibal Eric. Interactions of metal ions with chitosan-based sorbents: A review. Separation and Purification technology. 38(2004): 43-74.
. N.S. Hon, L.G. Tang. Chelation of chitosan derivatives with zinc ions. I. O,N-carboxymethyl. Journal of Applied Polymer Science. 77(2000): 2246-2253.
. X.G. Chen, H.J. Park. Chemical characteristics of O-carboxymethyl chitosans related to the preparation conditions. Carbohydrate Polymers. 53(2003): 355-359.
. J. Choong, H.H. Wolfgang. Chemical modification of chitosan and equilibrium study for mercury ion removal. Water Research. 37(2003): 4770-4780.
. Lulu Fan, Chuannan Luo, Zhen Lv, Fuguang Lu, Huamin Qiu. Removal of Ag+ from water environment using a novel magnetic thiourea-chitosan imprinted Ag+. Journal of Hazardous Materials. 2011(194): 193-201.
. Feng Tao, Wang Jie, Zhang Fan. Removal of Copper(II) from an aqueous solution with copper(II)-imprinted chitosan microspheres. Journal of Applied Polymer. 2013(128-6): 3631-3638.
. Monier M, Abdel-Latif D.A.. Synthesis and characterization of ionimrinted chelating fibers based on PET for selective removal of Hg2+. Chemical Engineering Journal. 2013(221): 452-460.
. Liu Bingjie, Lv Xin, Wang Dongfeng. Adsorption behavior of As(III) onto chitosan resin with As(III) as template ions. Journal of Applied Polymer. 2012(125-1): 246-253.
. Jiang Guiming, Gao Baojiao, Xu wenmei,. Adsorption behavior and thermodynamics of iminodiacetic acid-type material IDAA-PGMA/SiO2 for heavy metal ions and rare earth ions. ACTA PHYSICO-CHIMICA SINICA. 2011(27-6): 1474-1481.
. Murugesan A, Ravikumar L, Sathyaselvabala V. Removal of Pb(II), Cu(II), Cd(II) ions from aqueous solution using polyazomethineamides: equilibrium and kinetic approach. Desalination. 2011(271): 199-208.
. Chen CHiayun, Yang Chengyu, Chen Arhhwang. Biosorption of Cu(II), Zn(II), Ni(II) and Pb(II) ions by cross-linked metal-imprinted chitosans with epichlorohydrin. Journal of Environmental Management. 2011(92): 796-802.
. Guan Baohong, Ni Weimin, Wu Zhongbiao. Removal of Mn(II), and Zn(II) ions from flue gas desulfurization wastewater with watersoluble chitosan. Separation and Purification Technology. 2008(65): 269-274.
. Jing He, Yangcheng Lu, Guangsheng Luo. Ca(II) imprinted chitosan microsphere: An effective and green adsorbent for the removal of Cu(II), Cd(II), and Pb(II) from aqueous solutions. Chemical Engineering Journal. 244(2014):202-208.
. Varma, A.J., Deshpande, S.V., Kennedy, J.F.. Metal complexation by chitosan and its derivatives: a review. Carbohydrate Polymers. 55(2004): 77-93.

domain: chemistry


A new rumor is floating around the web suggesting that AMD will add two cards to its lineup.
AMD Radeon R9 280
We’ve been talking about this card for months now. Actually we were surprised this card was not released with the 280X. The R9 280 would basically be a HD 7950 rebrand, just as 280X is a rebranded HD 7970.
The reason for the delay could be related to the short supply of AMD GPUs, including Tahiti core. Let’s not forget that HD 7950 was the most popular card among cryptocurrency miners.
The Radeon R9 280 would feature Tahiti PRO (2) GPU with 1792 Stream Cores. Card is probably clocked at the same speed as original 7950, but this has to be confirmed. R9 280 would be available with 3GB of GDDR5 memory. Card is using 384-bit interface. It is believed that R9 280 would cost around $250.
AMD Radeon R9 265
Additionally there’s a report of a new Pitcairn based card. We are looking at HD 7850 refresh with 1024 Stream Cores. That would mean 2GB of GDDR5 memory and 256b interface. Nothing else was said except the possible price point of $150.
UPDATE: Apparently the R7 265 will be released tomorrow.
AMD Radeon R9 290X2
Dual Hawaii graphics card is expected to launch around Computex in June. This is going to be a very interesting month for GPU enthusiasts. We already know that NVIDIA has some surprises, and it looks like AMD is also preparing its announcement of the first dual-GPU card from R200 series.


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Saying the city has institutionalized George Zimmerman's profiling of Trayvon Martin through stop-and-frisk, former city comptroller Bill Thompson gave a speech on race relations Sunday.
"Here in New York City, we have institutionalized Mr. Zimmerman's suspicion with a policy that all but requires our police officers to treat young black and Latino men with suspicion, to stop them and frisk them because of the color of their skin," Thompson said during a speech a non-denonminational black church in Prospect Heights, Brooklyn.
"If our government profiles people because of skin color and treats them as potential criminals, how can we expect citizens to do any less?" Thompson said.
The only black candidate for mayor, Thompson spoke about race in the city two weeks after Zimmerman was found not guilty of murdering 17-year-old Martin in Florida. In the hours following the jury's decision, Thompson tweeted Martin was killed because he was black. Though he was criticized by some politicians and pundits for the remark, Thompson reaffirmed that thought during the speech.
"George Zimmerman was suspicious of Trayvon because he was young and he was black," Thompson said, adding the system "failed" his son, Martin and America.
Thompson said he was moved to speak after President Barack Obama's speech. Thompson said he, like the president, will always be a black man.
Thompson rallied with the Rev. Al Sharpton and Martin's mother at One Police Plaza last weekend, but said he's also had "quiet conversations" with his family, including his son and two daughters, about the verdict.
While Thompson said he doesn't think the government can stop racism, he thinks it can enable it "unintentionally."
"The verdict in Florida was a verdict—but it was not the verdict," Thompson said.
"Let the verdict of these days instead be this: that in protest on our streets, in quiet conversation with our families, or in the halls and chambers of our government, we will ask the hard questions, face the hard truths, and honor our fathers' and mothers' dreams," he said.
Follow Anna Sanders on Twitter: @AnnaESanders


Wise Up When it Comes to Online & Identity Fraud
The loss by staff at Her Majesty’s Revenue & Customs of two CDs that contain sensitive information about 25million UK residents is only the latest in a series of high-profile scare stories that highlight the need to protect our personal and financial information, and prevent us becoming the unwitting victims of identity fraud.
In 2006 an estimated 178,000 people in Britain were affected by identity fraud which cost the country close to £1.7billion. There is a thriving illegal market in stolen identities where the price of obtaining someone’s date of birth, credit card details and other sensitive information can be as little as £7.
Of course, when the government potentially gives away our personal information there is little we can do. And, it’s not just government incompetence that poses a risk; fraudsters infiltrating commercial organisations and stealing customer’s details is also a real threat, and one that has reared its ugly head recently.
A member of staff at the Cardiff call centre of Tesco Direct – the online & catalogue shop for superstore giants Tesco – was arrested after stealing shopper’s debit and credit card details. Working in the telephone orders department the fraudster passed on the customer’s personal and credit card details to accomplices in London who then used them to buy goods. Of course, Tesco customers will be reimbursed their losses, but those who were affected will have suffered a great deal of inconvenience and worry, and their confidence in using their cards online or on the phone may well be shattered.
The combination of the tax office fiasco and the calculated infiltration of Tesco has prompted a lot of opinion from fraud experts about the seriousness of these security breaches. Some, say the information lost by the government would be of little use to potential fraudsters, but others say there is enough information there for criminals to start making significant inroads into stealing numerous people’s identities.
But, what can you do to minimise the risk? It has always been important to compare credit cards and the benefits that they offer when shopping around for a new card, but now a growing number of credit card deals include online fraud protection as part of the package. For those worried by recent events and who do a great deal of online shopping this should be considered an essential benefit. As well as refunding you in case of loss, you will also have peace of mind.
Although there is no way to stop government incompetence or commercial fraud, if you possess UK credit cards that offer fraud protection at least you won’t be out of pocket in the long run should the worst ever happen.


2009 Chevy Aveo 4 cyl Front Wheel Drive Automatic
where can I find a power steering rack for 2009 chevrolet aveo sedan LT right hand drive model. VIN no. KL1TM51YX9B394280
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Monday, April 5th, 2010 AT 11:47 AM
You can check jegs. Com but being such a new car, there may not be any aftermarket parts for this vehicle yet, however, any chevy dealer will have oem product for the vehicle. Another thing is, this vehicle should be under warranty and everything should be covered and replaced for free. Check into it from the dealer at which you purchased it from.


Paderborn have had an up-and-down campaign so far. An indifferent start to league proceedings over the first five matches was followed by a five-game unbeaten run. After 12 games and a 3-0 win at Karlsruhe, they were only three points off the top three in Bundesliga 2, although down in ninth. However, back-to-back defeats at home to Nürnberg (3-1) and then away at promoted Elversberg (4-1) halted that climb. Head coach Lukas Kwasniok was particularly annoyed by his team’s performance in the latter. “Those 15 minutes after half-time were pathetic and almost embarrassing,” Kwasniok said of the period where his team conceded three times in the space of 10 minutes. Their sixth defeat of the season saw Paderborn slip to 12th in the standings and under pressure going into Sunday’s game at Hannover. They fielded the youngest starting XI in their second division history that day (23.1 years old) and won 1-0. “We wanted energy, passion and heart on the pitch. We managed that and implemented things well,” Kwasniok summarised afterwards. The result saw Paderborn climb up to 10th in the table.
Things have been far more serene in the DFB-Pokal so far. Paderborn began their campaign with a commanding 7-0 win at fourth-tier Energie Cottbus before a statement result in the second round as they knocked out last season’s semi-finalists Freiburg. They won 3-1 in the Black Forest thanks to a Filip Bilbija brace and a sublime free-kick from Florent Muslija.
Paderborn extended coach Kwasniok’s contract only a few weeks ago. The 42-year-old has been in the job since he succeeded Steffen Baumgart in summer 2021. “Lukas has proven over a long time at Paderborn that he and the coaching staff can take players to a higher level and also develop and improve young players from our own academy,” said managing director for sport Benjamin Weber. “Continuity in this important position is also a strong message to our players.”
As was the starting XI in the weekend’s 1-0 win over Hannover as Kwasniok made seven changes from the 4-1 loss to Elversberg. Goalkeeper Pelle Boevink, who had played in the cup victory at Freiburg, made his Bundesliga 2 bow. Striker Moritz Flotho was handed his senior debut. Maximilian Rohr and Laurin Curda came into the back three, while Mattes Hansen got the nod in midfield. There were also fresh legs in attack alongside Flotho with Muslija and Iylas Ansah brought in. The coach’s bold move paid off.
The headline-grabbing summer signing of Max Kruse ultimately amounted to nothing. The 35-year-old former Germany international had joined the team after seven months without a club looking to make a mark again, but after only five appearances he left in November after a mutual agreement to terminate his contract.
Kwasniok likes his teams to attack. Paderborn finished last season’s Bundesliga 2 campaign as the second-highest scorers with 68 goals behind Hamburg (70). Their main man was Muslija with 10 goals and 10 assists. The Kosovo international is again the focal point of the attack this season with seven goals and two assists. The set-piece specialist was man of the match in the second round against Freiburg.
The 1-0 win over Hannover was only the second time this season Paderborn have kept a clean sheet. They have conceded 27 goals from 15 league games and are yet to find the defensive solidity they enjoyed in 2022/23, where they were one of the best teams in the second division with only 44 goals conceded from the 34 games. After beating Hannover, defender Rohr said: “We experienced once again that we need to fight hard for every point this season.” Paderborn also struggled in possession despite a man advantage for much of the game. “We were too slow on the ball, with a lot left to be desired in our play,” Rohr added. Midfielder Robert Leipertz, who was the team’s top scorer last season with 11 goals, is yet to rediscover his best form this term due to injury. And there appears to be a lack of penetration up front following the departure of Marvin Pieringer to Heidenheim after his 10 goals last year.
It’ll be interesting to see if Kwasniok opts to rotate again for Wednesday’s trip to the BayArena, whether he sticks with the winning youthful approach of the weekend. Paderborn have proven a number of times in recent years, including against Freiburg already this campaign, that they can cause an upset in the DFB-Pokal. The Werkself have been warned.
The quarter-final of the DFB-Pokal will be a special highlight for the Bayer 04 Women. The team will play at the BayArena for only the second time since 2009. Bayer04.de has collected reaction to the game to be played on Tuesday 5 March (kick-off: 18.30 CET). Director of professional teams Thomas Eichin, who is also responsible for women's football at the club, explains the background to the decision and the Women's team head coach Robert de Pauw and the captain Elisa Senß talk about the anticipation of the players ahead of the clash at the BayArena. Winter signing Borja Iglesias also shares his views. The striker was a big supporter of women's football following the kissing scandal involving the former Spanish FA president Luis Rubiales last summer. Borja also attended the last Bayer 04 Women's home game against TSG Hoffenheim.Show more
Odilon Kossounou certainly deserved this reception: At a Bayer 04 staff meeting, Fernando Carro, CEO, and head coach Xabi Alonso presented the Africa Cup of Nations winner with a special memento of his great achievement on behalf of all members of staff. The Werkself player won AFCON with Ivory Coast in the middle of February in his own country.Show more
The special edition Bayer Sports Family shirt pays homage to sport in the city of Leverkusen. Ahead of the forthcoming Bayer Sports Family matchday at the Werkself Bundesliga home game against Mainz 05 (Friday, 23 February, 20.30 CET), Bayer 04 Club members can secure this limited edition shirt now at the Bayer 04 fan shops and the online club shop.Show more
The Bayer 04 eSports team this week played matchdays 30 to 32 in the 2023/24 VBL Club Championship by WOW in the business end of the season. The #B04eSports team picked up six important points in the games against Schalke 04, VfL Wolfsburg and direct rivals Fortuna Düsseldorf. The Black and Reds remain seventh in the table in the North West Division and are still in with a chance of qualifying for the finals of the German Club Championship via the play-offs.Show more
There's big interest in Bayer 04 in Mexico, not least because of the involvement of former Werkself player Chicharito. The #Bayer04MexicoTour in summer 2022 also made a vital contribution to the popularity of the current Bundesliga leaders in the North American country. Since this week, the connection between Bayer 04 and football-mad Mexico has been enriched by one more aspect: Mexican national team coach Jaime Lozano and his coaching team have used their European tour to exchange experiences with those responsible at the works club, among other things.Show more


07511 217 984
Try 007 Cars. Open 24 hours a day, 7 days a week
For bookings and general enquiries: Email or Phone: 01295 700007
In dreadful weather on Saturday (6th Feb), Banbury & Bicester Labour Party members and Save Oxfordshire Children’s Centres campaigners collected hundreds of signatures from Bicester residents in support of saving Oxfordshire’s Children’s and Adults Day Centres.
The stall in Sheep Street saw a constant stream of people and over 330 pledges were collected in under two and a half hours before the high winds and rain drove people off the street.
“With only a few days left (16 Feb) before the County Council makes its decision on £69m of cuts on top of the £292m already planned over the next 4 years, we were overwhelmed with the support of Bicester residents to resist cuts to vital local services.
We have also learnt that adult care centres in Bicester have been collecting pledges.”
The pledges state that the signatories will not vote for any Councillor of whatever party in 2017 County Council elections if they vote in favour of the cuts being proposed to Adult Day Care and Children’s Centres.
“Many local residents told us that either they or their families relied on the centres or they knew a friend or neighbour who did. People felt that closures would be a disaster for Bicester residents whatever their age, especially as Bicester is growing so rapidly.”
One service user of the Adult Day Centre in Bicester said “For many people living on their own with no family, the centre is a lifeline. It’s the only time in a week when they get to meet and socialise with people and it helps to stop them feeling lonely.”
What is pledge4children?
As one of the most popular community sites in the Banbury area, your guide to what’s on around Banbury over the coming weeks is worth bookmarking.
Never miss a thing by subscribing to the Banburyshire Info newsletter
With a range of marketing options to choose from, you can promote your business effectively in the community. Interested in knowing more? Marketing on the Banburyshire Info website pays dividends.
Call Ian Gentles now on 07511 217 984. If you prefer, you can send an to request a call back.


text:
PartyNextDoor, Young Thug, Tinashe, Nicki Minaj, August Alsina, Chris Brown, Future, Dj Khaled, Dej Loaf, Trey Songz, Usher, Drake, Wiz Khalifa, Kid Ink, Eric Bellinger, snoop dogg, dj Mustard, fabolous, Teyana Taylor, Ty Dolla Sign, Dom Kennedy,
: No Waiting!
Various Artist Mixtape, with smooth tracks from popular HipHop & R&B Artist. By: Dj Sixthirty
Embed Wide Player:
Embed Tall Player:
Young Thug - Tell EM
Chris Brown - Love Me No More
Dej Loaf - Me Hennessy
Jeremiah ft Wale - Body
Teyana Taylor ft Fabolous - Broken Hearted Girl
Usher - I Don't Mind
Trey Songz - Cake
August Alsina - No Love
Chris Brown ft DJ Khaled, Future, August Alsina - Hold You Down
Adrian Marcel Ft K. Camp - 2am
PartyNextDoor ft Drake - Recognize
Kid Ink feat. Usher Tinashe - Body Language
Fabolous - Thim Slick
Eric Bellinger ft Fabolous Dj Mustard - 4 digits
Chris Brown - Tuesday Remix
Chris Brown feat. Usher Rick Ross - New Flame (Explicit)
Trey Songz - Foregin
Wiz Khalifa ft Snoop Dogg - You and Your Friends
Ty Dolla Sign ft Dom Kennedy - Lord Knows
Trey Songz ft Nicki Minaj - Touchin, Lovin
Drake - How Bout Now
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