TITLE: Spectral symmetry of a certain structured matrix
QUESTION [16 upvotes]: I have a matrix
$$ A= \begin{pmatrix} 0 & a & d & c\\ \bar a & 0 & b & d \\ \bar d  & \bar b & 0 & a \\ \bar c & \bar d & \bar a & 0 \end{pmatrix} $$
As you can see, the matrix is always self-adjoint for any $a, b, c, d \in \mathbb C$.
But it has a funny property (that I found by playing with some numbers):
If $a,b,c$ are arbitrary real numbers and also $d$ is real, then the spectrum of $A$ is in general not symmetric with respect to zero. To illustrate this, we take $d := 2$, $a := 5$, $b := 3$, $c := 4$ then the eigenvalues are
$$\sigma(A):=\{10.5178, -6.54138, -3.51783, -0.458619\}$$
But once I take $d \in i \mathbb R$, the spectrum becomes immediately symmetric. In fact, $d := 2 i$, $a := 5$, $b := 3$, $c := 4$ leads to eigenvalues
$$\sigma(A)=\{-9.05607, 9.05607, -0.993809, 0.993809\}$$
Is there any particular symmetry that only exists for $d \in i\mathbb R$ that implies this nice inflection symmetry?
I am less interested in a brute-force computation of the spectrum than of an explanation of what symmetry causes the inflection symmetry.

REPLY [37 votes]: For real $a,b,c$ and imaginary $d$ the matrix $A$ has chiral symmetry, meaning it anticommutes with a matrix $X$ that squares to the identity:
$$X=\left(
\begin{array}{cccc}
 0 & 0 & 0 & -i \\
 0 & 0 & i & 0 \\
 0 & -i & 0 & 0 \\
 i & 0 & 0 & 0 \\
\end{array}
\right),\;\;XA+AX=0,\;\;X^2=I.$$
Hence the spectrum of $A$ has $\pm$ symmetry:
$$\det (\lambda-A)=\det(\lambda X^2-XAX)=\det(\lambda+X^2A)=\det(\lambda+A),$$
so if $\lambda$ is an eigenvalue then also $-\lambda$.

REPLY [16 votes]: An equivalent trick : Let $J:= \operatorname{diag}(1,i,-1,-i)$. Then $J^*AJ=iB$ where $B$ is real and skew-symmetric. Hence the spectrum of $iB$ (thus that of $A$) comes by pairs $\pm\lambda$.